Degradation of digested sewage sludge residue under anaerobic conditions for mine tailings remediation

Previous studies showed that 85 % of total organic matter (TOM) in digested sewage sludge (biosolids) used as a sealing layer material over sulfide tailings at the Kristineberg Mine, northern Sweden, had been degraded 8 years after application, resulting in a TOM reduction from 78 to 14 %. To achieve a better understanding of the field observations, laboratory studies were performed to evaluate biodegradation rates of the TOM under anaerobic conditions. Results reveal that the original biosolid consisted of ca. 60 % TOM (48.0 % lignin and 11.8 % carbohydrates) that had not been fully degraded. The incubation experiments proved that 27.8 % TOM in the biosolid was further degraded anaerobically at 20–22 °C during the 230 days’ incubation period, and that a plateau to the biodegradation rate was approached. Based on model results, the degradation constant was found to be 0.0125 (day^?1). The calculated theoretical gas formation potential was ca. 50 % higher than the modeled results based on the average degradation rate. Cumulated H₂S equated to 0.65 μmoL g^?1 of biosolid at 230 days. However, the large sulfurous compounds reservoir (1.76 g SO₄ ^2? kg^?1 biosolid) together with anaerobic conditions can generate high concentrations of this gas over a long-term perspective. Due to the rate of biodegradability identified via anaerobic processes, the function of the biosolid to serve as an effective barrier to inhibit oxygen migration to underlying tailings, may decrease over time. However, a lack of readily degradable organic fractions in the biosolid and a large fraction of organic matter that was recalcitrant to degradation suggest a longer degradation duration, which would prolong the biosolid material’s function and integrity.     

A model of dimethylsulfide dynamics for the subtropical North Atlantic

Dimethylsulfide (DMS) is a volatile sulfur compound produced by the marine biota. The flux of DMS to the atmosphere may act on climate via aerosol formation. It is therefore important to improve our understanding of the processes that regulate sea surface DMS concentrations for eventual inclusion into climate models. In order to simulate the dynamics of DMS concentrations in the mixed layer, a model of DMS production was developed and calibrated against a 1 year time-series of DMS and DMSP (dissolved and particulate) data collected in the Sargasso Sea at Hydrostation ‘S’. The model reproduces the observed divergence between the seasonal cycles of particulate DMSP, the DMS precursor produced by algae, and DMS produced through the microbial loop from the cleavage of dissolved DMSP. DMSP_p (particulate) reaches its maximum in the spring whereas DMSP_d (dissolved) and DMS reach maximum concentrations in summer. Several parameters had to vary seasonally and with depth in order to reproduce the data, pointing out the importance of physiological and structural changes in the plankton food web. These parameters include the intracellular S(DMSp):N ratio, the C:Chl ratio and the sinking rates of phytoplankton and detritus. For the Sargasso Sea, variations in the solar zenithal angle, which co-vary with the seasonal variations in the depth of the mixed layer, proved to be a convenient signal to drive the seasonal variation in the structure and dynamics of the plankton. Variations of the temperature and photosynthetically active radiation also help to reproduce the short-term variability of the annual S cycle. Results from a sensitivity analysis show that variations in DMSP_p are dependent mostly on parameters controlling phytoplankton biomass, whereas DMS is dependent mostly on variables controlling phytoplankton productivity.     

Cosmogenic Be dating of a sackung and its faulted rock glaciers, in the Alps of Savoy (France)

Sackungs are the largest gravitational deformation observed in mountains. They are characterized by the long-term slowness of the movements, but their mechanism is still not well understood. Nowadays cosmic ray exposure (CRE) dating methods allow dating the morphologic structures involved in sackung and can contribute at the understanding of their origin. In the Alps, the 5.3 km long Arcs sackung initiated during the activity of rock glaciers. Three samples from these faulted rock glaciers provide their first CRE ages and show that at 2000 m elevation these block accumulations moved during the Younger Dryas and stopped in early Holocene. Six ¹⁰Be ages of fault scarps show that the Arcs sackung lasted only a few thousand years and stopped at about 8462 ± 432 ¹⁰Be yr. They also reveal that deformation migrated upslope in agreement with a mechanism of flexural toppling of vertical layers. This unique and long gravitational event, characterized by migration of the deformation, does not support earthquake shaking as triggering mechanism for individual faults. It shows that, in the upper Isère valley, slope deformation was delayed of several thousand years after glacial debuttressing, and is not anymore active despite its fresh morphology.     

Limits on the chirality of interstellar and intergalactic space

We raise the question of whether velocities of left and right circularly-polarized photons might be different (for reasons other than the well-known Faraday effect). Such a difference could manifest itself either in the time profiles of pulsed or bursting astronomical sources or in the rotation of the direction of polarization of linearly polarized radiation from them. The existing observations of pulsars, gamma ray bursters, and quasar jets are used to set limits to the difference in speed, between 10^-17and 10^-32     

Thermal reservoir modeling in petroleum geomechanics

Thermal oil recovery processes involve high pressures and temperatures, leading to large volume changes and induced stresses. These cannot be handled by traditional reservoir simulation because it does not consider coupled geomechanics effects. In this paper we present a fully coupled, thermal half‐space model using a hybrid DDFEM method. A finite element method (FEM) solution is adopted for the reservoir and the surrounding thermally affected zone, and a displacement discontinuity method is used for the surrounding elastic, non‐thermal zone. This approach analyzes stress, pressure, temperature and volume change in the reservoir; it also provides stresses and displacements around the reservoir (including transient ground surface movements) in a natural manner without introducing extra spatial discretization outside the FEM zone. To overcome spurious spatial temperature oscillations in the convection‐dominated thermal advection–diffusion problem, we place the transient problem into an advection–diffusion–reaction problem framework, which is then efficiently addressed by a stabilized finite element approach, the subgrid‐scale/gradient subgrid‐scale method. Copyright © 2008 John Wiley & Sons, Ltd.     

Hydrological field data from a modeller's perspective: Part 1. Diagnostic tests for model structure

Hydrological scientists develop perceptual models of the catchments they study, using field measurements and observations to build an understanding of the dominant processes controlling the hydrological response. However, conceptual and numerical models used to simulate catchment behaviour often fail to take advantage of this knowledge. It is common instead to use a pre‐defined model structure which can only be fitted to the catchment via parameter calibration. In this article, we suggest an alternative approach where different sources of field data are used to build a synthesis of dominant hydrological processes and hence provide recommendations for representing those processes in a time‐stepping simulation model. Using analysis of precipitation, flow and soil moisture data, recommendations are made for a comprehensive set of modelling decisions, including Evapotranspiration (ET) parameterization, vertical drainage threshold and behaviour, depth and water holding capacity of the active soil zone, unsaturated and saturated zone model architecture and deep groundwater flow behaviour. The second article in this two‐part series implements those recommendations and tests the capability of different model sub‐components to represent the observed hydrological processes. Copyright © 2010 John Wiley & Sons, Ltd.     

Composition, age, and origin of the ~620?Ma Humr Akarim and Humrat Mukbid A-type granites: no evidence for pre-Neoproterozoic basement in the Eastern Desert, Egypt

The Humr Akarim and Humrat Mukbid plutons, in the central Eastern Desert of Egypt, are late Neoproterozoic post-collisional alkaline A-type granites. Humr Akarim and Humrat Mukbid plutonic rocks consist of subsolvus alkali granites and a subordinate roof facies of albite granite, which hosts greisen and Sn–Mo-mineralized quartz veins; textural and field evidence strongly suggest the presence of late magmatic F-rich fluids. The granites are Si-alkali rich, Mg–Ca–Ti poor with high Rb/Sr (20–123), and low K/Rb (27–65). They are enriched in high field strength elements (e.g., Nb, Ta, Zr, Y, U, Th) and heavy rare earth elements (La _n /Yb _n ?=?0.27–0.95) and exhibit significant tetrad effects in REE patterns. These geochemical attributes indicate that granite trace element distribution was controlled by crystal fractionation as well as interaction with fluorine-rich magmatic fluids. U–Pb SHRIMP zircon dating indicates an age of ~630–620?Ma but with abundant evidence that zircons were affected by late corrosive fluids (e.g., discordance, high common Pb). εNd at 620?Ma ranges from +3.4 to +6.8 (mean?=?+5.0) for Humr Akarim granitic rocks and from +4.8 to +7.5 (mean?=?+5.8) for Humrat Mukbid granitic rocks. Some slightly older zircons (~740?Ma, 703?Ma) may have been inherited from older granites in the region. Our U–Pb zircon data and Nd isotope results indicate a juvenile magma source of Neoproterozoic age like that responsible for forming most other ANS crust and refute previous conclusions that pre-Neoproterozoic continental crust was involved in the generation of the studied granites.     

Cl and Na Fluxes in an Andean Foreland Basin of the Peruvian Amazon: An Anthropogenic Impact Evidence

The dissolved load of the Amazon River is generally considered to be lowly impacted by anthropogenic activities. In this work, based on the chemical and hydrological database of the Environmental Research Observatory—HYBAM (http://www.ore-hybam.org), we explore the importance of the Peruvian Foreland petroleum activity on the dissolved Na and Cl fluxes of the Amazon River. The main result of this study allows us suggesting that oil extraction activity, concentrated in the El Tigre River basin, a small foreland watershed in the Peruvian Amazon, influenced drastically the Na and Cl exportation of the Amazon River during the 2006–2007 period. During these years,  the dissolved exportations of this basin represented almost 20 % of the annual dissolved Cl Amazon flux and almost 12 % of the annual dissolved Na Amazon flux for a mean annual discharge <1 % of the Amazon River discharge. Since the last decades, the anthropogenic activities are increasing over the whole Amazon basin, especially in Andean countries. In this context, our results demonstrate that extractive activity cannot be considered as negligible on the hydro-chemistry of the Amazonian Rivers especially for the weathering budget estimation based on river-dissolved loads. Moreover, Cl and Na can be used to trace the formation waters derived from oil extraction at a large spatial scale. The environmental impacts of contaminants associated with deep water released to the hydrosystem (polycyclic aromatics hydrocarbons, metallic trace elements, etc.) at local and regional scales are still underestimated and should be monitored to map their local and regional influence and to prevent their risks on human health.