Surface complexation modelling of Cd(II), Cu(II), Ni(II), Pb(II) and Zn(II) adsorption onto kaolinite

Proton binding constants for the edge and basal surface sites of kaolinite were determined by batch titration experiments at 25 °C in the presence of 0.1 M, 0.01 M and 0.001 M solutions of NaNO₃ and in the pH range 3-9. By optimizing the results of the titration experiments, the ratio of the edge sites to the basal surface sites was found to be 6:1. The adsorption of Cd(II), Cu(II), Ni(II), Zn(II) and Pb(II) onto kaolinite suspensions was investigated using batch adsorption experiments and results suggested that in the lower pH range the metallic cations were bound through non-specific ion exchange reactions on the permanently charged basal surface sites (X⁻). Adsorption on these sites was greatly affected by ionic strength. With increasing pH, the variable charged edge sites (SOH) became the major adsorption sites and inner-sphere specifically adsorbed monodentate complexes were believed to be formed. The effect of ionic strength on the extent of adsorption of the metals on the variable charged edge sites was much less than those on the permanently charged sites. Two binding constants, log K_(X2Me) and log K_(SOMe), were calculated by optimizing these constants in the computer program FITEQL. A model combining non-specific ion exchange reactions and inner-sphere specific surface complexations was developed to predict the adsorption of heavy metals onto kaolinite in the studied pH range. Linear free energy relationships were found between the edge site binding constants and the first hydrolysis constants of the metals.     

近55年来云南区域性干旱事件的分布特征和变化趋势研究

本文利用一种简化的区域性干旱事件识别方法,对近55年来云南区域性干旱事件进行了识别,在此基础上,选取区域性干旱事件的持续天数、影响站点数、平均强度、累积强度和极端最大强度这5个单一事件评价指标,构建了云南区域性干旱的综合评估模型,确定干旱等级划分标准。进一步分析表明,云南区域性干旱的发生频次、累积强度和累积影响站次均呈现上升趋势;云南在12、1和3月干旱发生最多,7、8月干旱发生最少;干旱持续天数集中在15～45 d,最长的可达222d;云南多发全省性的干旱且旱情偏重。云南中部区域干旱偏多、偏重发生;在严重的干旱事件中,中部型发生频次最多。     

城市小区建筑物和屋顶绿化对小区气象环境影响的数值模拟研究

为了研究城市小区建筑物和屋顶绿化对小区气象环境影响,利用USDSM(城市小区气象与污染扩散数值模式)对杭州市一临钱塘江小区进行敏感性试验。结果表明:(1)小区建筑物的拖曳、阻尼和摩擦作用造成敏感小区内10 m高度平均水平风速减小0.56 m·s-1;对风速的影响范围:迎风向为500 m,背风向为500~600 m,侧风向为200 m,影响高度达到建筑物群平均高度的两倍以上。(2)小区建筑物存在导致低层污染扩散能力减弱,平均污染物浓度达到初始浓度0.01的时间延迟7.6 min。(3)100%的屋顶绿化面积可造成敏感小区平均地表温度下降0.56℃;5 m高度平均气温下降0.70℃;小区平均建筑物高度处气温下降0.94℃。敏感小区内10 m高度平均水平风速增加0.14 m·s-1;小区建筑物下游水平风速显著减小,影响范围达到了600~800 m。     

Types of Organic Fades and Source Rock Assessment of the Coal-Measure Mudstone in the Turpan-Hami Basin

This paper discusses the enviromental characteristics of carbonaceous mudstone and mudstone (coal-measure mudstone in short) of the Early and Middle Jurassic in the Turpan-Hami basin, which were formed in swamps. Through the organic facies study of the coal-measure mudstone in this area, the authors clarify that the flowing-water swamp is the most advanced organic facies belt. Furthermore, according to the practical materials of coal-measure mudstone in the area and with the evaluation criteria of lacustrine mudstone in the past, the authors have established the integrated symbol systems from the abundance of organic matter and the type of organic matter, which can be used in the source rock evaluation of the coal-measure mudstone.     

东营凹陷广饶海相灰岩油藏的勘探与成因机制探讨

山东东营凹陷南部的广饶油藏为一奥陶系灰岩残丘山整带含稠油的大潜山油藏,其埋藏深度为６３４．４￣１５７５．０ｍ,现已探明含油面积３０．７ｋｍ＾２。１９９０年发现一个山头含油,１９９１￣１９９３年发现多个山头含油,１９９６￣１９９７年在各山头之间的部位钻探,结果探明潜山带南部整带含油。地质和地球化学资料分析证实,该油藏不仅是今生储潜山油藏,还是烃类经基岩风化壳运移、聚集而形成的稠油油藏。形成稠油的主要     

Numerical simulation of the impact of urban non-uniformity on precipitation

To evaluate the influence of urban non-uniformity on precipitation, the area of a city was divided into three categories (commercial, high-density residential, and low-density residential) according to the building density data from Landsat satellites. Numerical simulations of three corresponding scenarios (urban non-uniformity, urban uniformity, and non-urban) were performed in Nanjing using the WRF model. The results demonstrate that the existence of the city results in more precipitation, and that urban heterogeneity enhances this phenomenon. For the urban non-uniformity, uniformity, and non-urban experiments, the mean cumulative summer precipitation was 423.09 mm, 407.40 mm, and 389.67 mm, respectively. Urban non-uniformity has a significant effect on the amount of heavy rainfall in summer. The cumulative precipitation from heavy rain in the summer for the three numerical experiments was 278.2 mm, 250.6 mm, and 236.5 mm, respectively. In the nonuniformity experiments, the amount of precipitation between 1500 and 2200 (LST) increased significantly. Furthermore, the adoption of urban non-uniformity into the WRF model could improve the numerical simulation of summer rain and its daily variation.     

福建沿海牛头山玄武岩的铷,锶和稀土元素地球化学

牛头山玄武岩分为亚碱性、过渡性和碱性三类。微量和稀土元素及同位素组成表明它们是活动大陆边缘的钠质玄武岩类。从亚碱性到碱性玄武岩,M值减小,K、Ce、Rb、Sr增加。~(37)Sr/~(36)Sr和1/~(36)Sr相关分析表明本区母岩浆及分离结晶产物均未遭受壳层放射成因锶的混染。定量模拟计算表明本区橄榄拉斑玄武岩母岩浆是上地幔石榴石二辉橄榄岩7％部分熔融的产物。     

人工神经网络的短期气候定性预测方法研究

采用EOF方法将众多具有一定物理意义的环境场预报因子和序列周期因子进行降维去噪处理，并结合人工神经网络前馈网络模型，进行了影响广西热带气旋年频数和夏季(6～8月)降水量短期气候预测的定性预报建模方法研究。结果表明，该方法对于影响广西热带气旋的年频数及广西夏季降水量定性趋势具有很好的预报能力，可作为一种新的短期气候预测业务预报配套方法。     

Microorganisms Linked to Neoproterozoic Microspar Carbonate Sedimentation in the Jilin-Liaoning Area

Molar-tooth carbonate refers to a sort of rock that has ptygmatical folded structure comparable to the ivory. This kind of carbonate exists in a special time range (from Middle to Neoproterozoic). Its origin and the possibility to use it in stratigraphic correlation of the paleocontinent is the key task of the IGCP447, a project on Proterozoic molar tooth carbonates and the evolution of the earth (2001-2005). The importance lies in that the molar-tooth structure is the key to solving problems related to Precambrian biological and global geochemical events. The molar-tooth structure is associated with microorganisms. Development and recession of such carbonates have relations with the evolution process of early lives and abrupt changes in sea carbonate geochemistry. In recent years, based on researches on petrology, geochemistry and Sr isotope of molar-tooth carbonate in the Jilin-Liaoning and Xuzhou-Huaiyang area, the authors hold that it can be used as a marker for stratigraphic sequence and sedimentary