Estimation of the elastic earth parameters using the SLR LAGEOS 1 and LAGEOS 2 data

We present results for the global elastic parameters (k ₂, k ₃) and (h ₂, l ₂) derived from the analysis of Satellite Laser Ranging (SLR) data. The SLR data for two satellites, LAGEOS 1 and LAGEOS 2, collected over a period of two years, from 1 January 2005 to 1 January 2007, from 18 globally distributed ground stations are analyzed using different approaches. The analysis is performed for the two satellites jointly, and the four elastic parameters are estimated. We carry out a sequential analysis and study the stability of the estimates as a function of the length of the data set used. The adjusted final values for k ₂ (0.3011±0.0001) and k ₃ (0.0896±0.0037) and those for h ₂ (0.6146±0.0006) and l ₂ (0.0883±0.0003) for LAGEOS 1 and LAGEOS 2 tracking data are compared to the estimates derived in other studies.     

The evolution of legal instruments and the sustainability of the Peruvian anchovy fishery

Landings statistics of the Peruvian anchovy fishery show that the fishery went through a phase of explosive and uncontrolled growth from its establishment in the mid-fifties until its collapse in 1972. After the collapse, a second phase from 1973 to 1984 was characterized by unfavorable warm ocean conditions and low catches. A third phase, from 1984 to the present, with propitious ocean-environmental conditions and modern governance, can be further divided into a controlled growth period (1985-1994) and a sustainable landings' period (1995 to present). The most recent period of the third phase has enabled the fishery to maintain its catches and be labeled as one of the most sustainable fisheries worldwide. This article highlights the evolution of the legal system that provides for the current sustainable landings and governance of this fishery. Results show that General Fisheries Acts were enacted independently of failures to sustain anchovy landings. The three Peruvian Fisheries Acts were a reflection of broader national socio-political changes and were enacted mainly to define the role of the state and private investment and to delimit foreign involvement in the fishery industry. By contrast, the enactment of secondary legislation to control quotas and fishing seasons increased as the fishery moved towards stable landings. During this phase, enacted secondary legislation showed also a clear peak during strong positive sea surface anomalies driven by the El Niño Southern Oscillation (ENSO) 1997-1998, providing evidence of rapid adaptive management. The role of Fisheries Acts in defining access rights at the national level from a multilevel governance approach is discussed and further key elements that contributed to the transition towards sustainability are suggested.     

Point defects and pre-dose requirements for sensitization of the 300°C TL peak in natural quartz

This paper discusses the structural features required to stimulate a strong thermoluminescence (TL) glow peak near 300°C in clear natural quartz. For that reason, fresh TL data taken from several specimens prepared from five single crystals with known impurity content are shown. The TL emission was measured with a test dose of 10 mGy of γ-rays in the readout intervals 50–160 and 160–320°C. The readings were carried out prior and after the administration of a pre-dose of 175 kGy of γ-rays followed by heat-treatments at 400°C. For each single specimen, the OH content and the population of inclusions were evaluated by infrared spectroscopy and optical microscopy, respectively. The darkening induced by high γ dose was evaluated by optical spectroscopy. It was observed that the absorption at 475 nm and TL responses decrease with increase of the OH. It was shown that both smoky darkening and TL signals were better explained in terms of Li/Al and Li/OH content ratios rather than the absolute values of aluminum and alkali concentrations. The sensitization with high γ dose and heating is essential to create and stabilize a class of defects sites with Li⁺ ions dislodged from [AlO₄/Li]⁰ and Li-dependent OH centers. It is suggested that the defect sites formed with Li⁺ act as electron traps during test dose irradiation, whereas electron-hole recombination occurs essentially at [AlO₄]⁰ centers during the TL output near 300°C.     

Quality and Possibilities of Use of Stabilized Sludge Compost Obtained by Inoculation with Geocell‐1 Consortium

Anaerobically stabilized sludge from wastewater treatment is always a challenge from the environmental aspect of management. The agrarian environmental surroundings present a possibility for swift and efficient utilization of compost from anaerobically stabilized sludge in order to increase the quality of the biological product. With intensification of the composting procedure by means of the microbiological consortium Geocell‐1 (Cellvibrio sp., Pseudomonas fluorescens with the addition of micro‐ and macro‐elements), the results show that the compost obtained from stabilized sludge after inoculation is significantly improved in terms of moisture reduction (39–43%), while in the control compost, this value is significantly higher with 61%. The results of the pathogenic effect show a significant reduction in the number of fecal coliform (<1 × 10³) and Enterococcus bacteria (<1 × 10⁴) in the inoculated (treated) compost. With a slight decrease in the concentration of limiting factors such as As, Cd, Cu, a quality biological product can be achieved, which can be safely deposited on soil. The phytotoxicological germination test with white mustard (Sinapis alba) shows a higher number of sprouting plants with a mixture of treated compost and standard soil for flowers 1:1 and 1:4 compared to the control group.     

Seasonality of the submesoscale dynamics in the Gulf Stream region

Frontogenesis and frontal instabilities in the mixed layer are known to be important processes in the formation of submesoscale features. We study the seasonality of such processes in the Gulf Stream (GS) region. To approach this problem, a realistic simulation with the Hybrid Coordinate Ocean Model is integrated for 18 months at two horizontal resolutions: a high-resolution (1/48°) simulation able to resolve part of the submesoscale regime and the full range of mesoscale dynamics, and a coarser resolution (1/12°) case, in which submesoscales are not resolved. Results provide an insight into submesoscale dynamics in the complex GS region. A clear seasonal cycle is observed, with submesoscale features mostly present during winter. The submesoscale field is quantitatively characterized in terms of deviation from geostrophy and 2D dynamics. The limiting and controlling factor in the occurrence of submesoscales appears to be the depth of the mixed layer, which controls the reservoir of available potential energy available at the mesoscale fronts that are present most of the year. Atmospheric forcings are the main energy source behind submesoscale formation, but mostly indirectly through mixed layer deepening. The mixed layer instability scaling suggested in the (Fox-Kemper et al., J Phys Oceanogr 38:1145–1165, 2008) parametrization appears to hold, indicating that the parametrization is appropriate even in this complex and mesoscale dominated area.     

Fen ecosystem responses to water‐level fluctuations during the early and middle Holocene in central Europe: a case study from Wilczków,Poland

This paper presents a palaeoenvironmental reconstruction of the Wilczków fen (central Poland). The fen developed in an inactive valley at the onset of the Holocene (~11 ka BP) and peat accumulation lasted until 5.7 ka BP. Multi‐proxy reconstructions were made on the basis of palaeobotanical, cladoceran, chironomid, beetle and geochemical analyses. A Kohonen self‐organizing map (SOM, unsupervised artificial neural network) of the biotic sequence distinguished four stages of fen history. Stage X₁ (11.0–10.7 ka BP) was relatively wet and cool. Organic matter started to accumulate but the habitat conditions remained unstable. Moss, sedge and fern communities then developed. Sedimentary changes reveal an intensive groundwater supply at that time. Numerous and diverse chironomid and cladoceran subfossils indicate nearly permanent aquatic conditions. During stage Y₁ (10.6–9.2 ka BP) conditions were dry and the upper peat layer desiccated. Cladocera nearly disappeared whereas chironomids were represented by semi‐terrestrial and predatory (Tanypodinae) species. Conditions started to be more reducing. All the remaining samples belonged to the interweaving stages X₂ and Y₂. Stage Y₂ (mostly 9.1–7.3 and 6.0–5.7 ka BP) was also dry but humidity increased towards the top. Oxidizing conditions occurred and the pH became more alkaline, favouring Cladium mariscus. The basin received mostly allochthonous matter input at that time. Stage X₂ (mostly 6.8–6.1 ka BP) was humid and warm. The groundwater supply remained low but there was an increase in precipitation, changing local conditions to ombrotrophic. Species‐rich chironomid and cladoceran communities were associated with temporary pools. Finally, conditions returned to those characteristic of stage Y₂. The presented reconstruction documents long‐term abiotic and biotic changes determined by water supply, including groundwater outflow, which have rarely been detected at a multi‐proxy scale. We show that inactivated valley fens are sensitive to climate‐driven hydrological fluctuations. Kohonen neural networks appear to be a promising method for analysing variability in multi‐proxy data.     

An insight into the unrest phenomena at the Campi Flegrei caldera from Vp and Vp/Vs tomography

High resolution Vp and Vp/Vs tomography of the Campi Flegrei caldera is obtained using active and passive seismic data. We find a continuous ring of high Vp anomaly that defines the caldera rim associated to the last collapse. A sharp Vp/Vs decrease is observed between 2 and 4 km depth, suggesting the absence of magmatic fluids and the presence of rock volumes with over‐pressured gas within the source region of uplift. Atmospheric water penetrating within the caldera and deep CO₂ fluids are presumably heated by a magmatic body located at depth greater than 4 km nested within the limestone layer. Along the fractures bordering the shallow high Vp rim, deep gas and CO₂ fluids up‐raise and are released in the Pozzuoli solfatara. We hypothesize that the past unrest episode is more likely due to pressure changes within the shallow geothermal reservoir located at the top of the magma intrusion.     

Mössbauer milliprobe studies of small mineral samples with a silicon drift detector

Analysis of ⁵⁷Fe transmission Mössbauer spectra collected on a system where the proportional counter has been replaced with a silicon drift detector (SDD) to test milliprobing of mineral samples is described. In the region of the 14.4 keV Mössbauer line the detector has about 70% efficiency and is capable of delivering spectroscopic information with a high energy resolution and high counting rate. Satisfactory results are obtained from a phase analysis of mixtures of olivine and ilmenite in the proportion 97:3, 99:1 wt%, where in the latter case 2.4 μg of Fe³⁺ in the form of hematite was found in the ilmenite. New perovskite-type minerals (Pb_1.33Ba_0.67Fe₂O₅, Pb_1.33Sr_0.67Fe₂O₅ and Pb_1.33Ba_0.33Sr_0.33Fe₂O₅), synthesised by a combustion method, were studied by X-ray diffraction and Mössbauer spectroscopy as well. The advantage of the system with SDD compared to a conventional Mössbauer spectrometer equipped with a proportional counter as a detector is demonstrated for the perovskite samples. The Mössbauer set-up with the silicon drift detector may be successfully used for a wide range of materials containing a negligible amount of iron.     

Kenya's regional ambitions or China's Belt‐and‐Road? News media representations of the Mombasa‐Nairobi Standard Gauge Railway

Kenya's Standard Gauge Railway (SGR), and its construction and financing by China, exemplifies the prominence accorded to mega‐infrastructural projects in contemporary economic development, as well as the dependence this has engendered on external loans. Alongside, multiple geographies intertwine in the SGR which is both a component of China's global ‘Belt and Road Initiative’ (BRI), as well as an East African regional link between coastal Kenya and neighbouring landlocked countries. In most popular and academic analyses, the role of China is emphasized over the SGR's positioning within East Africa. Does this then lead to an undermining of the meanings that are attached to the SGR within Kenya? This article seeks to add Kenyan perspectives to the debate over China's infrastructural loans by examining the range of news media discourses that have emerged around the SGR. Utilizing the theoretical lens of South‐South cooperation and African agency, this study analyzes how material infrastructure becomes meaningful within the context of a political superstructure. For Kenya, this political superstructure is shaped not only by Kenya‐China relations, but also by infrastructural competitions within East Africa, as well as within Kenya itself.     

Mass balance of mercury in the Mediterranean Sea

The Mediterranean Basin is rich in mercury from natural and anthropogenic sources. During an extensive research from 2002–2005, measurements of different mercury forms were carried out in the Mediterranean Sea by the Italian research vessel Urania as a part of the Med Oceanor and MERCYMS projects funded by the EU Framework programme. Further on, transport and fate of mercury forms was simulated in water and air compartments by two different models, and an approximate coupling of both models was performed. The new 3-dimensional model PCFLOW3D was completed with the first version of a biogeochemical module which deals with various mercury species in dissolved and particulate forms. Exchange with the bottom and the atmosphere, methylation, demethylation, reduction and oxidation were taken into account. Based on the integrated hydrodynamic-atmospheric model and results of field measurements the mass balance of total mercury in the Mediterranean Sea was determined in order to estimate main sources and sinks and simulate future trends of mercury contamination in the Mediterranean. The following terms were taken into account: sources of mercury from major rivers and from point sources, exchange with the Atlantic Ocean and the Black Sea, estimated natural sources from geotectonic active areas in the sea, exchange with bottom sediments, and evasion to and deposition from the atmosphere.