浙江嵊州西白山表土花粉的初步研究

通过对浙江嵊州西白山香榧林、针阔混交林、茶园及竹园16份苔藓的花粉分析，研究其表土花粉与现代植被的关系。结果表明：① 研究区植物孢粉共由50科属组成，以乔木花粉（主要为香榧和马尾松）为优势，含量为71.5%~92.9%，草本花粉次之，含量为5.3%~24.7%，蕨类孢子含量最低，含量为1.5%~7.2%，表土花粉组合基本上反映了该区植被的总体特征；② PCA结果显示，香榧和香榧林均能很好的区分出来，说明其具有很好的分异性；③ 香榧花粉在香榧林的含量较高，平均高达41.1%，但在林外，其含量则迅速降低，为5.2%~9.8%，可见香榧花粉的传播距离非常有限。该结果建议当地层中香榧花粉化石的含量达到10%，就可以初步断定在研究区附近有古香榧林的存在。     

格陵兰海气溶胶光学深度、海冰、浮游植物与二甲基硫的关系及其对未来气候的影响

dimethylsulphide (DMS)的海空通量是海洋生物气溶胶的主要来源之一,对气候（特别是北冰洋的气候）具有重要的辐射影响。利用卫星数据得到的气溶胶光学深度(AOD)作为气溶胶负荷的代表,在夏季和秋季表现的尤其明显。春季海冰的融化是北极气溶胶前体的重要来源。然而,早春的高浓度气溶胶可能与南方大陆污染的平流有关(北极霾)。更高的AOD通常在研究区域的南部出现。海冰浓度(SIC)和AOD呈正相关,而云盖(CLD)和AOD则呈负相关。SIC和CLD的季节性峰值均在AOD峰值的前一个月。AOD与SIC之间存在强烈的正相关关系。融冰与叶绿素（CHL)几乎在3月至9月呈正相关,但与春季和初夏的AOD呈负相关。春季和初夏较高的AOD有可能是由融冰和春季强风在该地区的结合影响。由于春季风的升高和冰的融化,在春季出现了DMS通量的峰值。从3月到五月,DMS浓度和AOD及融冰都呈正相关。早秋季升高的AOD可能与浮游植物合成的生物气溶胶的排放有关。到2100年，格陵兰海的DMS通量将增加3倍以上。生物气溶胶的显著增加可以部分抵消格陵兰海的增温现象。     

A comparative study on the dissolution and solubility of hydroxylapatite and fluorapatite at 25 °C and 45 °C

Dissolution of the synthetic hydroxylapatite (HAP) and fluorapatite (FAP) in pure water was studied at 25 °C and 45 °C in a series of batch experiments. The XRD, FT-IR and SEM analyses indicated that the synthetic, microcrystalline HAP and FAP with apatite structure used in the experiments were found to have no obvious variation after dissolution except that the existence of OH groups in FT-IR spectra for FAP after 2880 h dissolution was observed. During the HAP dissolution (0–4320 h), the aqueous calcium and phosphate concentrations reached the maxima after 120 h and then decreased slowly with time. For the FAP dissolution in pure water, after a transient time of 1440 h (< 60 d), element concentrations and pH became constant suggesting attainment of a steady-state between the solution and solid. During early stages of the FAP dissolution reaction (< 72–120 h), mineral components were released in non-stoichiometric ratios with reacted solution ratios of dissolved Ca:P, Ca:F and P:F being lower than mineral stoichiometric ratios of Ca₅(PO₄)₃F, i.e., 1.67, 5.0 and 3.0, respectively. This indicated that F were preferentially released compared to Ca from the mineral structure. The mean K_sp values were calculated by using PHREEQC for HAP of 10^− 53.28 (10^− 53.02–10^− 53.51) and for FAP of 10^− 55.71 (10^− 55.18–10^− 56.13) at 25 °C, the free energies of formation ΔG_f^o[HAP] and ΔG_f^o[FAP] were calculated to be − 6282.82 kJ/mol and − 6415.87 kJ/mol, respectively.     

长沙城市空间破碎化的格局特征及其影响因素

空间破碎化是城市空间结构研究亟待深化的重要课题。从形态、联系以及功能3个维度构建城市空间破碎化测度指标,并运用地理探测器模型,探讨长沙城市空间破碎化的格局特征及其影响因素。主要结论：① 城市空间破碎化可从形态分割、联系阻隔、功能失序三方面进行测度,形态分割可用平均地块面积指数表征,联系阻隔可用平均阻抗指数刻画,功能失序可用功能多样指数、邻接冲突指数来反映;② 长沙城市空间破碎化呈现圈层式分异为主、扇形扩展分异为辅的格局特征,低破碎化区主要分布在城市核心区,高破碎化区沿着特定的扇面向外围扩展,且主要分布在大型封闭社区、工业园区、山地绿地及大型站场等区域;③ 长沙城市空间破碎化的空间分异是多因素综合作用的结果,其中海拔、坡度等自然因素是基础因素,土地价格、人口密度、设施投入是主导因素;④ 长沙城市空间破碎化治理可从突破市场供给约束、市场需求约束和设施丰度约束三方面着手,采取针对性调控对策,以最大程度地消减空间破碎化带来的负面效应。     

有棘和无棘两种表型栉江珧同工酶差异的比较

采用垂直板聚丙烯酰胺凝胶电泳对有棘和无棘两种不同表型的栉江珧（Ａｔｒｉｎａ ｐｅｃｔｉｎｔａ）的外套膜组织进行了ＥＳＴ 和ＳＯＤ 同工酶比较研究。结果显示这两种类型的酶谱表达有一定差异，但同时也存在中间类型，表明有棘和无棘的表型差异，尚不能提供它们应划分为两个种的充足证据     

Impacts of human interventions on the seasonal and nodal dynamics of the M2 and K1 tidal constituents in Lingdingyang Bay of the Zhujiang River Delta,China

Natural and human-induced changes may exert considerable impacts on the seasonal and nodal dynamics of M₂ and K₁ tidal constituents. Therefore, quantifying the influences of these factors on tidal regime changes is essential for sustainable water resources management in coastal environments. In this study, the enhanced harmonic analysis was applied to extract the seasonal variability of the M₂ and K₁ tidal amplitudes and phases at three gauging stations along Lingdingyang Bay of the Zhujiang River Delta. The seasonal dynamics in terms of tidal wave celerity and amplification/damping rate were used to quantify the impacts of human-induced estuarine morphological alterations on M₂ and K₁ tidal hydrodynamics in inner and outer Lingdingyang Bay. The results show that both tidal amplification/damping rate and wave celerity were considerably increased from the pre-anthropogenic activity period (Pre-AAP) to the post-anthropogenic activity period (Post-AAP) excepting the tidal amplification/damping rate in outer Lingdingyang Bay, and the variations in outer Lingdingyang Bay was larger than those in inner Lingdingyang Bay. The alterations in these two parameters were more significant in flood season than in dry season in both inner and outer Lingdingyang Bay. The seasonal variability of M₂ and K₁ tidal amplitudes were further quantified using a regression model accounting for the 18.61-year lunar nodal modulation, where this study observes a considerable alteration in M₂ constituent owing to human interventions. During the Post-AAP, the M₂ amplitudes at the downstream station were larger than those that would have occurred in the absence of strong human interventions, whereas the opposite was true for the upstream station, leading to a substantial decrease in tidal amplification in outer Lingdingyang Bay. However, it is opposite in inner Lingdingyang Bay. The underlying mechanism can be primarily attributed to channel deepening and narrowing caused by human interventions, that resulted in substantial enlargement of the bay volume and reduced the effective bottom friction, leading to faster wave celerity and stronger amplified waves.     

水泥-水玻璃灌浆在软弱地基中的应用

水泥 水玻璃化学灌浆是把水泥、水玻璃按一定比例混合后形成的，这种浆液注入地基后，能将原松散地层的土粒和裂隙胶结成一个整体（“结石体”），其结构新，强度大，化学稳定性好，能彻底改善软弱地基土的物理和力学性质。水泥 水玻璃化学灌浆不仅具有水泥灌浆的优点，而且兼有化学浆液的一些特点。     

Studies of melt inclusions in some basalts from eastern China

Cenozoic basalts widespread in eastern China constitute an important sector of the circum-Pacific Cenozoic basalt belt. Basalt samples were collected from Wudalianchi (Heilongjiang Province), Nushan (Anhui Province), Fangshan (Jiangsu Province), Zhuji (Zhejiang Province), and Mingxi(Fujian Province). These basalts, for the most part, belong to the alkali basaltic series, and partly to tholeiites. A variety of inclusions commonly occurs in the rock-forming minerals of these basalts. The physicochemical conditions of basalt formation in different areas have been reviewed in special reference to the inclusion data. Our studies have shown that there is a close relationship between the features of the inclusions and the physicochemical conditions of basalt formation, which can, therefore, be regarded as a guide to the mechanism of basaltic petrogenesis. The results of research in this aspect are presented in the present paper.     

江仓矿区巨厚煤层煤种结构与煤种储量计算方法

江仓矿区煤炭资源丰富。主采煤层属巨厚煤层,其煤层结构和煤种结构一般都很复杂,按不同煤种进行分层开采,有利于煤炭资源合理利用。江仓矿区20煤煤种结构变化大,且无规律可循,探讨了分煤种计算储量的几种方法,对未来煤矿的设计与开采有一定的指导意义。     

新疆维宝铅锌矿床地质、流体包裹体和同位素地球化学特征

新疆维宝铅锌矿床位于东昆仑祁漫塔格地区西段,铅锌矿体受地层及岩性控制,多呈层状、似层状赋存于蓟县纪狼牙山组中下部条带状绿帘石（透辉石）矽卡岩中,矿石类型主要为绿帘石-透辉石矽卡岩型铅锌（铜）矿石。矿石矿物主要为方铅矿、闪锌矿、黄铜矿等,脉石矿物主要为透辉石、绿帘石、方解石、绿泥石、石榴子石等。金属硫化物电子探针分析表明,闪锌矿中Fe质量分数为2.206%~2.679%,贫Ga、Ge、Cd,Zn/Cd为143~150,方铅矿中Ag质量分数较低（0.163%~0.210%）,具有与岩浆热液有关的金属硫化物特征。流体包裹体以富气相两相包裹体和富液相两相包裹体为主,均一温度平均值分别为268.2和273.1 ℃,含有CO₂、CH₄、N₂、H₂等成分,成矿流体可能来源于岩浆流体,具中温、高盐度、低密度的特征,成矿过程中发生了不混溶作用。金属硫化物的δ³⁴S_V-CDT为0.49‰~2.41‰,主要来源于岩浆;金属硫化物的²⁰⁶Pb/²⁰⁴Pb为18.254~18.336,²⁰⁷Pb/²⁰⁴Pb为15.556~15.664,²⁰⁸Pb/²⁰⁴Pb为38.060~38.367,主要来源于区内深源岩浆活动,有少量地壳铅的混染。综合分析认为维宝铅锌矿床为与印支期岩浆作用有关的层控矽卡岩型矿床。