Correlation between CME and Flare Parameters (with and without Type II Bursts)

CMEs and flares are the two energetic phenomena on the Sun responsible for generating shocks. Our main aim is to study the relation between the physical properties of CMEs and flares associated with and without type II radio bursts. We considered a set of 290 SOHO/LASCO CMEs associated with GOES X-ray flares observed during the period from January 1997 to December 2000. The relationship between the flares and CMEs is examined for the two sets i) with metric-type IIs and ii) without metric-type IIs. Physical properties such as rise time, duration, and strength of the flares and width, speed, and acceleration of CMEs are considered. We examined the energy relationship and temporal relationship between the CMEs and flares. First, all the events in each group were considered, and then the limb events in each group were considered separately. While there is a relationship between the temporal characteristics of flares and CME properties in the case of with-type IIs, it is absent in the case of all without-type IIs. Among all the relations studied, the correlation between flare duration and CME properties is found to be highly significant compared to the other relations. Also, the relationship between flare strength and CME speed found in the with-type II events is absent in the case of all without-type II events. However, when the limb without-type II events (with reduced time window between flare and CME) are studied separately, we found the energy relationship and the temporal relationship.     

Incorporation of Heavy Metals Bioavailability into Risk Characterization

The bioavailability of field‐aged Cd and Cu was calculated, and compared to the total concentrations determined by acid digestion. Only 0.60–4.15% for Cd and 0.59–9.43% for Cu were found to be bioavailable when determined by stomach‐phase extraction. The incorporation of bioavailability reduced more than 90% of the calculated risk of the metals at the site of study. It should be noted that such a reduction may not be generalized and the site‐specific bioavailability needs to be determined case by case.     

Hydrochemistry of the Amur River: Weathering in a Northern Temperate Basin

We report the dissolved major element, organic carbon, and δ¹³C_DOC, δ¹³C_POC, δD, δ¹⁸O, and ⁸⁷Sr/⁸⁶Sr composition of 19 summer samples from the Amur River. The Amur transported 2.6 Tg C/year of total organic carbon to the Sea of Okhotsk. The physical weathering rate (PWR) based on suspended particulate material was 13 (1.4–14) tons/(km² year), and the chemical weathering rate based on total dissolved solids was 7 (4.3–46) tons/(km² year). We further quantified the sources of the dissolved cations using an inverse model: rain accounted for 2 (0.6–5)%, evaporite 3 (0.7–7)%, carbonate 51 (29–74)%, and silicate 45 (25–64)%. The silicate weathering rate (SWR) in the Amur basin was 23 (15–98) × 10³ mol/(km² year) or 0.67 (0.40–2.81) tons/(km² year), comparable to those of the Siberian rivers and the Mackenzie at higher latitudes. The SWR of the Amur was negatively correlated with elevation and relief, and positively correlated with runoff.     

The first peak ground motion attenuation relationships for North of Vietnam

The first attenuation relationships of peak ground acceleration (PGA) and peak ground velocity (PGV) for northern Vietnam are obtained in this study. Ground motion data are collected by a portable broadband seismic network in northern Vietnam as a part of cooperation between the Institute of Geophysics, Vietnamese Academy of Science and Technology, Vietnam and Institute of Earth Sciences, Academia Sinica, Taiwan. The database comprises a total of 330 amplitude records by 14 broadband stations from 53 shallow earthquakes, which were occurred in and around northern Vietnam in the period between 01/2006 and 12/2009. These earthquakes are of local magnitudes between 1.6 and 4.6, focal depths less than 30 km, and epicentral distances less than 500 km. The new attenuation relationships for PGA and PGV are:

log₁₀(PGA)=-0.987+0.7521M_L-log₁₀(R)-0.00475R,     

Long-term simulations of the sulfur concentrations over the China, Japan and Korea: A model comparison study

Three comprehensive acid deposition models were used to simulate the sulfur concentrations over northeast Asia over the period covering entire year of 2002, and discussed the aggregated uncertainties and discrepancies of the three models. The participating models are from the countries participating in the project of Longrange Transboundary Air Pollutants in Northeast Asia (LTP): China, Japan and Korea. The Eulerian Model-3/CMAQ (by China), Regional Air Quality Model (RAQM, by Japan), and Comprehensive Acid Deposition Model (CADM, by Korea) were employed by each country with common emissions data established by the administrative agencies of China, Japan and Korea. The episodic simulation results between 1 to 15, March 2002 are also presented, during which aircraft measurements were carried out over the Yellow sea. The episodic results show both a wide short-term variability in simulations against measurements, and maximum concentration differences of 3～5 times among the three models, requiring that further attention before confidence among the three models can be claimed for short-term simulations. However, the year-long cumulative simulations showed almost the same general features, with lower aggregated uncertainties between the three models, produced by the long term integration over northeast Asia.     

Effect of highly pervious geological features on ground-water flow into a tunnel

Current practice for estimating water inflow rate relies mostly on analytical solutions which assume a homogeneous, isotropic porous medium around a tunnel. Field measurements indicate that current engineering practice does not consistently make adequate estimate of ground-water flow into a tunnel during excavation due to various factors that analytical solutions do not properly take into account. Among the various factors affecting ground-water flow, the significance of a highly pervious feature located near the tunnel is discussed in this research. The highly pervious feature, which is located near an underground opening and connected to a large source of water, can provide a path for relatively high-head water to the joints intersecting the opening. This paper describes the influence of a highly pervious feature on the ground-water flow regime around a tunnel and the change of inflow rate as the tunnel approaches a highly pervious feature.     

Adsorption of Cu(II) to Bacillus subtilis: A pH-dependent EXAFS and thermodynamic modelling study

Bacteria are very efficient sorbents of trace metals, and their abundance in a wide variety of natural aqueous systems means biosorption plays an important role in the biogeochemical cycling of many elements. We measured the adsorption of Cu(II) to Bacillus subtilis as a function of pH and surface loading. Adsorption edge and XAS experiments were performed at high bacteria-to-metal ratio, analogous to Cu uptake in natural geologic and aqueous environments. We report significant Cu adsorption to B. subtilis across the entire pH range studied (pH ∼2-7), with adsorption increasing with pH to a maximum at pH ∼6. We determine directly for the first time that Cu adsorbs to B. subtilis as a (CuO₅H_n)ⁿ⁻⁸ monodentate, inner-sphere surface complex involving carboxyl surface functional groups. This Cu-carboxyl complex is able to account for the observed Cu adsorption across the entire pH range studied. Having determined the molecular adsorption mechanism of Cu to B. subtilis, we have developed a new thermodynamic surface complexation model for Cu adsorption that is informed by and consistent with EXAFS results. We model the surface electrostatics using the 1pK basic Stern approximation. We fit our adsorption data to the formation of a monodentate, inner-sphere RCOOCu⁺ surface complex. In agreement with previous studies, this work indicates that in order to accurately predict the fate and mobility of Cu in complex biogeochemical systems, we must incorporate the formation of Cu-bacteria surface complexes in reactive transport models. To this end, this work recommends log K RCOOCu⁺ = 7.13 for geologic and aqueous systems with generally high B. subtilis-to-metal ratio.     

<Emphasis Type="Italic">Cochlodinium polykrikoides</Emphasis> red tide detection in the South Sea of Korea using spectral classification of MODIS data

To distinguish true red tide water (particularly Cochlodinium polykrikoides blooms) from non-red tide water (false satellite high chlorophyll water) in the South Sea of Korea, we developed a systematic classification method using spectral information from MODIS level products and applied it to five different harmful algal bloom events. Red tide and nonred tide waters were classified based on four different criteria. The first step revealed that the radiance peaks of potential red tide water occurred at 555 and 678 nm. The second step separated optically different waters that were influenced by relatively low and high contributions of colored dissolved organic matter (CDOM) (including detritus) to chlorophyll. The third and fourth steps discriminated red tide water from non-red tide water based on the blue-to-green ratio in areas with lower and higher contributions of CDOM to chlorophyll, respectively. After applying the red tide classification (using the four criteria), the spectral response of the red tide water, which is influenced by pigment concentration, showed different slopes for the blue and green bands (lower slope at blue bands and higher slope at green bands). The opposite result was found for non-red tide water, due to decreasing phytoplankton absorption and increasing detritus/CDOM absorption at blue bands. The results were well matched with the discoloration of water (blue to dark red/brown) and delineated the areal coverage of C. polykrikoides blooms, revealing the nature of spatial and temporal variations in red tides. This simple spectral classification method led to increase user accuracy for C. polykrikoides and non-red tide blooms (>46% and >97%) and provided a more reliable and robust identification of red tides over a wide range of oceanic environments than was possible using chlorophyll a concentration, chlorophyll anomaly, fluorescence analysis, or proposed red tide detection algorithms.     

Immobilization of As and Pb in contaminated sediments using waste resources

As and Pb-contaminated sediment obtained from the Nakdong Lake and Yeongsan River in the Republic of Korea was stabilized using a combination of calcined oyster shell (COS), waste cow bone (WCB) and coal mine drainage sludge (CMDS). The effectiveness of the stabilization treatment was evaluated using the Korean Standard Test (KST). The KST tests were performed using 1 N HCl extraction fluid for As and 0.1 N HCl extraction fluid for Pb. Scanning electron microscopy–energy dispersive X-ray spectroscopy (SEM–EDX) analyses were performed to investigate the mechanism responsible for As and Pb immobilization upon treatment. The treatment results showed that effective stabilization of As and Pb-contaminated sediment was obtained. Specifically, 10 wt% COS–5 wt% CMDS was the best treatment for As immobilization and 5 wt% COS–5 wt% WCB was the best treatment for Pb immobilization. The COS–WCB treatment outperformed the COS–CMDS treatment in immobilizing Pb in the contaminated sediment. SEM–EDX results indicated that Pb immobilization was strongly associated with Ca, Si, Al and P while As immobilization was strongly associated with Fe and O. Therefore, utilization of COS, WCB and CMDS is beneficial for the stabilization of contaminated sediment.     

Simultaneous stabilization of arsenic, lead, and copper in contaminated soil using mixed waste resources

In the present study, stabilization treatment using waste resource stabilizers was performed for soil contaminated with As and heavy metals (Pb and Cu). Calcined oyster shell (COS) and coal mine drainage sludge (CMDS) were used as a mixed stabilizing agent for a wet-curing duration of 28 days. After the stabilization treatment, the treatment process efficiency was evaluated by the results of various batch- and column-leaching tests. Neutral and weak acid extraction methods, such as water-soluble extraction and SPLP, did not exhibit satisfactory results for heavy metal stabilization, even if they showed very low leachability. On the other hand, TCLP and 0.1 M HCl extraction showed that the stabilizers significantly reduced the amount of heavy metals leached from the soil, which strongly supports the thesis that the stabilization treatment is efficient in the acidic leaching conditions that were explored. Specifically, in the 0.1 M HCl extraction, the reduction efficiencies of As, Pb, and Cu leachings were more than 90 %, compared with control experiments. This study demonstrates that the application of waste resources for the stabilization of As and heavy metals is feasible. However, some limitations observed in the experiments should be considered in future studies, such as the mobilization of alkali-soluble elements, and in particular, exchangeable fractions of Cu. In addition, the treatment efficiency can be evaluated by different leaching methods, which suggests that multidirectional approaches are required for the proper evaluation of stabilization treatment.