A conceptual hydrologic model for a forested Carolina bay depressional wetland on the Coastal Plain of South Carolina,USA

This paper describes how climate influences the hydrology of an ephemeral depressional wetland. Surface water and groundwater elevation data were collected for 7 years in a Coastal Plain watershed in South Carolina USA containing depressional wetlands, known as Carolina bays. Rainfall and temperature data were compared with water‐table well and piezometer data in and around one wetland. Using these data a conceptual model was created that describes the hydrology of the system under wet, dry, and drought conditions. The data suggest this wetland operates as a focal point for groundwater recharge under most climate conditions. During years of below‐normal to normal rainfall the hydraulic gradient indicated the potential for groundwater recharge from the depression, whereas during years of above‐normal rainfall, the hydraulic gradient between the adjacent upland, the wetland margin, and the wetland centre showed the potential for groundwater discharge into the wetland. Using high‐resolution water‐level measurements, this groundwater discharge condition was found to hold true even during individual rainfall events, especially under wet antecedent soil conditions. The dynamic nature of the hydrology in this Carolina bay clearly indicates it is not an isolated system as previously believed, and our groundwater data expand upon previous hydrologic investigations at similar sites which do not account for the role of groundwater in estimating the water budget of such systems. Copyright © 2007 John Wiley & Sons, Ltd.     

Temporal change of characteristics of shallow volcano-tectonic earthquakes associated with increase in volcanic activity at Kuchinoerabujima volcano, Japan

Shallow volcano-tectonic (VT) earthquakes recorded at the Kuchinoerabujima island volcano in southwest Japan are analyzed in order to clarify the role of hydrothermal activity in the development of volcanic seismicity. From analysis of shallow VT earthquakes in 2006, two specific episodes of elevated seismicity are observed in April and November 2006. The VT earthquakes have hypocenters at depths of 0–0.4 km beneath the summit crater, and normal fault focal mechanisms with WNW–ESE extension consistent with the tensional stress field indicated by the alignment of craters and fissures. Although the hypocenters and focal mechanisms are found to be largely invariant during these episodes, the corner frequencies of the VT earthquakes underwent a pronounced increase and decrease accompanying the changes in seismicity rates. The corner frequencies increased to 20–25 Hz approximately one month prior to the onset of elevated seismicity, and then decreased to 10–15 Hz in the period of peak seismicity. The rupture length also decreased at the onset of seismicity, thereafter increasing as the seismicity continued. The peak seismicity in terms of the daily number of VT events was accompanied by inflation around the crater, suggestive of a pressure increase in the volcanic system. It is inferred that the increase in shallow VT seismicity and rupture length is related to the development of a fractured zone. The pressure increase in the volcanic system is attributed to the intrusion of hydrothermal fluids, which is supported by an observed increase in fumarolic temperature and activity. The preceding monochromatic events are thus considered to be generated by the effect of fluid-filled cracks. The shortening of rupture length is then inferred to be related to the closing of non-fluid-filled cracks in the fracture zone under the increasing pressure field, leading to a transition from monochromatic events to low-frequency and shallow VT seismicity.     

HPLC determination of phytoplankton pigments using N,N-dimethylformamide

The suitability of N,N-dimethylformamide (DMF) as an extractant for the standard reverse-phase HPLC method was examined using algal cultures. Good pigment separations and recovery were achieved with 20% (volume %) addition of an ion-pairing solution in an injection. While slight amounts of degradation products of chlorophylla, i.e., chlorophyllidea, allomeric and epimeric forms, were produced, adequate attention to filtration and extraction prevents the formation of degradation products, confining them to an acceptable level. Because of its strong extractability, which expedites the extraction process, DMF is an efficient solvent for HPLC analysis of phytoplankton pigments.     

Characteristic features in Venus’ nightside cloud-top temperature obtained by Akatsuki/LIR

Mid-infrared images of almost the entire Venus nightside hemisphere obtained by the Longwave Infrared Camera (LIR) onboard Akatsuki on December 9 and 10, 2010 reveal that the brightness temperature of the cloud-top ranges from 237 K in the cold polar collars to 243 K in the equatorial region, significantly higher than the values obtained by Venera 15. Other characteristic features of the temperature distributions observed are zonal belt structures seen in the middle and low latitudes and patchy temperature structures or quasi-periodic streaks extending in a north–south direction in the northern middle latitudes and southern low latitudes.     

Characteristics of planetary-scale waves simulated by a new venusian mesosphere and thermosphere general circulation model

We have developed a new general circulation model (GCM) for the venusian mesosphere and thermosphere (80-about 180 km). Our GCM simulations show that winds in the subsolar-to-antisolar direction (SS–AS) are predominant above about 90 km. A weak return flow of the SS–AS is seen below about 90 km. We performed GCM simulations imposing the planetary-scale waves (thermal tides, Rossby wave, and Kelvin wave) at the lower boundary. Although the diurnal and semidiurnal tides are damped below 95 km, the Rossby wave propagates up to around 130 km. However, the amplitude of the Rossby wave is too small (<1 m/s) to affect the general circulation. On the other hand, the Kelvin wave propagates up to about 130 km with a maximum zonal wind fluctuation of approximately 5.9 m/s on average. The amplitude of the Kelvin wave sometimes exceeds 10 m/s around the terminator. The Kelvin wave causes a temporal variation in the wind velocity at the altitude of the O₂-1.27 μm nightglow emission (about 95 km). Using a newly developed 1-D nightglow model and the composition distribution calculated from our GCM, we investigated the impact of the Kelvin wave on the nightglow distribution. Our results suggest that the Kelvin wave would cause temporal variations in the nightglow emission in the 23:50–00:20 LT region with an intensity of 1.1–1.3 MR and a period of approximately 4 days.     

Quantitative risk assessment for future meteorological disasters

The 2007 Intergovernmental Panel on Climate Change report stated that in many regions extreme climate events are becoming increasingly frequent and that this trend will continue. However, few quantitative studies have examined the damage to society or industry that may be caused by future meteorological disasters. This study quantitatively estimates the risk of future drought and winter disasters (dzud) in Mongolia leading to massive livestock loss by applying an empirical tree-based model to data derived from the basic local trend in projections of an Earth system model (a climate model coupled with ecosystem models) based on the Special Report on Emissions Scenario A2. The results indicate that drought is the dominant factor for high livestock mortality, and the frequency of meteorological disasters leading to high livestock mortality during 2010–2099 will be lower than that during 1940–2003, mainly because of a slight increase in the leaf area index (LAI, representing forage for livestock), which is caused by increased summer rainfall. The increased precipitation in summer is likely caused mainly by increased precipitable water due to higher air temperature, rather than changes in atmospheric circulation. By the end of the 21st century, however, LAI will drop in the southern most province of Mongolia, inducing severe livestock mortality. This will be caused by extremely high temperatures, which may continue to increase in degree and extent after 2100 if climate change continues.     

Dissakisite-(Ce) chemical composition: some implications for its origins

Euhedral dissakisites from Trimouns dolomite mine, France, is compositionally zoned. Back-scattered electron (BSE) images reveal that each of the described dissakisite crystals has three distinct compositional zones: normal zoned core (Mg-rich), oscillatory zoned middle (Ca–Al-rich) and homogeneous rim (Fe–ΣREE-rich). The latter zone with Fe²⁺ > Mg corresponds to allanite-(Ce). Dissakisite-(Ce) also displays pronounced zoning in Fe/Mg which may suggest that the temperature of crystallization continuously decreased from core to rim. Despite a systematic increase in Fe/Mg of the dissakisite with an allanite rim, there is no monotonic decrease in the REE zoning: the normal zoned core and homogeneous rim are rich in La, Ce and Pr, but the relatively REE-poor oscillatory zoned middle is relatively abundant in Y, Sm and Gd. Discontinuous variation in REE content of the dissakisite, with the allanite rim may indicate a localized change in either the relative concentration of various ligands or pH of the crystallizing fluid. Observations under the polarizing microscope confirm that the different zones have simultaneous extinction. These chemical and optical observations suggest that epitaxial crystallization of dissakisite, from Trimouns, passes through three formation stages. The ternary Fe²⁺–Mg²⁺–(Al + Fe)³⁺ diagram illustrates that in general dissakisite can be classified into two groups, (Al + Fe)³⁺-rich and an Mg-rich; dissakisite from Trimouns belongs to the former group. Chondrite-normalized REE patterns of dissakisites from Trimouns are similar to those of allanites formed by hydrothermal fluids. In conclusion, it is clear from the above two geochemical characteristics that dissakisites from Trimouns are of (Al + Fe)³⁺-type, and were derived from hydrothermal fluids.     

Crystal chemistry of volcanic allanites indicative of naturally induced oxidation-dehydrogenation

The crystal chemistry of volcanic allanites from both the Youngest Toba Tuff (YTT), Sumatra, Indonesia and SK100 volcanic ash beds (SK100-VAB), Niigata, Japan has been examined by electron microprobe analysis (EMPA), Fourier-transform infrared spectroscopic analysis (FTIR), and single-crystal structure analysis. In the FTIR study, based on the Diamond ATR accessory, YTT and SK100- VAB allanites were observed to have different OH contents, respectively: the former has 0.64 wt% H₂O (OH: 0.40 apfu.), while the latter has 1.65 wt% H₂O (OH: 1.00 apfu.). The crystal structures of these two allanites have been refined to individual R indices (3.64 and 4.25) based on 1350 observed reflections (|Fo| > 4sig|Fo|) measured using a single-crystal diffractometer with MoKα X-radiation. The OH-poor YTT allanite has a shorter b axis, a longer c axis, and larger β value than the relatively OH-rich SK100-VAB one. The bond valence sums of O4 (accepter oxygen for H atom) and O10 (donor oxygen for H atom) are 1.962 and 1.709 v.u. for YTT allanite (valence sum: 3.671 v.u.) and 1.754 and 1.271 v.u. for SK100-VAB one (valence sum: 3.025 v.u.). The difference from the ideal total bond valence value (4.00 v.u.) of O4 and O10 in YTT allanite (0.33 v.u.) is smaller than that in SK100-VAB (0.98 v.u.). These difference values are also broadly consistent with the corresponding differences in OH content between the YTT (OH: 0.40 apfu.) and SK100-VAB allanites (OH: 1.00 apfu.) determined by FTIR- ATR. Chemical analyses, FTIR-ATR and crystal structure refinement of YTT and SK100-VAB allanites yielded the following crystal chemical formula: YTT: (Ca_0.83Mn²⁺ _0.06Fe²⁺ _0.11)(La_0.24Ce_0.32Pr_0.04Nd_0.11Sm_0.02Th_0.04Ca_0.21)(Al_0.73Fe³⁺ _0.19Ti_0.08)(Al_0.89Fe³⁺ _0.11)(Fe²⁺ _0.22Fe³⁺ _0.62Mg_0.16)(SiO₄)Si₂O₇O_1.6(OH)_0.4, SK100-VAB: (Ca_0.81Fe²⁺ _0.13Mn²⁺ _0.06)(La_0.22Ce_0.34Pr_0.05Nd_0.13Sm_0.02Th_0.02Ca_0.22)(Al_0.76Fe³⁺ _0.19Ti_0.05)Al_1.00(Fe²⁺ _0.73Fe³⁺ _0.17Mg_0.10)(Si_0.96Al_0.04O₄)Si₂O₇O(OH). Therefore, it is concluded that welding of the Youngest Toba Tuff caused the following post-crystallization changes to occur in YTT allanite: oxidation of Fe²⁺ to Fe³⁺, release of H₂, and the concomitant replacement of OH^? by O^2?. These oxidation and dehydrogenation processes advanced during the welding to thereby produce oxyallanite. Oxyallanite had been reported only in laboratory studies where it was produced by heating natural allanite. Our report on natural oxyallanite suggests that it may be present in other welded silicic volcanic rocks as well.     

The nationwide investigation of endocrine disruptors in sediment of harbours

Various types of endocrine disruptors or environmental hormones flow from their sources down into harbours through rivers and other watercourses, and are accumulated in sediment on the sea bottom. Tributyltin, which has been used as paint for ship bottoms, is considered one of the endocrine disruptors.In close cooperation with the other ministries and agencies, the Ports and Harbours Bureau of the Ministry of Land, Infrastructure and Transport carried out an investigation in 1999 to determine the actual condition of 12 endocrine disruptors in the sediment of 39 harbours, in order to gather fundamental data to be used in future examinations of policy. Furthermore, in 2000 the bureau chose seven harbours out of the above 39 harbours as subjects of an additional investigation regarding the surface distribution of endocrine disruptors in the harbour areas and the synchronistic change of accumulation of dioxin and other substances. As the result of the investigation regarding the surface distribution of endocrine disruptors accumulated in seven harbours, relatively high concentrations were measured in the innermost parts of harbours and the mouths of rivers. Synchronistic changes in the amount of dioxin and other substances accumulated in sediments of five harbours were determined. Small amounts of dioxin and other substances, including an especially small amount of coplanar-PCBs, were found in the layers formed before or around 1950. Relatively large amounts of these substances were measured in the upper layers formed during roughly 1960-1990, though no significant yearly differences in concentration could be identified. This result coincides with the facts that, during roughly 1960-1980, PCP and CNP were used as agricultural chemicals and full-scale production of PCBs started in 1960.