Diet of Phycis blennoides (Gadidae) in Relation to Fish Size and Season in the Western Mediterranean (Spain)

Abstract. Despite its commercial value, little is known about the feeding ecology of the greater forkbeard, Phycis blennoides (Brünnich 1768). The stomach contents of 2631 greater forkbeard were taken at monthly intervals off the coast of the Gulf of Valencia (western Mediterranean). They were examined in order to assess the diet and to determine the fish size- and season-related dietary variation of the species. Prey items were identified to the lowest taxonomic level possible. The basic food consisted of epibenthic species, mostly Decapoda, Mysidacea and Teleostei. A change in food composition based on fish size was observed and seasonal variation in diet was also recorded. The food overlap analysis indicated a high convergence in diet among similar size groups.     

Consequences of winter upwelling events on biogeochemical and phytoplankton patterns in a western Galician ria (NW Iberian peninsula)

The consequences of two upwelling events in mid- (MW) and late (LW) winter on biogeochemical and phytoplankton patterns were studied in the Pontevedra Ria and compared with the patterns measured under typical winter conditions and under a summer upwelling event. Thermohaline patterns measured during the mid-winter upwelling event (MW-up) revealed the intrusion of saltier seawater (35.9) into the ria associated with the Iberian Poleward Current (IPC). During the late-winter upwelling event (LW-up), the seawater which had welled up into the ria showed characteristics of the Eastern North Atlantic Central Water mass (ENACW). In both cases the measured water residence time (4 days during MW-up and 10 days during LW-up) was related to both meteorological and fluvial forcing. This residence time contrasts with that of summer upwelling (7 days) and with that estimated under unfavorable upwelling atmospheric conditions (2–4 weeks). During MW-up, the ria became poor in nutrients due to continental freshwater dilution, associated with the shorter residence time of the water, and the intrusion of IPC, which is a water body poor in nutrient salts: 2.9 μM of nitrate, 0.1 μM of phosphate and 1.5 μM of silicate. During this event, the ria exported 3.4 mol_DIN s⁻¹, compared with 6.9 mol_DIN s⁻¹ in non-upwelling conditions. Phytoplankton showed a uniform distribution throughout the ria, as during unfavorable upwelling conditions, and was characterized by the dominance of diatoms, mainly Nitzschia longissima and Skeletonema costatum. During LW-up, a nutrient depletion in the photic layer also occurred, but as a result of a phytoplankton spring bloom developing at this time. The ria was a nutrient trap where 4.1 mol_DIN s⁻¹ were processed by photosynthesis. This budget is three times higher than the one under non-upwelling conditions. In contrast with the MW-up, which had no effect on primary production, during LW-up the ria became more productive, although not as productive as during a summer upwelling event (9.9 mol_DIN s⁻¹). The taxonomic composition of the phytoplankton community did not change noticeably during LW-up and the summer upwelling, with the same species present and changing only in relative proportions. Diatoms were always the dominant microphytoplankton community, with Pseudonitzschia pungens, Thalassionema nitzschioides and several species of Chaetoceros as characteristic taxons.     

The enigma of helium and anomalous xenon

Isotopically anomalous xenon in chondrites is closely associated with low-Z noble gases, but there is no helium (or neon) in the noble gas component with normal xenon. The correlation of elemental and isotopic heterogeneities in meteoritic noble gases places stringent limits on the origin of isotopically anomalous elements in meteorites and on the formation of the solar system.     

Rodent paleofaunas as indicators of climatic change in Europe during the last 125,000 years

This paper presents a quantitative reconstruction of the European late Pleistocene paleoclimate based on 72 rodent assemblages of five sequences from France, Germany and Bulgaria, covering the last interglacial-glacial cycle. They show a pattern of severe changes in temperature, with reduced precipitation during the coldest periods. A tentative correlation between the isotopic and palynological records and the paleotemperature changes is shown. These changes are consistent with variations in atmospheric circulation patterns in response to an expanding-retracting Fennoscandian ice-sheet. They can be attributed to the enhancement-weakening of the Scandinavian-Polar anticyclone and its associated dry winds, the south-north shifting of the North Atlantic Polar Front, and the varying supply of moist air from the Atlantic. Qualitative paleoenvironmental analysis shows broadleaved-deciduous forests in France and Bulgaria during most of the studied period. Taiga and tundra appeared in eastern France during the lower Würm. The German sequence indicates the presence of coniferous forests. These results are broadly consistent with other paleobiological records (mammalian, avian and insect faunas, isotopic record in dental tissue, palynology). The main discrepancies with the paleoclimate inferred from the palynological record are found during the coldest periods and are probably due to the interaction between vegetation, climate, and atmospheric CO₂ levels.     

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.     

GGM02 – An improved Earth gravity field model from GRACE

A new generation of Earth gravity field models called GGM02 are derived using approximately 14 months of data spanning from April 2002 to December 2003 from the Gravity Recovery And Climate Experiment (GRACE). Relative to the preceding generation, GGM01, there have been improvements to the data products, the gravity estimation methods and the background models. Based on the calibrated covariances, GGM02 (both the GRACE-only model GGM02S and the combination model GGM02C) represents an improvement greater than a factor of two over the previous GGM01 models. Error estimates indicate a cumulative error less than 1 cm geoid height to spherical harmonic degree 70, which can be said to have met the GRACE minimum mission goals. Electronic Supplementary Material Supplementary material is available in the online version of this article at     

He and Ne isotopes in oceanic crust: implications for noble gas recycling in the mantle

In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10⁻¹⁰ to 2.5×10⁻⁷ ccSTP/g by crushing and from 5.4×10⁻⁸ to 2.4×10⁻⁷ ccSTP/g by melting. ³He/⁴He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric ²⁰Ne/²²Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/³He ratio of these crustal gabbros will generate very radiogenic ⁴He/³He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing.     

Cenozoic Plate interaction of the Australia and Philippine Sea Plates: “hit-and-run” tectonics

Recent studies in northwest New Guinea have shown the presence of at least two marginal basins of different age, both of which formed in back-arc settings. The older basin opened between the Middle Jurassic and Early Cretaceous, a remnant of which is now preserved as the New Guinea Ophiolite. Its obduction started at 40 Ma and it was finally emplaced on the Australian margin at 30 Ma. The younger basin was active during the Oligocene to Middle Miocene and was obducted in the Early Pliocene. Studies of the western edge of the Philippine Sea also reveal an important deformation of the Philippine arc in the Oligocene, which hitherto has remained unexplained. Using information from these systems, paleomagnetic results, kinematic reconstructions and geochemistry of the supra-subduction ophiolite, we present a plate model to explain the region's Eo–Oligocene development. We suggest that an extensive portion of oceanic crust extended the Australian Plate a considerable distance north of the Australian Craton. As Australia began its steady 7–8 cm/year northward drift in the Early Eocene, this lithosphere was subducted. Thus, the portion of the Philippine Sea Plate carrying the Taiwan–Philippine Arc to its present site may have actually been in contact with the ophiolite now in New Guinea and obduction led to deformation of the Philippine Sea Plate itself. Neogene Plate kinematics transported the deformed belt in contact with the Sunda block in the Late Miocene and Pliocene. This interpretation has implications for the origin for the Philippine Sea Plate and the potential incorporation of continental fragments against its boundaries.