Macrobenthos and multi-molecular markers as indicators of environmental contamination in a South American port (Mar del Plata,Southwest Atlantic)

We evaluated benthic habitat quality along a presumed contamination gradient in the Mar del Plata port (Southwestern Atlantic) by coupling biological and chemical proxies in a multidisciplinary approach. Organic matter and photosynthetic pigment contents were higher in silty-clay bottoms of the inner port sites. Levels of all fecal steroids decreased from the inner sites to the port inlet. High concentrations of coprostanol in the inner sites seemed to derive from a permanent population of sea lions rather than from sewage outfalls due to coprostanol/epicoprostanol ratio (IV) values <2.5. PAHs levels were also higher in the inner sector, related to both biomass combustion and petroleum combustion associated to local marine traffic. High disturbance and low ecological status were reflected in low benthic diversity and high AMBI values in the inner sites.     

Seismic stratigraphical record of Lake Levinson‐Lessing,Taymyr Peninsula: evidence for ice‐sheet dynamics and lake‐level fluctuations since the Early Weichselian

A multi‐channel, high‐resolution seismic reflection survey using a Micro‐GI airgun was carried out in the framework of the Russian‐German project PLOT (Paleolimnological Transect) on Lake Levinson‐Lessing, Taymyr Peninsula, in 2016. In total, ~70 km of seismic reflection profiles revealed in unprecedented detail the glacial and postglacial sedimentary infill of the lake basin. Five main seismic units have been recognized and interpreted as glacial (Unit V), subglacial and proglacial (Unit IV), marine (Unit III), fluvial‐lacustrine (Unit II) and lacustrine (Unit I) sediments. Of particular significance are imbricated, south‐orientated structures present in the southernmost part of the lake basin within Unit V and a large topographic ridge recognized in front of those structures. We interpret these structures as push moraines and an end moraine, respectively, left by the glacier after its retreat. The depositional pattern of the units above the moraines documents past lake‐level fluctuations. We interpret Unit IV, Unit III and Unit I as highstand deposits, and Unit II as lowstand deposits. Gas‐charged sediments dominate the northern part of the lake basin, whilst they occur only sporadically and in limited spatial extent in the central and southern parts of the lake. In the latter areas, the seismic and echo‐sounder data suggest recent tectonic activity. Our study contributes to the reconstruction of environmental conditions in the Taymyr Peninsula directly following the Early Weichselian deglaciation and shows that deep tectonic lake basins affected by several glaciations can preserve important palaeoenvironmental records, which contributes significantly to our understanding of palaeoenvironmental changes in the Taymyr Peninsula and the central Russian Arctic.     

Surface moisture area during rainfall–run‐off events to understand the hydrological dynamics of a basin in a plain region

The understanding of the hydrology of plain basins may be improved by the combined analysis of rainfall–run‐off records and remote sensed surface moisture data. Our work evaluates the surface moisture area (SMA) produced during rainfall–run‐off events in a plain watershed of the Argentine Pampas Region, and studies which hydrological variables are related to the generated SMA. The study area is located in the upper and middle basins of the Del Azul stream, characterized by the presence of small gently hilly areas surrounded by flat landscapes. Data from 9 rainfall–run‐off events were analysed. MODIS surface reflectance data were processed to calculate SMA subsequent to the peak discharge (post‐SMA), and previous to the rainfall events (prev‐SMA), to consider the antecedent wetness. Rainfall–run‐off data included total precipitation depth (P), maximum intensity of rainfall over 6 hr (I6max), surface run‐off registered between the beginning of the event and the day previous to the analysed MODIS scene (R), peak flow (Qp), and flood intensity (IF). In contrast with other works, post‐SMA showed a negative relationship with the R. Three groups of cases were identified: (a) Events of low I6max, high prev‐SMA, and low R were associated with slow and weakly channelized flow over plain areas, leading to saturated overland flow (SOF), with large SMA; (b) events of high I6max, low prev‐SMA, and medium to high R were rapidly transported along the gentle slopes of the basin, related to Hortonian overland flow (HOF) and low post‐SMA; and (c) events of medium to high I6max and prev‐SMA with medium R were related to heterogeneous input‐antecedent‐run‐off conditions combined: Local spatial conditions may have produced HOF or SOF, leading to an averaged response with medium SMA. The interactions between the geomorphology of the basin, the characteristics of the events, and the antecedent conditions may explain the obtained results. This analysis is relevant for the general knowledge of the hydrology of large plains, whose functioning studies are still in their early stages.     

Experimental shock metamorphism of terrestrial basalts: Agglutinate-like particle formation,petrology, and magnetism

Hypervelocity impacts occur on bodies throughout our solar system, and play an important role in altering the mineralogy, texture, and magnetic properties in target rocks at nanometer to planetary scales. Here we present the results of hypervelocity impact experiments conducted using a two-stage light-gas gun with 5 mm spherical copper projectiles accelerated toward basalt targets with ~6 km s⁻¹ impact velocities. Four different types of magnetite- and titanomagnetite-bearing basalts were used as targets for seven independent experiments. These laboratory impacts resulted in the formation of agglutinate-like particles similar in texture to lunar agglutinates, which are an important fraction of lunar soil. Materials recovered from the impacts were examined using a suite of complementary techniques, including optical and scanning electron microscopy, micro-Raman spectroscopy, and high- and low-temperature magnetometry, to investigate the texture, chemistry, and magnetic properties of newly formed agglutinate-like particles and were compared to unshocked basaltic parent materials. The use of Cu-projectiles, rather than Fe- and Ni-projectiles, avoids magnetic contamination in the final shock products and enables a clearer view of the magnetic properties of impact-generated agglutinates. Agglutinate-like particles show shock features, such as melting and planar deformation features, and demonstrate shock-induced magnetic hardening (two- to seven-fold increases in the coercivity of remanence B_cr compared to the initial target materials) and decreases in low-field magnetic susceptibility and saturation magnetization.     

Andesitic Plinian eruptions at Mt. Ruapehu: quantifying the uppermost limits of eruptive parameters

New tephro-stratigraphic studies of the Tongariro Volcanic Centre (TgVC) on the North Island (New Zealand) allowed reconstruction of some of the largest, andesitic, explosive eruptions of Mt. Ruapehu. Large eruptions were common in the Late Pleistocene, before a transition to strombolian-vulcanian and phreatomagmatic eruptive styles that have predominated over the past 10,000?years. Considering this is the most active volcano in North Island of New Zealand and the uppermost hazard limits are unknown, we identified and mapped the pyroclastic deposits corresponding to the five largest eruptions since ~27?ka. The selected eruptive units are also characterised by distinctive lithofacies associations correlated to different behaviours of the eruptive column. In addition, we clarify the source of the ~10–9.7?ka Pahoka Tephra, identified by previous authors as the product of one of the largest eruptions of the TgVC. The most common explosive eruptions taking place between ~13.6 and ~10?ka?cal?years BP involved strongly oscillating, partially collapsing eruptive columns up to 37?km high, at mass discharge rates up to 6?×?10⁸?kg/s and magnitudes of 4.9, ejecting minimum estimated volumes of 0.6?km³. Our results indicate that this volcano (as well as the neighbouring andesitic Mt. Tongariro) can generate Plinian eruptions similar in magnitude to the Chaitén 2008 and Askja 1875 events. Such eruptions would mainly produce pyroclastic fallout covering a minimum area of 1,700?km² ESE of the volcano, where important touristic, agricultural and military activities are based. As for the 1995/1996 eruption, our field data indicate that complex wind patterns were critical in controlling the dispersion of the eruptive clouds, developing sheared, commonly bilobate plumes.     

Aerosol Measurements in the Atmospheric Surface Layer at L’Aquila,Italy: Focus on Biogenic Primary Particles

Two year measurements of aerosol concentration and size distribution (0.25 μm < d < 30 μm) in the atmospheric surface layer, collected in L’Aquila (Italy) with an optical particle counter, are reported and analysed for the different modes of the particle size distribution. A different seasonal behaviour is shown for fine mode aerosols (largely produced by anthropogenic combustion), coarse mode and large-sized aerosols, whose abundance is regulated not only by anthropogenic local production, but also by remote natural sources (via large scale atmospheric transport) and by local sources of primary biogenic aerosols. The observed total abundance of large particles with diameter larger than 10 μm is compared with a statistical counting of primary biogenic particles, made with an independent technique. Results of these two observational approaches are analysed and compared to each other, with the help of a box model driven by observed meteorological parameters and validated with measurements of fine and coarse mode aerosols and of an atmospheric primary pollutant of anthropogenic origin (NO_x). Except in winter months, primary biogenic particles in the L’Aquila measurement site are shown to dominate the atmospheric boundary layer population of large aerosol particles with diameter larger than 10 μm (about 80 % of the total during summer months), with a pronounced seasonal cycle, contrary to fine mode aerosols of anthropogenic origin. In order to explain these findings, the main mechanisms controlling the abundance and variability of particulate matter tracers in the atmospheric surface layer are analysed with the numerical box-model.     

Modeling the formation of the K-Pg boundary layer

In this paper we investigate the formation of the Cretaceous-Paleogene (K-Pg) boundary layer through numerical modeling. The K-Pg layer is widely agreed to be composed of meteoritic material and target rock from the Chicxulub impact site, that has been ejected around the globe and mixed with local material during final deposition. The observed composition and thickness of the K-Pg boundary layer changes with azimuth and distance from the impact site. We have run a suite of numerical simulations to investigate whether we can replicate the observational data, with a focus on the distal K-Pg layer and the impact glasses at proximal sites such as Beloc, Haiti. Previous models of the K-Pg ejecta have assumed an initial velocity distribution and tracked the ejecta to its final destination. Here, we attempt to model the entire process, from impact to the arrival of the ejecta around the globe. Our models replicate the observed ejecta thickness at proximal sites, and the modeled ejecta is composed of sediments and silicate basement rocks, in agreement with observational data. Models that use a 45° impact angle are able to replicate the total ejecta and iridium volume at distal sites, and the majority of the ejecta is composed of meteorite and target sediments. Sub-vertical impacts generate too little iridium, and oblique impacts of ?30 degrees generate too much. However, in contrast to observations, models that involve ballistic transport of ejecta lead to ejecta thickness decreasing with increasing distance, and are unable to transport shocked minerals (quartz and zircon) from the Chicxulub basement rocks around the globe. We suggest that much of the K-Pg ejecta is transported non-ballistically, and that the most plausible mechanism is through re-distribution from a hot, expanding atmosphere. The results are important for future investigations of the environmental effects of the Chicxulub impact.