Ejecta from impacts at 0.2-2.3 m/s in low gravity

Collisions between planetary ring particles and in some protoplanetary disk environments occur at speeds below 10 m/s. The particles involved in these low-velocity collisions have negligible gravity and may be made of or coated with smaller dust grains and aggregates. We undertook microgravity impact experiments to better understand the dissipation of energy and production of ejecta in these collisions. Here we report the results of impact experiments of solid projectiles into beds of granular material at impact velocities from 0.2 to 2.3 m/s performed under near-weightless conditions on the NASA KC-135 Weightless Wonder V. Impactors of various densities and radii of 1 and 2 cm were launched into targets of quartz sand, JSC-1 lunar regolith simulant, and JSC-Mars-1 martian regolith simulant. Most impacts were at normal or near-normal incidence angles, though some impacts were at oblique angles. Oblique impacts led to much higher ejection velocities and ejecta masses than normal impacts. For normal incidence impacts, characteristic ejecta velocities increase with impactor kinetic energy, KE, as approximately KE^0.5. Ejecta masses could not be measured accurately due to the nature of the experiment, but qualitatively also increased with impactor kinetic energy. Some experiments were near the threshold velocity of 0.2 m/s identified in previous microgravity impact experiments as the minimum velocity needed to produce ejecta [Colwell, J.E., 2003. Icarus 164, 188-196], and the experimental scatter is large at these low speeds in the airplane experiment. A more precise exploration of the transition from low-ejecta-mass impacts to high-ejecta-mass impacts requires a longer and smoother period of reduced gravity. Coefficient of restitution measurements are not possible due to the varying acceleration of the airplane throughout the experiment.     

Physical properties of near-Earth Asteroid (33342) 1998 WT24

During its close Earth approach in 2001, the E-class near-Earth Asteroid (33342) 1998 WT24 was the focus of extensive radar, optical, and thermal infrared observations. We present a physical model of this object, estimated from Arecibo and Goldstone radar images that cover multiple rotations and span over 100° of sky motion. The asteroid has an equivalent diameter of 415±40 m and a diffuse radar scattering law that is identical in both senses of circular polarization, implying a surface that is extremely rough on centimeter-to-decimeter scales. The shape is dominated by three large basins, which may be impact craters or a relic of past dynamical disruption of the object. Analysis of YORP perturbations on WT24's spin state predicts that the asteroid's spin rate is decreasing at a rate of . Simply extrapolating this rate suggests that the asteroid will despin over the next 150 kyr and was spinning at its surface disruption rate 75 kyr ago, but the rotational evolution of WT24 depends on the surface's thermal properties and probably is more complex than a simple spin-down.     

The coating hypothesis for ammonia ice particles in Jupiter: Laboratory experiments and optical modeling

We report laboratory experiments and modeling calculations investigating the effect of a hydrocarbon coating on ammonia ice spectral signatures. Observational evidence and thermochemical models indicate an abundance of ammonia ice clouds in Jupiter's atmosphere. However, spectrally identifiable ammonia ice clouds are found covering less than 1% of Jupiter's atmosphere, notably in areas of strong vertical transport, indicating a short lifetime for the signature of ammonia absorption on condensed ammonia particles [Baines, K.H., Carlson, R.W., Kamp, L.W., 2002. Icarus 159, 74-94]. Current literature has suggested coating of ammonia ice particles by a hydrocarbon haze as a possible explanation for this paradox. The work presented here supports the inference of a coating effect that can alter or suppress ammonia absorption features. In the experiments, thin films of ammonia ices are deposited in a cryogenic apparatus, coated with hydrocarbons, and characterized by reflection-absorption infrared spectroscopy. We have observed the effects on the ammonia ice absorption features near 3 and 9 μm with coverage by thin layers of hydrocarbons. Modeling calculations of these multilayer thin films assist in the interpretation of the experimental results and reveal the important role of optical interference in altering the aforementioned ammonia spectral features. Mie and T-matrix scattering calculations demonstrate analogous effects for ammonia ice particles and investigate the relative effects of ammonia ice particle size, shape, and coating layer thickness on the ice particle spectral signatures.     

IRCS/Subaru observations of water in the inner coma of Comet 73P-B/Schwassmann-Wachmann 3: Spatially resolved rotational temperatures and ortho-para ratios

Comet 73P-B/Schwassmann-Wachmann 3 was observed with IRCS/Subaru at geocentric distance of 0.074 AU on UT 10 May 2006. Multiple H₂O emission lines were detected in non-resonant fluorescence near 2.9 μm. No significant variation in total H₂O production rate was found during the (3 h) duration of our observations. H₂O rotational temperatures and ortho-to-para abundance ratios were measured for several positions in the coma. The temperatures extracted from two different time intervals show very similar spatial distributions. For both, the rotational temperature decreased from ∼110 to ∼90 K as the projected distance from the nucleus increased from ∼5 to ∼30 km. We see no evidence for OPR change in the coma. The H₂O ortho-para ratio is consistent with the statistical equilibrium value (3.0) for all spatially resolved measurements. This implies a nuclear spin temperature higher than ∼45 K.     

‘Box‐Profile’ Ion Implants as Geochemical Reference Materials for Electron Probe Microanalysis and Secondary Ion Mass Spectrometry

Although electron probe microanalysis and secondary ion mass spectrometry are widely used analytical techniques for geochemical and mineralogical applications, metrologically rigorous quantification remains a major challenge for these methods. Secondary ion mass spectrometry (SIMS) in particular is a matrix‐sensitive method, and the use of matrix‐matched reference materials (RMs) is essential to avoid significant analytical bias. A major problem is that the number of available RMs for SIMS is extremely small compared with the needs of analysts. One approach for the production of matrix‐specific RMs is the use of high‐energy ion implantation that introduces a known amount of a selected isotope into a material. We chose the more elaborate way of implanting a so‐called ‘box‐profile’ to generate a quasi‐homogeneous concentration of the implanted isotope in three dimensions, which allows RMs not only to be used for ion beam analysis but also makes them suitable for EPMA. For proof of concept, we used the thoroughly studied mineralogically and chemically ‘simple’ SiO₂ system. We implanted either ⁴⁷Ti or ⁴⁸Ti into synthetic, ultra‐high‐purity silica glass. Several ‘box‐profiles’ with mass fractions between 10 and 1000 μg g^?1 Ti and maximum depths of homogeneous Ti distribution between 200 nm and 3 μm were produced at the Institute of Ion Beam Physics and Materials Research of Helmholtz‐Zentrum Dresden‐Rossendorf. Multiple implantation steps using varying ion energies and ion doses were simulated with Stopping and Range of Ions in Matter (SRIM) software, optimising for the target concentrations, implantation depths and technical limits of the implanter. We characterised several implant test samples having different concentrations and maximum implantation depths by means of SIMS and other analytical techniques. The results show that the implant samples are suitable for use as reference materials for SIMS measurements. The multi‐energy ion implantation technique also appears to be a promising procedure for the production of EPMA‐suitable reference materials.     

Zircon U-Pb-Hf constraints from Gongga Shan granites on young crustal melting in eastern Tibet

The Gongga Shan batholith is a complex granitoid batholith on the eastern margin of the Tibetan Plateau with a long history of magmatism spanning from the Triassic to the Pliocene. Late Miocene-Pliocene units are the youngest exposed crustal melts within the entire Asian plate of the Tibetan Plateau.Here, we present in-situ zircon Hf isotope constraints on their magmatic source, to aid the understanding of how these young melts were formed and how they were exhumed to the surface. Hf isotope signatures of Eocene to Pliocene zircon rims(ε_Hf(t)=-4 to +4), interpreted to have grown during localised crustal melting, are indicative of melting of a Neoproterozoic source region, equivalent to the nearby exposed Kangding Complex. Therefore, we suggest that Neoproterozoic crust underlies this region of the Songpan-Ganze terrane, and sourced the intrusive granites that form the Gongga Shan batholith. Localised young melting of Neoproterozoic lower or middle crust requires localised melt-fertile lithologies. We suggest that such melts may be equivalent to seismic and magnetotelluric low-velocity and high-conductivity zones or "bright spots" imaged across much of the Tibetan Plateau. The lack of widespread exposed melts this age is due either to the lack of melt-fertile rocks in the middle crust, the very low erosion level of the Tibetan plateau, or to a lack of mechanism for exhuming such melts. For Gongga Shan, where some melting is younger than nearby thermochronological ages of low temperature cooling, the exact process and timing of exhumation remains enigmatic, but their location away from the Xianshuihe fault precludes the fault acting as a conduit for the young melts. We suggest that underthrusting of dry granulites of the lower Indian crust(Archaean shield) this far northeast is a plausible mechanism to explain the uplift and exhumation of the eastern Tibetan Plateau.     

William Smith's map brought alive by digital remastering

The geological mapping carried out by William Smith, which resulted in the publication of his famous map in 1815, was remarkable in many respects, not least because it relied on him being able to make consistent and accurate observations on the rock types he encountered during his fieldwork. This ability, gained from his many years studying rocks, allowed him to observe features with his own eyes (or at the very least, with the aid of a simple magnifying device) that others could not. We take a new look at William Smith's original stratigraphical sequences, and with samples collected from his classic field areas (many of which are around the city of Bath, Somerset, UK), demonstrate how spatial mineralogy mapping can be incorporated into the modern age of digital mapping.     

The variation and controls of mean transit times in Australian headwater catchments

Determining mean transit times in headwater catchments is critical for understanding catchment functioning and understanding their responses to changes in landuse or climate. Determining whether mean transit times (MTTs) correlate with drainage density, slope angle, area, or land cover permits a better understanding of the controls on water flow through catchments and allows first-order predictions of MTTs in other catchments to be made. This study assesses whether there are identifiable controls on MTTs determined using ³H in headwater catchments of southeast Australia. Despite MTTs at baseflow varying from a few years to >100 years, it was difficult to predict MTTs using single or groups of readily-measured catchment attributes. The lack of readily-identifiable correlations hampers the prediction of MTTs in adjacent catchments even where these have similar geology, land use, and topography. The long MTTs of the Australian headwater catchments are probably in part due to the catchments having high storage volumes in deeply-weathered regolith, combined with low recharge rates due to high evapotranspiration. However, the difficulty in estimating storage volumes at the catchment scale hampers the use of this parameter to estimate MTTs. The runoff coefficient (the fraction of rainfall exported via the stream) is probably also controlled by evapotranspiration and recharge rates. Correlations between the runoff coefficient and MTTs in individual catchments allow predictions of MTTs in nearby catchments to be made. MTTs are shorter in high rainfall periods as the catchments wet up and shallow water stores are mobilized. Despite the contribution of younger water, the major ion geochemistry in individual catchments commonly does not correlate with MTTs, probably reflecting heterogeneous reactions and varying degrees of evapotranspiration. Documenting MTTs in catchments with high storage volumes and/or low recharge rates elsewhere is important for understanding MTTs in diverse environments.     

Insights into agricultural influences and weathering processes from major ion patterns

Karst areas and their catchments pose a great challenge for protection because fast conduit flow results in low natural attenuation of anthropogenic contaminants. Studies of the hydrochemistry of karst sources and river solutes are an important tool for securing and managing water resources. A study of the geochemical downriver evolution of the Wiesent River and its tributaries, located in a typical karst terrain, revealed unexpected downstream decreases of nitrate with maximum mean values of 30 mg/L at the source to minimum values of 18 mg/L near the river mouth. This trend persisted over the length of the river even though increased agricultural activities are evident in the downstream section of the catchment. This pattern is caused by fertilizer inputs via diffusive and fast conduits flow from karst lithology in the upstream area that may have reached the river's source even from beyond the hydrological catchment boundaries. Further downstream, these influences became diluted by tributary inputs that drain subcatchments dominated by claystone and sandstone lithologies that increased potassium and sulphate concentrations. Our findings indicate that bedrock geology remains the dominant control on the major ion chemistry of the Wiesent River and that agricultural influences are strongest near the headwaters despite increased land use further downstream, due to long‐term storage and accumulation in karst aquifers. This feature may not be unique to the Wiesent River system, as carbonates cover significant portions of the Earth's surface and subsequent work in other river systems could establish whether such patterns are ubiquitous worldwide.     

Calibration of oxygen isotope fractionation and calcite-corundum thermometry in emery at Naxos,Greece

Corundum (Crn), including sapphire, occurs in emery pods surrounded by marble on the island of Naxos, Greece. The emery formed from bauxite deposited in karst that was metamorphosed to 400–700°C at 20–15 Ma. Many of these rocks initially appeared well suited for refractory accessory mineral (RAM) thermometry, which uses oxygen isotope fractionation between a RAM – corundum – and a modally dominant phase with faster diffusion of oxygen – calcite (Cc) – to determine peak metamorphic temperatures. However, previous attempts at oxygen isotope thermometry were confounded by highly variable fractionations (Δ¹⁸O) measured at mm-scale and the uncertain calibration of Δ¹⁸O(Cc-Crn) versus temperature. Secondary ion mass spectrometry (SIMS) permits in situ analysis of δ¹⁸O in corundum and calcite at the 10-μm scale in adjacent grains where textures suggest peak metamorphic equilibrium was attained. SIMS analyses of adjacent mineral pairs in eight rocks yield values of Δ(Cc-Crn) that systematically decrease from 7.2 to 2.9‰ at higher metamorphic grade. Pairing these data with independent temperature estimates from mineral isograds yields an empirical calibration of 1,000 lnα(Cc-Crn) = 2.72 ± 0.3 × 10⁶/T² (T in K). The new fractionations (2.7‰ at 1,000 K) are significantly smaller than those calculated from the modified increment method (6.5‰ at 1,000 K; Zheng, Geochimica et Cosmochimica Acta, 1991, 55:2299–2307; Zheng, Mineral Mag, 1994, 58A:1000–1001), which yield unreasonably high temperatures of 630 to 1,140°C when applied to the new Naxos data. The new calibration of Δ(Cc-Crn) can be combined with published fractionations to calculate A-factors for corundum versus a range of 14 other minerals. These new fractionation factors can be used for thermometry or to constrain the genesis of corundum. A compilation of gem corundum δ¹⁸O values shows that many igneous sapphires, including important deposits of basalt-associated sapphire, are mildly elevated in δ¹⁸O relative to the calculated range in equilibrium with mantle values (4.4–5.7‰) and formed from evolved magmas.