Evidence for Enhanced Mineral Dissolution in Organic Acid-Rich Shallow Ground Water

Total concentrations of formate, acetate, and isobutyrate varied from less than 5 to greater than 9,000 μmol/l over distances of < 3 m in ground water from a shallow hydrocarbon contaminated aquifer. Laboratory incubations of aquifer material indicate that organic acid concentrations were dependent on the amount of hydrocarbon loading in the sediment and the relative rates of microbial organic acid production and consumption. In heavily contaminated sediments, production greatly exceeded consumption and organic acid concentrations increased. In lightly contaminated sediments rates were essentially equal and organic acid concentrations remained low. Concentrations of dissolved calcium, magnesium, and iron generally were one to two orders of magnitude higher in organic acid-rich ground water than in ground water having low organic acid concentrations. Carbonate and Fe(III)-oxyhydroxide minerals were the likely sources of these elements. Similarly, concentrations of dissolved silica, derived from quartz and k-feldspar, were higher in organic acid-rich ground water than in other waters. The positive relation (r = 0.60, p < .05, n = 16) between concentrations of silica and organic acids suggests that the microbially mediated buildup of organic acids in ground water enhanced quartz/k-feldspar dissolution in the aquifer, although it was not the only factor influencing their dissolution. A model that included organic acid microequivalents normalized by cation microequivalents significantly strengthened the correlation (r = 0.79, p < .001, n = 16) between dissolved silica and organic acid concentrations, indicating that competition between silica and cations for complexation sites on organic acids also influenced quartz/k-feldspar dissolution. Physical evidence for enhanced mineral dissolution in organic acid-rich waters included scanning electron microscopy images of highly corroded quartz and k-feldspar grains from portions of the aquifer containing organic acid-rich ground water. Microporosity generated in hydrocarbon contaminated sediments may adversely affect remediation efforts that depend on the efficient injection of electron acceptors into an aquifer or on the recovery of solutes from an aquifer.     

Basalt geochemistry and tectonic discrimination within continental flood basalt provinces

Continental flood basalts are usually regarded as a single tectonomagmatic entity but frequently quoted examples exhibit a variety of tectonic settings. In one well-studied, classic, flood basalt province, the Mesozoic Karoo province of southern Africa, magmatism occurred in the following tectonic settings: (a) continental rifting leading to ocean-floor spreading in the South Atlantic Ocean (Etendeka suite of Namibia); (b) stretched continental lithosphere and rifting not leading directly to ocean-floor formation (Lebombo suite of southeastern Africa); and (c) an a-tectonic, within-plate, continental setting characterized by an absence of faulting or warping (Lesotho highlands and Karoo dolerites of South Africa). By means of spidergrams of the elements Rb, Ba, Th, Nb, K, La, Ce, Sr, Nd, P, Hf, Zr, Sm, Ti, Tb, Y, V, Ni and Cr, uncontaminated tholeiites from (c) above [i.e. the Lesotho-type continental flood basalts (LTCFB)] are compared with mid-ocean ridge basalts (MORB), ocean-island tholeiites (OIT), and tholeiites and calc-alkali basalts from subduction environments. The comparison reveals the LTCFBs are geochemically distinct. The differences are reflected in relative enrichments or depletions of the more incompatible elements (Rb-Ce) to less incompatible elements (Ce-Y), i.e. the overall slope of the spidergrams, and in anomalous enrichments or depletions of one or more of the elements Th, K, Nb, Sr, Ti, Hf, and Zr. The distinctive geochemical character of the Lesotho LTCFBs is interpreted in terms of a lithospheric mantle source for the basalts. This is supported by isotopic data. There are no major geochemical differences between Lesotho CFBs and basalts of the rift-related Etendeka and Lebombo suites, although the latter are somewhat enriched in Rb, Ba and K. However, unlike the Lesotho basalts, the Lebombo and Etendeka basalts are associated with voluminous silicic volcanics or intrusive centres and late-stage dolerites having MORB/OIT (i.e. asthenospheric) geochemical characteristics. The flood basalt/silicic magmatism/late-stage dyke swarm association is characteristic of several rift or thinned lithosphere environments (e.g., Ethiopia, Skye, eastern Greenland) but in many of these the flood basalts have ocean-island basalt (OIT) geochemical characteristics. The Lesotho-type CFB geochemistry is exhibited by the Grande Ronde Basalt of the Columbia River Group (a possible subduction-related flood basalt province) and the basic rocks associated with Mesozoic rifting in the North and South Atlantic. Basalt geochemistry alone is unhelpful in determining the tectonic setting of CFBs although the rift-related environments may be identified by the petrology and geochemistry of the whole igneous suite. A two-source model is proposed for the mantle-derived basic rocks in rift-related CFB provinces. Early enriched basalts are derived from the lithosphere and, following pronounced lithospheric attenuation or rifting, later MORB-like melts are emplaced from the rising asthenosphere. The presence of both Lesotho- and OIT-type geochemical patterns in rift-related CFBs suggests that the lithosphere exhibits different styles of enrichment.     

USGS Reference Samples Attapulgite ATT-1 and Bentonite CSB-1

The U.S. Geological Survey has prepared an attapulgite and a bentonite as reference samples because of their economic importance. The attapulgite (ATT-1) is from the Meigs-Attapulgite-Quincy fuller's earth district of Georgia and Florida, and the bentonite (CSB-1) is from the Northern Black Hills bentonite district of Wyoming, Montana, and South Dakota. The chemical and mineralogical properties of these two samples are quite different. Provisional values calculated from the few analytical data and the X-ray diffraction mineralogy are presented for those who wish to use the clays as reference samples.     

Estimation of uranium endowment by subjective geological analysis—a comparison of methods and estimates for the San Juan Basin,New Mexico

This study investigates how estimates of uranium endowment made by a geologist using an appraisal system that is based upon a formalization of geoscience and decision rules compare with estimates made by informal and unconstrained intuitive processes. The motivation for this study derives from the premise that formalization of decisions would mitigate the heuristic biases and hedging that may result from the use of unconstrained intuitive processes. Estimates of the uranium endowment of the San Juan Basin of New Mexico by four methodologies are compared in this study. These methods, ranked from top to bottom by degree of decomposition (mitigating of heuristic bias)and control on hedging, are as follows Implicit 2 1.5 × 10⁶ s.t. of U₃O₈ Implicit 1 1.6 × 10⁶ s.t. of U₃O₈ NURE (1980) 2.4 × 10⁶ s.t. of U₃O₈ Appraisal system 3.9 × 10⁶ s.t. of U₃O₈ The magnitude of expected uranium endowment estimated by these methods, ranked from smallest to largest, is in this same order. With the exception of the NURE estimates, the magnitude of the variance (uncertainty)of uranium endowment, ranked from smallest to largest, also is in this same order. These results prompt the suggestion that the more decomposed and formalized the estimation procedure, the greater the expected value and the variance of uranium endowment. Equivalently, predicating U ₃ O ₈ endowment estimation strictly upon that part of the geologist's geoscience that is useful in making U ₃ O ₈ endowment estimates and upon his understanding of the region's history produced larger estimates than have previously been reported. However, this method of estimation also shows that uncertainty about the actual state of U ₃ O ₈ endowment is much greater than previously described.     

Naturally Enhanced Ion-Acoustic Spectra And Their Interpretation

Incoherent scatter radars are designed to detect scatter from thermalfluctuations in the ionosphere. These fluctuations contain, among other things,features associated with ion-acoustic waves driven by random motions within theplasma. The resulting spectra are generally broad and noisy, but neverthelessthe technique can, through a detailed analysis of spectra, be used to measure arange of physical parameters in the Earth's upper atmosphere, and provides apowerful diagnostic in studies of magnetosphere-ionosphere coupling,thermosphere dynamics and the geospace environment in general. In recent yearsthere has been much interest in naturally occurring (as opposed to artificiallystimulated) enhanced ion-acoustic spectra seen in the auroral zone andcusp/cleft region. A study of the plasma instability processes that lead tosuch spectra will help us to better understand auroral particle acceleration,wave-particle and wave-wave interactions in the ionosphere, and theirassociation with magnetospheric processes. There is now a substantial body ofliterature documenting observations of enhanced ion-acoustic spectra, but thereremains controversy over generation mechanisms. We present a review ofliterature documenting observations of naturally enhanced ion-acoustic spectra,observed mainly along the geomagnetic field direction, along with a discussionof the theories put forward to explain such phenomena.