Chemical and chronologic complexity in the convecting upper mantle: Evidence from the Taitao ophiolite, southern Chile

Exposure of the ca. 6 Ma Taitao ophiolite, Chile, located 50 km south of the Chile Triple Junction, allows detailed chemical and isotopic study of rocks that were recently extracted from the depleted mantle source of mid-ocean ridge basalts (DMM). Ultramafic and mafic rocks are examined for isotopic (Os, Sr, Nd, and O), and major and trace element compositions, including the highly siderophile elements (HSE). Taitao peridotites have compositions indicative of variable extents of partial melting and melt extraction. Low δ¹⁸O values for most whole rock samples suggest some open-system, high-temperature water–rock interaction, most likely during serpentinization, but relict olivine grains have δ¹⁸O values consistent with primary mantle values. Most of the peridotites analyzed for Nd–Sr isotopes have compositions consistent with estimates for the modern DMM, although several samples are characterized by ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd indicative of crustal contamination, most likely via interactions with seawater. The peridotites have initial ¹⁸⁷Os/¹⁸⁸Os ratios that range widely from 0.1168 to 0.1288 (γ_Os = −8.0 to +1.1), averaging 0.1239 (γ_Os = −2.4), which is comparable to the average for modern abyssal peridotites. A negative correlation between the Mg^# of relict olivine grains and Os isotopic compositions of whole rock peridotites suggests that the Os isotopic compositions reflect primary mantle Re/Os fractionation produced by variable extents of partial melting at approximately 1.6 Ga. Recent re-melting at or near the spatially associated Chile Ridge further modified these rocks, and Re, and minor Pt and Pd were subsequently added back into some rocks by late-stage melt–rock or fluid–rock interactions.In contrast to the peridotites, approximately half of the mafic rocks examined have whole rock δ¹⁸O values within the range of mantle compositions, and their Nd and Sr isotopic compositions are all generally within the range of modern DMM. These rocks have initial ¹⁸⁷Os/¹⁸⁸Os ratios, calculated for 6 Ma, that range from 0.126 (γ_Os = −1) to as high as 0.561 (γ_Os = +342). The Os isotopic systematics of each of these rocks may reflect derivation from mixed lithologies that include the peridotites, but may also include pyroxenites with considerably more radiogenic Os than the peridotites. This observation supports the view that suprachondritic Os present in MORB derives from mixed mantle source lithologies, accounting for some of the worldwide dichotomy in ¹⁸⁷Os/¹⁸⁸Os between MORB and abyssal peridotites.The collective results of this study suggest that this >500 km³ block of the mantle underwent at least two stages of melting. The first stage occurred at 1.6 Ga, after which the block remained isolated and unmixed within the DMM. A final stage of melting recently occurred at or near the Chile Ridge, resulting in the production of at least some of the mafic rocks. Convective stirring of this mantle domain during a >1 Ga period was remarkably inefficient, at least with regard to Os isotopes.     

Precipitation and mixing properties of the “disordered” (Mn,Ca)CO3 solid solution

The enthalpy of mixing of the calcite-rhodochrosite (Ca,Mn)CO₃ solid solution was determined at 25 °C from calorimetric measurements of the enthalpy of precipitation of solids with different compositions. A detailed study of the broadening of powder X-ray diffraction peaks shows that most of the precipitates are compositionally homogeneous. All the experimental enthalpy of mixing (ΔH^m) values are positive and fit reasonably well (R² = 0.86) to a Guggenheim function of three terms:

     

Euro-Cordex Regional Projection Models: What Kind of Agreement for Europe?

Mathematical Geosciences - EURO-CORDEX is an international initiative which provides regional climate projections based on multiple dynamical and empirical–statistical downscaling models. The...     

A depth average SPH model including μ(I) rheology and crushing for rock avalanches

Classical depth-integrated smoothed particle hydrodynamics (SPH) models for avalanches are extended in the present work to include a μ(I)− rheological model enriched with a fragmentation law. With this improvement, the basal friction becomes grain distribution dependent. Rock avalanches, where grain distribution tends to change with time while propagating, are the appropriate type of landslide to apply the new numerical proposal. The μ(I)− rheological models considered in the present work are those of Hatano and Gray, combined with two different fragmentation laws, a hyperbolic and a fractal-based law. As an application, Frank avalanche, which took place in Canada in 1903, is analyzed under the scope of the present approach, focusing in the influence of the rheological and fragmentation laws in the evolution of the avalanche.     

Changes in heat wave characteristics over Extremadura (SW Spain)

Theoretical and Applied Climatology - Heat wave (HW) events are becoming more frequent, and they have important consequences because of the negative effects they can have not only on the human...     

The Barranco de Arás flood of 7 August 1996 (Biescas, Central Pyrenees, Spain)

Geomorphic effects observed in the Barranco (creek) de Arás basin are used to characterize the flood. Sediment features allow to qualify the flood as essentially a water flow. Using the critical section method, the peak flood discharge is estimated to be between 400 and 600 m³ s⁻¹. Similar results were obtained using a paleohydraulic formula based on the size of the largest mobilized clasts. Using the rational method with available rainfall data, the discharge for a recurrence interval of 500 years is estimated to be between 150 and 200 m³ s⁻¹. These results agree with predictions obtained using curves of peak discharge versus basin area based on regional data. Several trenches dug on the fan showed that the size of boulders mobilized by the event is larger that those left by previous floods at the same place. When the estimated peak flood discharge is related to the basin area, values between 20 and 30 m³ s⁻¹ km⁻² are obtained, demonstrating that the Barranco de Arás flood was most unusual.     

Palaeokarst and rauhwacke development,mountain uplift and subaerial sliding of tectonic sheets (northern Sierra de los Filabres,Betic Cordilleras,Spain)

The rauhwackes near Serón in the northern Sierra de los Filabres (S Spain), previously considered as true tectonic breccias, are reinterpreted on the basis of sedimentological, geomorphological and geometrical evidence as subaerial or nearly subaerial sedimentary deposits. Channel fills, parallel lamination, cross-lamination, graded bedding, sedimentary clastic dykes and other sedimentary structures and features occur in the rauhwacke body. These sedimentary rocks correspond to continental deposits of alluvial and karstic origin deposited over a karstified erosional surface of Nevado–Filabride marbles. Although no fossils have been found in the rauhwackes, a Tortonian age for these rocks is suggested on the basis of structural arguments and lithostratigraphic data from the nearby Almanzora basin. The rauhwackes were buried by slabs of Alpujarride rocks that gravitationally slid over them during the uplifting of the Sierra de los Filabres.     

SlugIn 1.0: A Free Tool for Automated Slug Test Analysis

The correct characterization of aquifer parameters is essential for water‐supply and water‐quality investigations. Slug tests are widely used for these purposes. While free software is available to interpret slug tests, some codes are not user‐friendly, or do not include a wide range of methods to interpret the results, or do not include automatic, inverse solutions to the test data. The private sector has also generated several good programs to interpret slug test data, but they are not free of charge. The computer program SlugIn 1.0 is available online for free download, and is demonstrated to aid in the analysis of slug tests to estimate hydraulic parameters. The program provides an easy‐to‐use Graphical User Interface. SlugIn 1.0 incorporates automated parameter estimation and facilitates the visualization of several interpretations of the same test. It incorporates solutions for confined and unconfined aquifers, partially penetrating wells, skin effects, shape factor, anisotropy, high hydraulic conductivity formations and the Mace test for large‐diameter wells. It is available in English and Spanish and can be downloaded from the web site of the Geological Survey of Spain. Two field examples are presented to illustrate how the software operates.     

The shape of the seismic response interaction diagram: The effect of combination rules in response spectrum analysis

This paper deals with the construction of seismic response interaction diagrams that show the correlation of multiple responses and are important to determine the critical combination of modal responses. Many design problems, such as column design under combined axial force and bending moments, fall into this category. We address general modal and multicomponent combination rules and study their effect on the shape of the response interaction diagrams, thus extending previous work done for quadratic combination rules. Special attention is given to multilinear combination rules which lead to polyhedral shapes. Having developed efficient methods to deal with polyhedral shapes, we explore the idea of adopting a multilinear modal combination rule to compose with a multicomponent percentage rule.     

Separation of PP- and PS-wave reflected seismic data using two-dimensional finite offset common-reflection-surface traveltime approximation

Recently, the interest in PS-converted waves has increased for several applications, such as sub-basalt layer imaging, impedance estimates and amplitude-versus-offset analysis. In this study, we consider the problem of separation of PP- and PS-waves from pre-stacked multicomponent seismic data in two-dimensional isotropic medium. We aim to demonstrate that the finite-offset common-reflection-surface traveltime approximation is a good alternative for separating PP- and PS-converted waves in common-offset and common shot configurations by considering a two-dimensional isotropic medium. The five parameters of the finite-offset common-reflection-surface are firstly estimated through the inversion methodology called very fast simulated annealing, which estimates all parameters simultaneously. Next, the emergence angle, one of the inverted parameters, is used to build an analytical separation function of PP and PS reflection separation based on the wave polarization equations. Once the PP- and PS-converted waves were separated, the sections are stacked to increase the signal-to-noise ratio using the special curves derived from finite-offset common-reflection-surface approximation. We applied this methodology to a synthetic dataset from simple-layered to complex-structured media. The numerical results showed that the inverted parameters of the finite offset common-reflection-surface and the separation function yield good results for separating PP- and PS-converted waves in noisy common-offset and common shot gathers.