The polymer-like organic material in the Orgueil meteorite

The insoluble organic material in the Orgueil (Cl) chondrite was analyzed by combined high vacuum pyrolysis-gas chromatography-mass spectrometry. Stepwise pyrolyses at 150, 300, 450 and 600°C of Orgueil meteorite powder which had been exhaustively extracted with solvents yielded a series of alkenes and alkanes to C₈, an extensive series of alkylbenzene isomers, thiophene, alkylthiophenes, and benzothiophene, together with the nitrogen- and oxygen-containing breakdown products, acetonitrile, acrylonitrile, benzonitrile, acetone and phenol. The Orgueil polymer fragmentation products are very similar both qualitatively and quantitatively to pyrolysis products of solvent-extracted Pueblito de Allende (C3) chondrite described in the literature.Changes in the relative abundances of polymer degradation products between 150 and 600°C imply the preferential loss of aliphatic and certain heteroatomic portions of the polymer at lower temperatures to leave highly condensed aromatic and heteroaromatic portions of the polymer which begin to fragment only at 450–600°C. The Orgueil polymer-like matter thus appears to be a complex mixture of polymerized materials having different thermal stabilities. Similarities between vacuum pyrolyzates of the Orgueil polymer and terrestrial kerogen suggest the possibility that meteorite organic matter may have been subjected on the meteorite parent bodies to diagenetic processes similar to those by which terrestrial kerogen is formed.     

Plutonism in Pan-African belts and the geologic evolution of northeastern Africa

Plutonic igneous rocks of Pan-African belts (500–600 m.y. age) in Africa can be described in terms of three types of assemblages: (1) migmatites formed largely by remobilization of pre-existing sialic crust during Pan-African time; (2) calcalkaline batholithic suites formed in association with subduction of oceanic crust; and (3) alkali-rich, post-tectonic granites. Many suites cannot be placed precisely in one of these categories, either because of intermediate (gradational) characteristics or because of lack of adequate information. Distinction of rocks formed during Pan-African time from older ones whose radiometric clocks were reset at that time is also difficult.The rock suites are very unevenly distributed geographically. Migmatites formed by ensialic crustal remobilization occur mostly in southern and central Africa. Calcalkaline suites occur in north Africa, particularly the northeast. Alkali-rich granites are virtually restricted to the northeastern portion of the continent, the one major part of Africa not occupied by an Archean shield. Evidence for subduction of oceanic crust is also restricted to northeastern Africa.The geologic history proposed for northeastern Africa is as follows: During, and immediately preceding, Pan-African time an ocean basin of uncertain size and shape occurred between the West African and Nubian-Arabian shields. Subduction zones were active on the margins and within the basin. During, and at the end of, Pan-African time extensive development of alkali-rich granites was associated with cratonization of the basin. Paleozoic sediments were then deposited under platform conditions on the newly formed craton, which showed mild epeirogenic activity throughout the Phanerozoic.     

The prism method for terrain corrections using digital computers

Summary In the prism method of making terrain corrections, the topography is approximated by a model consisting of right rectangular prisms. The vertical component of the gravitational attraction of each prism is calculated and the sum of these components gives the terrain correction.The prism method as programmed has no computational limitations. It can be used on all sizes of computers; it can be applied to a large area with any fine grid interval; it can be processed in a single run and yet provides complete flexibility for both research and routine computations. This has been achieved by breaking up larger areas into regions which fit into the computer memory. The contributions of these regions are automatically summed up for each station. While processing each region, various controls may be used at each station to exclude the contribution of a distant part of the area, to use approximate expressions farther from the station, to print out details around the station. There is also provision to refine the model by using smaller prisms around each computation point. Thus full use of elevation control can be made to calculate the terrain correction, the accuracy of which depends only on the quality of the input data.The prism method has been used to calculate terrain corrections for 130 stations in the New Quebec crater area. For five of these stations terrain corrections were also calculated by usingHammer's template. The two independent sets of values differ by less than four per cent.     

Advances in the combined interpretation of seismics with magnetotellurics1

Five examples, obtained during exploration for hydrocarbons in the Pannonian Basin of Hungary, are used to show how the interpretation of seismic sections can be usefully complemented by results from MT surveys. Selection of the most appropriate MT quantities, considered to be proper ‘MT attributes’ for the purpose of visualization as well as recognition of the subsurface structures and the different inversions of MT data is essential for practical integration of seismic and MT surveys. A new technique providing a semiquantitive MT-attribute pseudosection for the purpose of visualization of the subsurface structures is proposed. The procedure utilizes derivative functions of the phase of MT impedance for visualization and derives estimated depths from the Bostick transformation of Cagniard apparent resistivities. On the basis of the MT-attribute pseudosections, constructed from the phase derivatives and transformed resistivity data, depths are estimated for interfaces between geological formations with significant resistivity contrast. In particular examples, the interface between the Tertiary sediments and the older basement rocks as well as tectonic fracture zones with decreased resistivity can be resolved.     

Ab initio 2-D periodic Hartree–Fock study of Fe-substituted lizardite 1T– a simplified cronstedtite model

 A 2-D periodic ab initio Hartree–Fock LCAO study was performed on Fe-substituted 1:1 sheet silicate, lizardite. The atomic orbitals were described by large-core pseudopotentials (Fe atoms) and a sp basis set (the other atoms). Calculated atomic charges and the results of bond population analysis indicate that the Fe-O bond was as ionic as the Mg-O. This hypothesis was supported by calculated density of states and electron density maps. Increasing Fe for Mg substitution changed the shape of projected density of states (PDOS) of O(p) orbitals. Received: 27 January 2000 / Accepted: 21 May 2000     

Disappearing ionospheres on the nightside of Venus

Instruments on the Pioneer Venus Orbiter have detected a substantial ionosphere on the nightside of Venus during most orbits. However, during some orbits the nightside ionosphere seems to have almost disappeared, existing only as irregular patches of low-density plasma. The solar wind dynamic pressure on these occasions is greater than average. We have correlated data from several instruments (Langmuir probe, ion mass spectrometer, retarding potential analyzer, magnetometer, and plasma analyzer) for a number of orbits during which the nightside ionosphere had disappeared. The magnetic field tends to be coherent, horizontal, and larger than usual, and the electron and ion temperatures are much larger than they usually are on the nightside. We suggest mechanisms which might explain the reasons for the disappearance of the ionosphere when the solar wind dynamic pressure is large.