Using inverse modeling and hierarchical cluster analysis for hydrochemical characterization of springs and Talkhab River in Tang-Bijar oilfield,Iran

Hierarchical cluster analysis (HCA) and inverse modeling (PH REdox EQuilibrium (in C language) (PHREEQC)) were simultaneously useful approaches in interpreting surface water hydrochemistry within Talkhab River in the Tang-Bijar oilfield, Iran, where large uncertainties exist in the understanding of the water quality system. Q-mode HCA applied to the data revealed three major surface water associations distinguished on the basis of the major causes of variation in the hydrochemistry. The three water groups were classified as upstream waters (group 1: Ca–SO₄), intermediate waters (group 2: Ca–SO₄–Cl), and downstream waters (group 3: Na–Cl). Geochemical reaction models were constructed using PHREEQC to establish the reactions associated with the different mineral phases through inverse modeling. The hydrochemical compositions of the water groups and the mass balance calculations indicate that the dominant processes and reactions responsible for the hydrochemical evolution in the system are (1) dissolution of evaporites, (2) precipitation of carbonate minerals, (3) silicate weathering reactions, (4) limited mixing with saline water, and (5) ion exchange.     

Hydrogeological assessment of the Tabarteh fault zone by physicochemical analysis and multivariate statistical methods

Hydrogeologically, faults may impede, conduit, exert no influence, or may play a combination of these roles on groundwater flow. The object of this paper is to study the hydrogeological role of the Tabarteh fault, which is located on the border of Zagros and Central Iran tectonic zones in an alluvial aquifer. The recorded data of water table levels, chemical parameters, and discharge rate of wells, in addition to geological maps and geophysical results, were collected and evaluated. The outcrop of travertine in limited areas and the emergence of a few small springs within the alluvium show a barrier role of the fault in the groundwater flow. The spatial analysis of chemical components, head time series, and groundwater flow direction assessment demonstrated that the fault acts as both a barrier and a non-barrier in different sections. The multivariate statistical methods of cluster and discriminant analyses also confirm the dual role of the fault.     

Comparative analysis of Lake Urmia and Lake Van water level time series

Recent decline in Lake Urmia water level makes it crucial to consider this issue more seriously. For this purpose, comparison of water level in Lake Urmia with Lake Van in Turkey, which is in relatively similar geographic and climate conditions, can be an effective approach. To follow this objective, trend analysis, regime shift, and coherency analyses are implemented. The results showed negative trend in Lake Urmia water level for the past 20 years, while in Lake Van, the trend is positive. Moreover, correlation of the lake level variations versus the basin rainfall during three common periods, identified by the regime shifts analysis, illustrated a decreasing trend in the correlation. These changes can be attributed to non-climatic factors such as different allocation disciplines in two lake’s catchments. Finally, the coherency analysis showed significant annual and inter-annual frequencies common between the two lake levels. Herein, the short-term period relations are associated with lags, while in long term, they act simultaneously.     

Impact assessment of land cover changes on the runoff changes on the extreme flood events in the Kelantan River basin

In the current years, changing the land cover/land use had serious hydrological impacts affecting the flood events in the Kelantan River basin. The flood events at the east coast of the peninsular Malaysia got highly affected in the recent decades due to several factors like urbanisation, rapid changes in the utilisation of land and lack of meteorological (i.e. change in climate) and developmental monitoring and planning. The Kelantan River basin has been highly influenced due to a rapid change in land use during 1984 to 2013, which occurred in the form of transformation of agricultural area and deforestation (logging activities). In order to evaluate the influence of the modifications in land cover on the flood events, two hydrological regional models of rainfall-induced runoff event, the Hydrologic Engineering Center (HEC)-Hydrologic Modeling System (HMS) model and improved transient rainfall infiltration and grid-based regional model (Improved TRIGRS), were employed in this study. The responses of land cover changes on the peak flow and runoff volume were investigated using 10 days of hourly rainfall events from 20 December to the end of December 2014 at the study area. The usage of two hydrological models defined that the changes in land use/land cover caused momentous changes in hydrological response towards water flow. The outcomes also revealed that the increase of severe water flow at the study area is a function of urbanisation and deforestation, particularly in the conversion of the forest area to the less canopy coverage, for example, oil palm, mixed agriculture and rubber. The monsoon season floods and runoff escalate in the cleared land or low-density vegetation area, while the normal flow gets the contribution from interflow generated from secondary jungle and forested areas.     

Subduction-related mafic to felsic magmatism in the Malayer–Boroujerd plutonic complex,western Iran

The Malayer–Boroujerd plutonic complex (MBPC) in western Iran, consists of a portion of a magmatic arc built by the northeast verging subduction of the Neo-Tethys plate beneath the Central Iranian Microcontinent (CIMC). Middle Jurassic-aged felsic magmatic activity in MBPC is manifested by I-type and S-type granites. The mafic rocks include gabbroic intrusions and dykes and intermediate rocks are dioritic dykes and minor intrusions, as well as mafic microgranular enclaves (MMEs). MBPC Jurassic-aged rocks exhibit arc-like geochemical signatures, as they are LILE- and LREE-enriched and HFSE- and HREE-depleted and display negative Nb–Ta anomalies. The gabbro dykes and intrusions originated from metasomatically enriched garnet-spinel lherzolite [Degree of melting (f_mel) ~ 15%] and exhibit negative Nd and positive to slightly negative ε_Hf(T) (+ 3.0 to ? 1.6). The data reveal that evolution of Middle Jurassic magmatism occurred in two stages: (1) deep mantle-crust interplay zone and (2) the shallow level upper crustal magma chamber. The geochemical and isotopic data, as well as trace element modeling, indicate the parent magma for the MBPC S-type granites are products of upper crustal greywacke (f_mel: 0.2), while I-type granites formed by partial melting of amphibolitic lower crust (f_mel: 0.25) and mixing with upper crustal greywacke melt in a shallow level magma chamber [Degree of mixing (f_mix): 0.3]. Mixing between andesitic melt leaving behind a refractory dense cumulates during partial crystallization of mantle-derived magma and lower crustal partial melt most likely produced MMEs (f_mix: 0.2). However, enriched and moderately variable ε_Nd(T) (? 3.21 to ? 4.33) and high (⁸⁷Sr/⁸⁶Sr)_i (0.7085–0.7092) in dioritic intrusions indicate that these magmas are likely experienced assimilation of upper crustal materials. The interpretations of magmatic activity in the MBPC is consistent with the role considered for mantle-derived magma as heat and mass supplier for initiation and evolution of magmatism in continental arc setting, elsewhere.     

Ghaleh-khargushi rhyodacite and Gorid andesite from Iran: characterization,uses, and durability

Durability of building stones is an important issue in sustainable development. Crystallization of soluble salts is recognized as one of the most destructive weathering agents of building stones. For this reason, durability of Ghaleh-khargushi rhyodacite and Gorid andesite from Iran was investigated against sodium sulfate crystallization aging test. Petrographic and physico-mechanical properties and pore size distribution of these stones were examined before and after the aging test. The characteristics of the microcracks were quantified with fluorescence-impregnated thin sections. Durability and physico-mechanical characteristics of Ghaleh-khargushi rhyodacite are mainly influenced by preferentially oriented preexisting microcracks. Stress induced by salt crystallization led to the widening of preexisting microcracks in Ghaleh-khargushi rhyodacite, as confirmed by the pore size distributions before and after the aging test. The preexisting microcracks of Gorid andesite were attributed to the mechanical stress induced by contraction of lava during cooling. The number of transcrystalline microcracks was significantly increased after the aging test. The degree of plagioclase microcracking was proportional to its size. Durability of the studied stones depends on initial physico-mechanical properties, pore size distribution, and orientation of microcracks. Initial effective porosity is found to be a good indicator of the stones’ durability. Salt crystallization resulted in an increase in the effective porosity with a parallel decrease in the wave velocities. Surface microroughness parameters increased with the development of salt crystallization-induced microcracking. Gorid andesite showed higher quality and durability than Ghaleh-khargushi rhyodacite.