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51.
Mark A. Rathmell Margaret M. Streepey Eric J. Essene Ben A. van der Pluijm 《Contributions to Mineralogy and Petrology》1999,134(2-3):217-231
The Elzevir Terrane of the Grenville Orogen in southern Ontario contains metapelites and abundant graphitic marbles that
were regionally metamorphosed from the upper greenschist to upper amphibolite facies. Comparative thermometry was undertaken
with widely used calibrations for the systems garnet-biotite, calcite-dolomite, and calcite-graphite. Temperatures that are
obtained from matrix biotites paired with prograde garnet near-rim analyses are usually consistent with those determined using
calcite-graphite thermometry. However, calcite-graphite thermometry occasionally yields low temperatures due to lack of equilibration
of anomalously light graphite. Application of calcite-graphite and garnet-biotite systems may yield temperatures up to 70 °C
higher than calcite-dolomite in amphibolite facies rocks. Calcite-dolomite temperatures most closely approach those from calcite-graphite
and garnet-biotite when the samples contain a single generation of dolomite and calcite grains contain no visible dolomite
exsolution lamellae. However, some of these samples yield temperatures considerably lower than temperatures calculated from
calcite-graphite and garnet-biotite thermometry, indicating that the calcite-dolomite thermometer may have been partially
reset during retrogression. Estimated peak metamorphic temperatures of regional metamorphism between Madoc (upper greenschist
facies) and Bancroft (upper amphibolite facies) range from 500 to 650 °C. These results place the chlorite-staurolite isograd
at 540 °C, the kyanite-sillimanite isograd at 590 °C, and the sillimanite-K-feldspar isograd at 650 °C. Although each thermometer
may have an absolute uncertainty of as much as ±50 °C, the 50 to 60 °C temperature differences between the isograds are probably
accurate to 10 to 20 °C. An incomplete picture of the thermal gradients can result from the application of only one thermometer
in a given area. Simultaneous application of several systems allows one to recognize and overcome the inherent limitations
of each thermometer.
Received: 26 March 1997 / Accepted: 15 April 1998 相似文献
52.
To facilitate precise and cost-effective watershed management, a simple yet spatially and temporally distributed hydrological model (DHM-WM) was developed. The DHM-WM is based on the Mishra-Singh version of the curve number method, with several modifications: The spatial distribution of soil moisture was considered in moisture updating; the travel time of surface runoff was calculated on a grid cell basis for routing; a simple tile flow module was included as an option. The DHM-WM was tested on a tile-drained agricultural watershed in Indiana, USA. The model with the tile flow module performed well in the study area, providing a balanced water budget and reasonable flow partitioning. The daily coefficient of determination and Nash-Sutcliffe coefficient were 0.58 and 0.56, for the calibration period, and 0.63 and 0.62 for the validation period. The DHM-WM also provides detailed information about the source areas of flow components, the travel time and pathways of surface runoff.
EDITOR A. Castellarin; ASSOCIATE EDITOR F.-J. Chang 相似文献
53.
Dissolved organic matter variations in coastal plain wetland watersheds: The integrated role of hydrological connectivity,land use,and seasonality 下载免费PDF全文
Dissolved organic matter (DOM) is integral to fluvial biogeochemical functions, and wetlands are broadly recognized as substantial sources of aromatic DOM to fluvial networks. Yet how land use change alters biogeochemical connectivity of upland wetlands to streams remains unclear. We studied depressional geographically isolated wetlands on the Delmarva Peninsula (USA) that are seasonally connected to downstream perennial waters via temporary channels. Composition and quantity of DOM from 4 forested, 4 agricultural, and 4 restored wetlands were assessed. Twenty perennial streams with watersheds containing wetlands were also sampled for DOM during times when surface connections were present versus absent. Perennial watersheds had varying amounts of forested wetland (0.4–82%) and agricultural (1–89%) cover. DOM was analysed with ultraviolet–visible spectroscopy, fluorescence spectroscopy, dissolved organic carbon (DOC) concentration, and bioassays. Forested wetlands exported more DOM that was more aromatic‐rich compared with agricultural and restored wetlands. DOM from the latter two could not be distinguished suggesting limited recovery of restored wetlands; DOM from both was more protein‐like than forested wetland DOM. Perennial streams with the highest wetland watershed cover had the highest DOC levels during all seasons; however, in fall and winter when temporary streams connect forested wetlands to perennial channels, perennial DOC concentrations peaked, and composition was linked to forested wetlands. In summer, when temporary stream connections were dry, perennial DOC concentrations were the lowest and protein‐like DOM levels the highest. Overall, DOC levels in perennial streams were linked to total wetland land cover, but the timing of peak fluxes of DOM was driven by wetland connectivity to perennial streams. Bioassays showed that DOM linked to wetlands was less available for microbial use than protein‐like DOM linked to agricultural land use. Together, this evidence indicates that geographically isolated wetlands have a significant impact on downstream water quality and ecosystem function mediated by temporary stream surface connections. 相似文献
54.
Peter J. Smith Mike Page Sean J. Handley S. Margaret McVeagh Merrick Ekins 《新西兰海洋与淡水研究杂志》2013,47(4):347-355
A colonial ascidian was first reported by marine farmers in Houhora Harbour, Northland, New Zealand in early 2005 and subsequently found on oyster racks in Parengarenga Harbour and the Bay of Islands. The Northland ascidian was identified with a combination of morphological characters and DNA cytochrome c oxidase I (COI) sequence data, as Eudistoma elongatum, a species native to Australia, where it is found from northern New South Wales to Northern Queensland, and distinguished from Eudistoma circumvallatum, the only reported species in this genus from New Zealand. Ascidian larvae are weak dispersers and long distance dispersal of E. elongatum is likely to be enhanced by vectors such as oyster barges and/or movement of cultured oysters. In its native range, E. elongatum is restricted to areas with a minimum winter sea temperature of 16°C. Assuming similar biological limitations apply in New Zealand, the spread of E. elongatum might be restricted to northern New Zealand (north of latitude 37°S). 相似文献
55.
Gas production from unconventional reservoirs has led to widespread environmental concerns. Despite several excellent reviews of various potential impacts to water resources from unconventional gas production, no study has systematically and quantitatively assessed the potential for these impacts to occur. We use empirical evidence and numerical and analytical models to quantify the likelihood of surface water and groundwater contamination, and shallow aquifer depletion from unconventional gas developments. These likelihoods are not intended to be exact. They provide a starting point for comparing the probabilities of adverse impacts between types of water resources and pathways. This analysis provides much needed insight into what are “probable” rather than simply “possible” impacts. The results suggest that the most likely water resource impacts are surface water and groundwater contamination from spills at the well pad, which can be as high as 1 in 10 and 1 in 100 for each gas well, respectively. For wells that are hydraulically fractured, the likelihood of contamination due to inter-aquifer leakage is 1 in 106 or lower (dependent on the separation distance between the production formation and the aquifer). For gas-bearing formations that were initially over-pressurized, the potential for contamination from inter-aquifer leakage after production ceases could be as high as 1 in 400 where the separation between gas formation and shallow aquifer is 500 m, but will be much lower for greater separation distances (more characteristic of shale gas). 相似文献
56.
Katherine C. Filippino Todd A. Egerton William S. Hunley Margaret R. Mulholland 《Estuaries and Coasts》2017,40(1):80-94
Due to the unpredictable nature of intense storms and logistical constraints of sampling during storms, little is known about their immediate and long-term impacts on water quality in adjacent aquatic ecosystems. By combining targeted experiments with routine monitoring, we evaluated immediate impacts of two successive storm events on water quality and phytoplankton community response in the tidal James River and compared these findings to a non-storm year. The James River is a subestuary of the Chesapeake Bay and sampling was conducted before, during, and after Hurricane Irene and Tropical Storm (TS) Lee in 2011 and during the same time period (late summer/early fall) in 2012 when there were no storms. We collected and compiled data on nutrient and chlorophyll a concentrations, phytoplankton abundance, nitrogen uptake, primary productivity rates, and surface salinity, temperature, and turbidity in the meso- and polyhaline segments of the James River. Hurricane Irene introduced significant amounts of freshwater over the entire James River and Chesapeake Bay watersheds, while rainfall from TS Lee fell primarily on the tidal fresh region of the James River and headwaters of the Chesapeake Bay. Dinoflagellates dominated the algal community in the meso- and polyhaline segments prior to the storms in 2011, and a mixed diatom community emerged after the storms. In the mesohaline river segment, cyanobacteria abundance increased after TS Lee when salinities were depressed, likely due to washout from the oligohaline and tidal fresh regions of the river. In 2012, dinoflagellates dominated the community in both segments of the river during late summer but diatoms were also abundant and their biomass fluctuated throughout the summer and fall. Cyanobacteria were not present in either segment. Overall, we observed that the high-intensity rainfall from Hurricane Irene combined with high flushing in the headwaters as a result of TS Lee likely reduced primary productivity and altered community composition in the mesohaline segment but not the more estuarine-influenced polyhaline segment. Understanding the influence of high freshwater flow with a short residence time associated with storms is key to the planning and management of estuarine restoration as such disturbances are projected to increase as a result of climate change. 相似文献
57.
58.
Techniques for characterizing the hydraulic properties and groundwater flow processes of aquifers are essential to design hydrogeologic conceptual models. In this study, rapid time series temperature profiles within open‐groundwater wells in fractured rock were measured using fiber optic distributed temperature sensing (FO‐DTS). To identify zones of active groundwater flow, two continuous electrical heating cables were installed alongside a FO‐DTS cable to heat the column of water within the well and to create a temperature difference between the ambient temperature of the groundwater in the aquifer and that within the well. Additional tests were performed to examine the effects of pumping on hydraulic fracture interconnectivity around the well and to identify zones of increased groundwater flow. High‐ and low‐resolution FO‐DTS cable configurations were examined to test the sensitivities of the technique and compared with downhole video footage and geophysical logging to confirm the zones of active groundwater flow. Two examples are presented to demonstrate the usefulness of this new technique for rapid characterization of fracture zones in open boreholes. The combination of the FO‐DTS and heating cable has excellent scope as a rapid appraisal tool for borehole construction design and improving hydrogeologic conceptual models. 相似文献
59.
Elizabeth A. McHuron James T. Harvey J. Margaret Castellini Craig A. Stricker Todd M. O’Hara 《Marine pollution bulletin》2014
We measured total selenium and total mercury concentrations ([TSe] and [THg]) in hair (n = 138) and blood (n = 73) of harbor seals (Phoca vitulina) from California to assess variation by geography and sex, and inferred feeding relationships based on carbon, nitrogen, and sulfur stable isotopes. Harbor seals from Hg-contaminated sites had significantly greater [THg], and lesser [TSe] and TSe:THg molar ratios than seals from a relatively uncontaminated site. Males had significantly greater [THg] than females at all locations. Sulfur stable isotope values explained approximately 25% of the variability in [THg], indicating increased Hg exposure for seals with a greater use of estuarine prey species. Decreased [TSe] in harbor seals from Hg-contaminated regions may indicate a relative Se deficiency to mitigate the toxic effects of Hg. Further investigation into the Se status and the potential negative impact of Hg on harbor seals from Hg-contaminated sites is warranted. 相似文献
60.
This paper describes the in situ response of groundwater biofilms in an alluvial gravel aquifer system on the Canterbury Plains, New Zealand. Biofilms were developed on aquifer gravel, encased in fine mesh bags and suspended in protective columns in monitoring wells for at least 20 weeks. Four sites were selected in the same groundwater system where previous analyses indicated a gradient of increasing nitrate down the hydraulic gradient from Sites 1 to 4. Measurements during the current study classified the groundwater as oligotrophic. Biofilm responses to the nutrient gradients were assessed using bioassays, with biomass determined using protein and cellular and nucleic acid staining and biofilm activity using enzyme assays for lipid, carbohydrate, phosphate metabolism, and cell viability. In general, biofilm activity decreased as nitrate levels increased from Sites 1 to 4, with the opposite relationship for carbon and phosphorus concentrations. These results showed that the groundwater system supported biofilm growth and that the upper catchment supported efficient and productive biofilms (high ratio of activity per unit biomass). 相似文献