Pressure-induced incipient amorphization of α-quartz and transition to coesite in an eclogite from Antarctica: a first record and some consequences

Monocrystalline quartz inclusions in garnet and omphacite from various eclogite samples from the Lanterman Range (Northern Victoria Land, Antarctica) have been investigated by cathodoluminescence (CL), Raman spectroscopy and imaging, and in situ X‐ray (XR) microdiffraction using the synchrotron. A few inclusions, with a clear‐to‐opalescent lustre, show ‘anomalous’ Raman spectra characterized by weak α‐quartz modes, the broadening of the main α‐quartz peak at 465 cm^?1, and additional vibrations at 480–485, 520–523 and 608 cm^?1. CL and Raman imaging indicate that this ‘anomalous’α‐quartz occurs as relicts within ordinary α‐quartz, and that it was preserved in the internal parts of small quartz inclusions. XR diffraction circular patterns display irregular and broad α‐quartz spots, some of which show an anomalous d‐spacing tightening of ～2%. They also show some very weak, hazy clouds that have d‐spacing compatible with coesite but not with α‐quartz. Raman spectrometry and XR microdiffraction characterize the anomalies with respect to α‐quartz as (i) a pressure‐induced disordering and incipient amorphization, mainly revealed by the 480–485 and 608‐cm^?1 Raman bands, together with (ii) a lattice densification, evidenced by d‐spacing tightening; (iii) the cryptic development of coesite, 520–523 cm^?1 being the main Raman peak of coesite and (iv) Brazil micro‐twinning. This ‘anomalous’α‐quartz represents the first example of pressure‐induced incipient amorphization of a metastable phase in a crustal rock. This issue is really surprising because pressure‐induced amorphization of metastable α‐quartz, observed in impactites and known to occur between 15 and 32 GPa during ultrahigh‐pressure (UHP) experiments at room temperature, is in principle irrelevant under normal geological P–T conditions. A shock (due to a seism?) or a local overpressure at the inclusion scale (due to expansion mismatch between quartz and its host mineral) seem the only geological mechanisms that can produce such incipient amorphization in crustal rocks. This discovery throws new light on the modality of the quartz‐coesite transition and on the pressure regimes (non‐lithostatic v. lithostatic) during high‐pressure/UHP metamorphism. In particular, incipient amorphization of quartz could favour the quartz‐coesite transition, or allow the growth of metastable coesite, as already experimentally observed.     

Old Pulsators: White Dwarfs and Their Immediate Precursors

There are now fully six classes of pulsators among white dwarfsand their immediate precursors among central stars of planetarynebulae and on the extended horizontal branch.In this review, we outline those observational and theoreticalconsiderations that link them together and set them apart fromother kinds of pulsating stars.We summarize some select astrophysical puzzles to which studiesof such pulsators might speak, and we discuss current applicationsin the fields of atomic, nuclear, and neutrino physics.Finally, we suggest how future observing programs might solve somegeneral problems common not only to the white dwarf and pre-whitedwarf pulsators but to many types of variable stars.     

Metamorphic phase relations in orthopyroxene-bearing granitoids: implication for high-pressure metamorphism and prograde melting in the continental crust

In this work, the factors controlling the formation and preservation of high-pressure mineral assemblages in the metamorphosed orthopyroxene-bearing metagranitoids of the Sandmata Complex, Aravalli-Delhi Mobile Belt (ADMB), northwestern India have been modelled. The rocks range in composition from farsundite through quartz mangerite to opdalite, and with varying K₂O, Ca/(Ca + Na)_rock and FeO_tot + MgO contents. A two stage metamorphic evolution has been recorded in these rocks.
An early hydration event stabilized biotite with or without epidote at the expense of magmatic orthopyroxene and plagioclase. Subsequent high-pressure granulite facies metamorphism (∼15 kbar, ∼800 °C) of these hydrated rocks produced two rock types with contrasting mineralogy and textures. In the non-migmatitic metagranitoids, spectacular garnet ± K-feldspar ± quartz corona was formed around reacting biotite, plagioclase, quartz and/or pyroxene. In contrast, biotite ± epidote melting produced migmatites, containing porphyroblastic garnet incongruent solids and leucosomes.
Applying NCKFMASHTO T–M (H₂O) and P–T pseudosection modelling techniques, it is demonstrated that the differential response of these magmatic rocks to high-pressure metamorphism is primarily controlled by the scale of initial hydration. Rocks, which were pervasively hydrated, produced garnetiferous migmatites, while for limited hydration, the same metamorphism formed sub-solidus garnet-bearing coronae. Based on the sequence of mineral assemblage evolution and the mineral compositional zoning features in the two metagranitoids, a clockwise metamorphic P–T path is constrained for the high-pressure metamorphic event. The finding has major implications in formulating geodynamic model of crustal amalgamation in the ADMB.     

LU Vel (GJ 375): A M3.5Ve Flare and Double-Lined Spectroscopic Binary

High resolution echelle spectroscopic observations taken with the FEROS spectrograph at the 2.2 m telescope ESO confirm the binary nature of the flare M3.5V star LU Vel (GJ 375, RE J0958-462) previously reported by Christian and Mathioudakis (2002). Emission of similar intensity from both components is detected in the Balmer, Na i D₁&D₂, He i D₃, Ca ii H&K, and Ca ii IRT lines. We have determined precise radial velocities by cross correlation with radial velocity standard stars, which have allowed us to obtain for the first time the orbital solution of the system. The binary consists of two near-equal M3.5V components with an orbital period shorter than 2 days. We have analyzed the behaviour of the chromospheric activity indicators (variability and possible flares). In addition, we have determined its rotational velocity and kinematics.     

Smeared crack approach: back to the original track

This paper briefly reviews the formulations used over the last 40 years for the solution of problems involving tensile cracking, with both the discrete and the smeared crack approaches. The paper focuses on the smeared approach, identifying as its main drawbacks the observed mesh‐size and mesh‐bias spurious dependence when the method is applied ‘straightly’. A simple isotropic local damage constitutive model is considered, and the (exponential) softening modulus is regularized according to the material fracture energy and the element size. The continuum and discrete mechanical problems corresponding to both the weak discontinuity (smeared cracks) and the strong discontinuity (discrete cracks) approaches are analysed and the question of propagation of the strain localization band (crack) is identified as the main difficulty to be overcome in the numerical procedure. A tracking technique is used to ensure stability of the solution, attaining the necessary convergence properties of the corresponding discrete finite element formulation. Numerical examples show that the formulation derived is stable and remarkably robust. As a consequence, the results obtained do not suffer from spurious mesh‐size or mesh‐bias dependence, comparing very favourably with those obtained with other fracture and continuum mechanics approaches. Copyright © 2006 John Wiley & Sons, Ltd.     

On the orbits and masses of the satellites of the Pluto-Charon system

Two small satellites of Pluto, S/2005 P1 (hereafter P1) and S/2005 P2 (hereafter P2), have recently been discovered outside the orbit of Charon, and their orbits are nearly circular and nearly coplanar with that of Charon. Because the mass ratio of Charon-Pluto is ∼0.1, the orbits of P2 and P1 are significantly non-Keplerian even if P2 and P1 have negligible masses. We present an analytic theory, with P2 and P1 treated as test particles, which shows that the motion can be represented by the superposition of the circular motion of a guiding center, the forced oscillations due to the non-axisymmetric components of the potential rotating at the mean motion of Pluto-Charon, the epicyclic motion, and the vertical motion. The analytic theory shows that the azimuthal periods of P2 and P1 are shorter than the Keplerian orbital periods, and this deviation from Kepler's third law is already detected in the unperturbed Keplerian fit of Buie and coworkers. In this analytic theory, the periapse and ascending node of each of the small satellites precess at nearly equal rates in opposite directions. From direct numerical orbit integrations, we show the increasing influence of the proximity of P2 and P1 to the 3:2 mean-motion commensurability on their orbital motion as their masses increase within the ranges allowed by the albedo uncertainties. If the geometric albedos of P2 and P1 are high and of order of that of Charon, the masses of P2 and P1 are sufficiently low that their orbits are well described by the analytic theory. The variation in the orbital radius of P2 due to the forced oscillations is comparable in magnitude to that due to the best-fit Keplerian eccentricity, and there is at present no evidence that P2 has any significant epicyclic eccentricity. However, the orbit of P1 has a significant epicyclic eccentricity, and the prograde precession of its longitude of periapse with a period of 5300 days should be easily detectable. If the albedos of P2 and P1 are as low as that of comets, the large inferred masses induce significant short-term variations in the epicyclic eccentricities and/or periapse longitudes on the 400-500-day timescales due to the proximity to the 3:2 commensurability. In fact, for the maximum inferred masses, P2 and P1 may be in the 3:2 mean-motion resonance, with the resonance variable involving the periapse longitude of P1 librating. Observations that sample the orbits of P2 and P1 well on the 400-500-day timescales should provide strong constraints on the masses of P2 and P1 in the near future.