Structural properties of Urfa stone doped with erbium oxide

In this study, we investigated the structural properties of Urfa stone (US) doped with erbium oxide (Er₂O₃). Solid US was powdered by using an agate mortar, and its elemental composition was determined using inductive coupling plasma (ICP) methods. Varying amounts of Er₂O₃ (5, 10, 20, 30, and 40%) were added as a dopant to the US powder using mechanical alloying methods. The resultant samples were sintered at 1000 °C for 1 h. The structural properties of the Er₂O₃-doped US samples were subsequently investigated using X-ray diffraction (XRD), Fourier-transform infrared spectrometry (FTIR), and photoluminescence methods. Results from the XRD analysis of the Er₂O₃-doped US powder indicated two crystalline phases: (1) calcium oxide (CaO) or lime and (2) Er₂O₃. After the samples were sintered at 1000 °C, CaO, Er₂O₃, calcium carbonate (CaCO₃), and mixed crystalline phases were observed. Results from the FTIR analysis of the Er₂O₃-doped US samples indicated absorption bands at 711.91, 872.08, and 1396.87 cm^?1 in the spectra. Finally, photoluminescence analysis results indicated a shift in the emission and excitation bands to longer and shorter wavelengths, respectively, in the solid state (non-aqueous media) US-Er complex.     

Chemical composition of rock-forming minerals and crystallization physicochemical conditions of the Middle Eocene I-type Haji Abad pluton,SW Buin-Zahra,Iran

The Haji Abad intrusion is a well-exposed Middle Eocene I-type granodioritc pluton in the Urumieh–Dokhtar magmatic assemblage (UDMA). The major constituents of the investigated rocks are K-feldspar, quartz, plagioclase, pyroxene, and minor Fe–Ti oxide and hornblende. The plagioclase compositions fall in the labradorite, andesine, and oligoclase fields. The amphiboles range in composition from magnesio-hornblende to tremolite–hornblende of the calcic-amphibole group. Most pyroxenes principally plot in the field of diopside. The calculated average pressure of emplacement is 1.9 kbar for the granodioritic rocks, crystallizing at depths of about 6.7 km. The highest pressure estimated from clinopyroxene geobarometry (5 kbar) reflects initial pyroxene crystallization pressure, indicating initial crystallization depth (17.5 km) in the Haji Abad granodiorite. The estimated temperatures using two-feldspar thermometry give an average 724 °C. The calculated average temperature for clinopyroxene crystallization is 1090 °C. The pyroxene temperatures are higher than the estimated temperature by feldspar thermometry, indicating that the pyroxene and feldspar temperatures represent the first and late stages of magmatic crystallization of Haji Abad granodiorite, respectively. Most pyroxenes plot above the line of Fe³⁺?=?0, indicating they crystallized under relatively high oxygen fugacity or oxidized conditions. Furthermore, the results show that the Middle Eocene granitoids crystallized from magmas with H₂O content about 3.2 wt%. The relatively high water content is consistent with the generation environment of HAG rocks in an active continental margin and has allowed the magma to reach shallower crustal levels. The MMEs with ellipsoidal and spherical shapes show igneous microgranular textures and chilled margins, probably indicating the presence of magma mixing. Besides, core to rim compositional oscillations (An and FeO) for the plagioclase crystals serve as robust evidence to support magma mixing. The studied amphiboles and pyroxenes are grouped in the subalkaline fields that are consistent with crystallization from I-type calc-alkaine magma in the subduction environment related to active continental margin. Mineral chemistry data indicate that Haji Abad granodiorites were generated in an orogenic belt related to the volcanic arc setting consistent with the subduction of Neo-Tethyan oceanic crust beneath the central Iranian microcontinent.     

Determining the hard rock groundwater pathway in Golgohar complex formation using hydrochemical data in AHP

Thirty percent of present industrial water consumption of the Golgohar Iron Ore Mine (GIOM) is supplied from a hard rock well (PW-A15) and the rest from 25 wells located in 4 disconnected alluvial aquifers. This well is drilled in the metamorphic complex of Golgohar formation. Attempts have been made to develop extraction of water from other hard rocks existing in the area with no success. Therefore, extensive researches have been carried out to find the pathway, or a provision pathway of water discharged from this well. To study the hydrochemical similarity of this water with other water resources, 122 water samples from an area of 7132 km² were collected from the existing pumping wells, piezometers, mine exploration bore holes, and three salt pans in the vicinity of the area for hydrochemical analysis. The analyses were performed for concentration of major ions and some minor elements. Furthermore, the spatial distribution of ion concentration was plotted in the GIS to delineate the similarity of the PW-A15 water with other water sources and their hydrochemical neighborhood by analytical hierarchy process (AHP). The AHP was performed in two steps: first, iso-concentration maps of seven major ions, eight minor elements, and TDS were used to produce an AHP map (Map1) using weights for different hydrochemical parameters; and second, a similarity index (SI) map was prepared by performing a suggested clustering approach in SPSS using K-means clustering, which was overlaid on Map1 producing Map2. The result of AHP Map2 was then overlaid on the iso-potential map of the sampled locations in GIS software using a mask operator. Therefore, the zones having the most similarity and higher hydraulic potential than PW-A15 were nominated as the zones which possibly could recharge this well, and the groundwater (GW) pathway was proposed. The result of the study method showed to be successful and will be used as a guide for future exploration drillings.     

The measurement of soil gases and shallow temperature for determination of active faults in a geothermal area: a case study from Ömer–Gecek,Afyonkarahisar (West Anatolia)

Afyonkarahisar is a very important geothermal province of western Anatolia and has low and medium enthalpy geothermal areas. This study has been carried out for the preparation of distribution maps of soil gases (radon and carbon dioxide) and shallow soil temperature and the exploration of permeable tectonic regions associated with geothermal systems and reveal the origins of radon and carbon dioxide gases. The western district of the study area is characterized by the high radon concentration (168.30 kBq/m³), carbon dioxide ratio (0.30%), and soil temperature (21.0 °C) values. Fethibey and Demirçevre faults, which allow the circulation of geothermal fluids, have been detected in the distribution maps of radon, carbon dioxide, and shallow depth temperature and the directions of the curves in these maps correspond to the strikes of Demirçevre faults. The effect of the fault plays an important role in the change of carbon dioxide concentration along the W-E directional geological section prepared to determine the change of soil gas and shallow depth temperature values depending on lithological differences, fault existence, and geothermal reservoir depth. On the other hand, it was determined that Rn²²² concentration and soil temperature changed as a function of geothermal reservoir depth or lithological difference. Tuffs in Köprülü volcano-sedimentary units are the main source of radon due to their higher uranium contents. Besides, the carbon dioxide in Ömer–Gecek soils has geothermal origin because of the highest carbon dioxide content (99.3%) in non-condense gas. The similarities in patterns of soil temperature, radon, and carbon dioxide indicate that the variation in soil temperatures is related to radon and carbon dioxide emissions. It is concluded that soil gas and temperature measurements can be used to determine the active faults in the initial stage of geothermal exploration successfully.     

Retrieving of Land Surface Temperature Using Thermal Remote Sensing and GIS Techniques in Kandaihimmat Watershed,Hoshangabad, Madhya Pradesh

Remotely sensed thermal infrared (TIR) data have been widely used to retrieve land surface temperature (LST). LST is an important parameter in the studies of urban thermal environment and dynamics. In the study, an attempt has been made using LANDSAT 8 thermal imagery to compute LST and the associated land cover parameters viz; land surface emissivity (LSE), normalized difference vegetation index (NDVI), normalized difference built-up index (NDBI) and normalized difference water index (NDWI). Landsat 8 TIRS band 10 & 11 (thermal bands) during 21 Oct. 2016, 22 Nov.2016, 24 Dec. 2016 and 09 Jan. 2017 were processed for LST analysis. However, band 5 & band 4 of the imagery was processed for NDVI, band 6 & band 5 for NDBI and band 2 & band 5 for NDWI analysis. LST has been derived from both the bands 10 &11 and validated by in-situ observations on the date and time of satellite overpass from the study area. Band 10 derived LST have shown much temperature difference while comparing with the in-situ observations. However, LST derived from band 11 found similar & close to the in-situ measurements. Relationship between band 11 results and in-situ observed measurements were developed, which has showing a strong correlation with (r² = 0.991). Land surface emissivity were also evaluated which shows variation in different land cover surfaces like vegetation, settlement, forest cover and water body. The study has proven that land surface temperature derived from satellite band 11 is the actual surface temperature of the study area.     

Petrogenesis and tectonic association of rift-related basic Panjal dykes from the northern Indian plate,North-Western Pakistan: evidence of high-Ti basalts analogous to dykes from Tibet

Mineralogy and Petrology - Rift related magmatism during Permian time in the northern margin of Indian plate is represented by basic dykes in several Himalayan terranes including north western...     

Uncertainties in Grout Penetrability Measurements; Evaluation and Comparison of Filter pump,Penetrability Meter and Short Slot

To measure grout penetrability in fractured hard rock, various measuring instruments have been developed over the years. Penetrability meter and Filter pump have been designed to use in both the lab and the field. Short slot has been applicable mainly in the lab due to its complexity. The fact, that these instruments have been built based on different assumptions, limitations, and test conditions, makes their results occasionally in contradict. Deficiency in design of the instruments as well as the methods of evaluating grout penetrability is additionally a basis for uncertainty in results. This study is an experimental effort to determine and thoroughly perceive the nature of the most governing uncertainties in grout penetrability measurements. The test apparatus, procedure, and method used to evaluate the grout penetrability in both Penetrability meter and Filter pump were thus modified. The aim was to control the corresponding uncertainties and make their limitations and test conditions as similar as possible with the ones in Short slot. The results suggested that to obtain a more realistic evaluation of the grout penetrability, measurement should be accomplished at both the high and the low pressures with sufficient grout volume using Short slot. Moreover, application of both Filter pump and Penetrability meter is no longer recommended due to the revealed uncertainties.     

2-D delineation of individual citrus trees from UAV-based dense photogrammetric surface models

One of the challenges of remote sensing and computer vision lies in the three-dimensional (3-D) reconstruction of individual trees by using automated methods through very high-resolution (VHR) data sets. However, a successful and complete 3-D reconstruction relies on precise delineation of the trees in two dimensions. In this paper, we present an original approach to detect and delineate citrus trees using unmanned aerial vehicles based on photogrammetric digital surface models (DSMs). The symmetry of the citrus trees in a DSM is handled by an orientation-based radial symmetry transform which is computed in a unique way. Next, we propose an efficient strategy to accurately build influence regions of each tree, and then we delineate individual citrus trees through active contours by taking into account the influence region of each canopy. We also present two efficient strategies to filter out erroneously detected canopy regions without having any height thresholds. Experiments are carried out on eight test DSMs composed of different types of citrus orchards with varying densities and canopy sizes. Extensive comparisons to the state-of-the-art approaches reveal that our proposed approach provides superior detection and delineation performances through supporting a nice balance between precision and recall measures.     

Missing basics: a study on sanitation and women’s health in urban slums in Lucknow,India

GeoJournal - Sanitation is a multidimensional concept alluding primarily to provision of services for safe disposal of human excreta, provision of clean potable water as well as maintenance of...