3-D Modelling of Campi Flegrei Ground Deformations: Role of Caldera Boundary Discontinuities

Campi Flegrei is a caldera complex located west of Naples, Italy. The last eruption occurred in 1538, although the volcano has produced unrest episodes since then, involving rapid and large ground movements (up to 2 m vertical in two years), accompanied by intense seismic activity. Surface ground displacements detected by various techniques (mainly InSAR and levelling) for the 1970 to 1996 period can be modelled by a shallow point source in an elastic half-space, however the source depth is not compatible with seismic and drill hole observations, which suggest a magma chamber just below 4 km depth. This apparent paradox has been explained by the presence of boundary fractures marking the caldera collapse. We present here the first full 3-D modelling for the unrest of 1982–1985 including the effect of caldera bordering fractures and the topography. To model the presence of topography and of the complex caldera rim discontinuities, we used a mixed boundary elements method. The a priori caldera geometry is determined initially from gravimetric modelling results and refined by inversion. The presence of the caldera discontinuities allows a fit to the 1982–1985 levelling data as good as, or better than, in the continuous half-space case, with quite a different source depth which fits the actual magma chamber position as seen from seismic waves. These results show the importance of volcanic structures, and mainly of caldera collapses, in ground deformation episodes.     

Diesel oil and PCB-degrading psychrotrophic bacteria isolated from Antarctic seawaters (Terra Nova Bay, Ross Sea)

Fifty-seven Antarctic marine bacteria were examined for their ability to degrade commercial diesel oil as the sole organic substrate at both 4 °C and 20 °C. Based on the preliminary screening, two isolates (B11 and B15) with high capacity to degrade diesel oil were selected and their biodegradation efficiency was quantified by gas chromatographic analysis. As expected for psychrotrophs, diesel oil biodegradation was slower at 4 °C than at 20 °C. The two strains also mineralized the C₂₈ n-paraffin octacosane at 20 °C and polychlorinated biphenyls (PCBs) at 4 °C and 20 °C.     

Extensive impact melting on the H-chondrite parent asteroid during the cataclysmic bombardment of the early solar system: Evidence from the achondritic meteorite Dar al Gani 896

DaG 896 is an olivine-rich microporphyritic rock of komatiitic composition. Both the olivine composition (Fa_17.5±2.1, [Mn/Mg] = 0.0061) and the bulk oxygen isotopic composition (δ17O = +2.55, δ18O = +3.50) indicate that DaG 896 is a sample of the H-chondrite parent body. The bulk chemistry shows an H-chondritic distribution of lithophile elements, whereas chalcophile and siderophile elements are strongly depleted, indicating formation through whole-rock melting (or nearly so) of H-chondrite material, nearly complete loss of the metal plus sulfide component, and crystallization without significant igneous fractionation. Superheated, severely shocked chondritic relics (∼10 vol%), typically in the form of corroded lithic fragments <100 μm in size intimately distributed within the igneous lithology, indicate that melting was triggered by a highly energetic impact, which possibly induced shock pressures of ∼80-100 GPa. The relatively young 3.704 ± 0.035 Ga 40Ar-39Ar crystallization age is consistent with the impact melting origin, as magmatism in the asteroid belt was active only in the first hundred million years of solar system history.Based on textural data and thermodynamic crystallization modelling, we infer that DaG 896 crystallized from a liquidus temperature of ∼1630°C under relatively slow cooling rates (∼10°C h⁻¹) to ∼1300°C, before quenching. The two-stage cooling history indicates that a reasonable formation environment might be a dike intruding cooler basement below a crater floor. Metal-silicate fractionation may have been accomplished, at least at the centimeter-scale of the studied meteorite sample, through differential acceleration of immiscible liquids of different density during the intense flow regimes associated with the excavation and modification stages of the cratering mechanism. Alternatively, DaG 896 may represent a surface sample of a differentiated melt body at the floor of an impact crater, as gravitational settling appears to be an effective process at the surface of a chondritic parent asteroid: for metal particles 1 to 10 mm in size, typically observed in partially differentiated impact melt rocks, Stokes’ Law indicates a settling velocity >1 m h ⁻¹ during the first few hours of crystallization on asteroidal bodies of >25 km radius.The ∼3.7 Ga age of DaG 896 nearly overlaps with the slightly older resetting ages of H-chondrites (all impact melts) available from the literature, indicating that the H-chondrite parent asteroid underwent extensive impact melting at the enduring of the cataclysmic bombardment of the early solar system. Such an age overlap may also indicate early disruption of the initial H-chondrite parent asteroid.The close similarity between the bulk composition and degassing age of DaG 896 and silicate inclusions in IIE iron meteorites is further evidence in support of a common origin by impact melting and metal-silicate segregation on the H-chondrite parent asteroid. Our new high-precision oxygen isotopic measurements of H-chondrites (Δ17O = 0.77 ± 0.04) should be extended to IIEs to verify this possible petrogenetic link.     

The Alpine evolution of the Southern Alps around the Giudicarie faults: A Late Cretaceous to Early Eocene transfer zone

Data supporting relevant Late Cretaceous–Early Eocene sinistral displacement along the Giudicarie fault zone and a minor Neogene dextral displacement along the Periadriatic lineament are discussed. The pre-Adamello structural belt is present only in the internal Lombardy zone, located W of the Adamello massif. This belt is unknown in the Dolomites and surrounding areas located to the E of the Giudicarie lineament. Upper Cretaceous–Early Eocene thick syntectonic Flysch deposits of Lombardy and Giudicarie are well preserved along the southern and eastern border of the pre-Adamello belt (S-vergent Alpine orogen). Towards the E, in the Dolomites and in the Carnic Alps and external Dinarides, only incomplete remnants of Flysch deposits, Aptian–Albian and Turonian–Maastrichtian in age, are present. They can be considered as equivalent to those of Lombardy and Giudicarie formerly in connection to each other along the N-Giudicarie corridor. To the S, the syntectonic Flysch deposits are laterally replaced by the calcareous red pelagites of the Scaglia Rossa and by the carbonate shelf deposits of the Friuli (to the E) and Bagnolo (to the S) carbonate platforms. The different location in the southern structural accretion of the eastern and western opposite blocks (the Dolomites versus the pre-Adamello belt) can be related to the Cretaceous–Eocene convergence. In this frame, the N-Giudicarie fault has been considered as part of a former transfer zone, which produced the sinistral lateral displacement of the Southern Alps front for an amount of some 50 km. During the Late Eocene to Early Oligocene the transfer zone was mostly sealed by the Paleogene Adamello batholith. Oligocene to Neogene compressional evolution inverted the N-Giudicarie fault into a backthrust of the Austroalpine units over the South-Alpine chain.     

Millimetric properties of IRAS galaxies – III. Luminosity functions, sub-mm counts and contributions to the sky background

We exploit observations at 1.25 mm with the ESO–SEST telescope of a southern galaxy sample, selected from the IRAS PSC and complete to S ₆₀=2 Jy, to derive the FIR and mm luminosity functions and the conditional probability distributions of FIR and mm luminosity of galaxies. The reliability of these estimates is ensured by the good observed correlation of the far-infrared and mm emissions. This detailed knowledge of the millimetric properties of galaxies is used to simulate the extragalactic sub-mm sky (background intensity, small-scale anisotropy signals and discrete source statistics), which is the target of a variety of ground-based and space observatories. We find, in particular, that a recent tentative detection of a sub-mm background would require, if confirmed, strong evolution with cosmic time of the galaxy long-wavelength emissivity. We finally discuss ways to test such evolution with present and forthcoming facilities: while emphasizing the difficulty of achieving this with large mm telescopes on the ground (because of the poor atmospheric conditions of current sub-mm sites), we mention an interesting opportunity with the long-wavelength camera on ISO . Preliminary results of deep surveys, both from space and from the ground, seem indeed to require excess emission in the past by dusty galaxies with respect to no-evolution predictions.     

Natural hexavalent chromium in groundwaters interacting with ophiolitic rocks

Thirty of the 58 groundwaters sampled in September-October 2000 in the study area (La Spezia Province, Italy) have Mg-HCO₃ to Ca-HCO₃ composition, undetectable Cr(III) contents, and virtually equal concentrations of total dissolved Cr and Cr(VI). Therefore, dissolved Cr is present in toto as Cr(VI), with concentrations of 5-73 ppb. These values are above the maximum permissible level for drinking waters (5 ppb). Local ophiolites, especially serpentinites and ultramafites, are Cr-rich and represent a Cr source for groundwaters. However, since Cr is present as Cr(III) in rock-forming minerals, its release to the aqueous solution requires oxidation of Cr(III) to Cr(VI). This can be performed by different electron acceptors, including Mn oxides, H₂O₂, gaseous O₂, and perhaps Fe(III) oxyhydroxides. Based on this evidence and due to the absence of anthropogenic Cr sources, the comparatively high Cr(VI) concentrations measured in the waters of the study area are attributed to natural pollution.     

The Buffon's needle problem and the design of a geophysical survey

A logical procedure for designing a geophysical survey when sampling an area with a regular grid can be summarized as follows: model the expected anomaly, estimate the expected noise level, estimate the area of the anomaly above the noise level, choose the spacing, in both the x - and y -directions, of the measurement grid. This last step can be approached according to two main strategies: either when applying the sampling theorem to the shortest dimension of the anomaly or when using a coarser grid, leaving a more complete definition of the anomaly to a later fitting. When following this second option, it can be constructive to estimate the probability of intercepting a given anomaly with a specific segment of profile and a given profile spacing. This latter procedure is analysed by considering a rectangle approximating the plane projection of the anomaly shape and taking into account various ratios between the grid spacing and the rectangle sides. The formulae for estimating the probability of intersecting a given anomaly with a given segment of a given profile spacing are calculated. To demonstrate the accuracy of the results, a Monte-Carlo simulation on a synthetic magnetic map was performed, obtaining, for different ratios between the sides, segment length and profile interval, an agreement better than 0.1% with the analytical formulae.