Meso‐scale particle modeling of concrete deterioration caused by alkali‐aggregate reaction

A meso‐scale particle model is presented to simulate the expansion of concrete subjected to alkali‐aggregate reaction (AAR) and to analyze the AAR‐induced degradation of the mechanical properties. It is the first attempt to evaluate the deterioration mechanism due to AAR using the discrete‐element method. A three‐phase meso‐scale model for concrete composed of aggregates, mortar and the interface is established with the combination of a pre‐processing approach and the particle flow code, PFC2D. A homogeneous aggregate expansion approach is applied to model the AAR expansion. Uniaxial compression tests are conducted for the AAR‐affected concrete to examine the effects on the mechanical properties. Two specimens with different aggregate sizes are analyzed to consider the effects of aggregate size on AAR. The results show that the meso‐scale particle model is valid to predict the expansion and the internal micro‐cracking patterns caused by AAR. The two different specimens exhibit similar behavior. The Young's modulus and compressive strength are significantly reduced with the increase of AAR expansion. The shape of the stress–strain curves obtained from the compression tests clearly reflects the influence of internal micro‐cracks: an increased nonlinearity before the peak loading and a more gradual softening for more severely affected specimens. Similar macroscopic failure patterns of the specimens under compression are observed in terms of diagonal macroscopic cracks splitting the specimen into several triangular pieces, whereas localized micro‐cracks forming in slightly affected specimens are different from branching and diffusing cracks in severely affected ones, demonstrating different failure mechanisms. Copyright © 2012 John Wiley & Sons, Ltd.     

Paleolimnological investigations of anthropogenic environmental change in Lake Tanganyika: V. Palynological evidence for deforestation and increased erosion

Pollen spectra from seven short cores taken from deltaic sites in the central and northern parts of Lake Tanganyika provide information about vegetation changes around the lake during the last 5000 years. Pollen analysis was undertaken to understand the history and timing of catchment deforestation and its causal linkage to excess sedimentation and ecosystem change in Lake Tanganyika. The spectra are dominated by grass pollen at all levels in every core. Grass pollen percentage values range between 40 and 80%. Low values of arboreal pollen taxa (1–20%) were documented from most cores except core LT-98-2M. Core LT-98-2M represents the longest duration vegetation record of this study (close to 5000 years BP), and records the onset of increasingly arid conditions in the Late Holocene, especially after 500 A.D., with the probable replacement of forest by open grassland in the Mahale Mountains region. The pollen/spore content for other cores showed a consistent trend of a decrease in grass pollen and an increase in pteridophyte and forest indicator pollen taxa during the last few centuries, contemporaneous with other indications of increased watershed disturbance from forest clearing (especially isotopes and lake faunal change). The timing or strength of this trend is not tied to specific levels of watershed disturbance. However, increasing fern spore abundance does occur progressively later towards the south, where modern human population densities are lower. Although increasing fern spore abundance is consistent with a land-clearing hypothesis, the rising arboreal pollen percentages are seemingly counterintuitive. One possible explanation is that increasing arboreal pollen proportions reflects the recycling of abundant pollen of this type from rapidly eroding soils. Another likely explanation for this finding is that land clearing involved the replacement of miombo woodland, with its mixture of trees producing little pollen and understory grasses producing large amounts of pollen, by the present day cassava, banana, and legume agricultural systems, all of which are poor pollen producers. This shift in catchment vegetation would increase the relative contribution of Afromontane pollen transported long distances from the surrounding highland regions. This hypothesis is consistent with both the lack of correlation of palynological history with specific watershed deforestation attributes, as well as the broader historical record of human habitation in the Lake Tanganyika region. This study also highlights the need for both modern pollen transect data from the region and comparative cores from low elevation swamps or ponds (wetlands) in the region with smaller catchment areas.     

Multi-electrode resistivity survey for groundwater exploration in the Harare greenstone belt, Zimbabwe

A multi-electrode resistivity survey, carried out over metasedimentary strata and metavolcanics in the Harare greenstone belt in northeastern Zimbabwe as part of a groundwater resources investigation, illustrates the ability of this technique to produce high-resolution images of the subsurface, which are useful for groundwater resources assessment. The resistivity results provide a clear view of the thickness of the weathered regolith and of the distribution of the various lithological units. Using a combination of apparent formation resistivity and inferred depth of weathering, it is possible to characterize the various lithologies on the geophysical profiles. These assigned lithologies show excellent correlation with the mapped geology, and the main lithologies, metabasalt, meta-arenite, granodiorite and banded iron formation can be clearly identified. The banded iron formation is characterized by low resistivity values, while a combination of the depth of weathering and resistivity values are used to distinguish between the meta-arenite on one hand and the metabasalt and granodiorite on the other. The multi-electrode method is successful in identifying potentially favourable zones for obtaining groundwater, such as areas with a maximum depth of weathered regolith, zones of fracturing and faulting, and high porosity and permeability zones associated with lithological contacts.

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Resumen Un estudio de resistividad multi-electrodo que se llevó a cabo en estratos meta sedimentarios y metavolcánicos en el cinturón de rocas verdes de Harare, en la parte noreste de Zimbabwe, como parte de una investigación de recursos de agua subterránea, ilustra la capacidad de esta técnica para producir imágenes de alta resolución de la subsuperficie, las cuales son útiles para la evaluación de los recursos da agua subterránea. Los resultados de resistividad suministran una visión clara el espesor del regolito meteorizado y de la distribución de varias unidades litológicas. Mediante el uso de una combinación de resistividad aparente de formación y de una profundidad inferida de meteorización, es posible caracterizar las diferentes litologías en los perfiles geofísicos. Estas litologías asignadas muestran una excelente correlación con la cartografía geológica y se pueden identificar las litologías predominantes como metabasalto, meta-arenita, granodiorita y formación de hierro bandeado. Esta última se caracteriza por valores bajos de resistividad, mientras que se utiliza una combinación de profundidad de meteorización y valores de resistividad, para distinguir entre meta-arenita por un lado y metabasalto y granodiorita por el otro. El método multi-electrodo es exitoso para identificar zonas potencialmente favorables para captar agua subterránea, las cuales pueden ser áreas con una profundidad máxima de regolito meteorizado, o bien zonas de fracturamiento y fallamiento, o también zonas de porosidad y permeabilidad altas asociadas con contactos litológicos.

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Résumé La prospection électrique par la méthode de multiélectrodes, effectuée pour linvestigation des eaux souterraines cantonnés dans des roches métamorphiques dorigine sédimentaire et volcanique de la ceinture de Harare-Zimbabwe a mis en évidence les possibilités de cette technique de réaliser des images à grande résolution du sous-sol qui sont très utiles pour lévaluation de la ressource en eaux souterraines. Daprès la distribution de la résistance il résulte une image très claire de lépaisseur des regolithes altérés ainsi que de la distribution des différentes unités lithologiques. Daprès les profiles géophysiques on peut caractériser les différents lithologies en utilisant les résistivités apparentes de la formation respective et les informations sur la profondeur de la zone altérée. Les lithologies ainsi déterminées montrent une excellente corrélation avec les cartes géologiques et on peut très bien identifier les lithologies principales comme les metabasaltes et les meta-arenites, les granodiorites et les formations de fer rubanées. Cettes dernières sont caractérisées par des faibles valeurs de la résistivité, tandis que en utilisant les résistivité et la profondeur de la zone altérée on peut distinguer les meta-arenites de granodiorites et des metabasaltes. La méthode des multiélectrodes est donc capable didentifier des formations favorables à laccumulation en eau comme les zones de faille et des fractures, ainsi que les zones à grande porosité et perméabilité, associées aux contactes lithologiques.

     

William Smith's map brought alive by digital remastering

The geological mapping carried out by William Smith, which resulted in the publication of his famous map in 1815, was remarkable in many respects, not least because it relied on him being able to make consistent and accurate observations on the rock types he encountered during his fieldwork. This ability, gained from his many years studying rocks, allowed him to observe features with his own eyes (or at the very least, with the aid of a simple magnifying device) that others could not. We take a new look at William Smith's original stratigraphical sequences, and with samples collected from his classic field areas (many of which are around the city of Bath, Somerset, UK), demonstrate how spatial mineralogy mapping can be incorporated into the modern age of digital mapping.     

Taming a “chaotic concept”: gentrification and segmented consumption in Brooklyn, 2002–2012

Public debate and prior scholarship tend to emphasize the link between gentrification and high-end chain retail, underscoring the importance of taste cultures tied to social class in making sense of gentrification’s impact on neighborhood identity. In this study, we present evidence from 10 years of change in the businesses of Brooklyn, New York City, a period of extensive gentrification across a wide variety of neighborhood and census-tract level contexts. Adopting census tracts clustered in neighborhoods as the units of analysis, we model the effects of institutional and demographic change on two separate outcomes: chain retail density and homogeneity in the types of goods and services available. We argue that changes in consumer culture embedded in broader processes of gentrification are neither “chaotic” nor “unitary” but are “segmented” according to local spatial and demographic context, taking two discrete forms: institutionally facilitated corporatization; lifestyle-driven homogenization.     

A novel index of susceptibility of rivers and their catchments to acidification in regions subject to a maritime influence

A simple, unifying approach to classifying quantitatively the susceptibility of catchment soils and surface waters to acidification is suggested. In areas subject to a strong maritime influence, such as the UK and substantial parts of NW Europe, wherever soil mineral weathering rates are low and soils are unfertilised, atmospherically derived base cations of maritime origins have a greater effect than those derived from biogeochemical weathering on the exchangeable soil base cations. This is directly reflected in the relative base cation concentrations of the associated drainage waters, which become increasingly Na-dominated. Using 10 sub-catchments of the River Dee in north-eastern Scotland, it is shown here that the extent of Na dominance, the ratio of Na⁺ to ΣNa⁺+Ca²⁺+Mg²⁺, at any point in a river provides a quantitative index of the upstream weathering rate and thus of the susceptibility of the river concerned to acidification under diverse flow conditions. Data from a further 58 sub-catchments from the same river system, and from 4 other catchments from around Scotland, were used to validate this theory.