Adsorption of REE(III)-humate complexes onto MnO2: Experimental evidence for cerium anomaly and lanthanide tetrad effect suppression

Experiments were conducted to evaluate the impact of organic complexation on the development of Ce anomalies and the lanthanide tetrad effect during the adsorption of rare-earth elements (REE) onto MnO₂. Two types of aqueous solutions—NaCl and NaNO₃—were tested at pH 5 and 7.5. Time-series experiments indicate that a steady-state is reached within less than 10 h when REE occur as free inorganic species, whereas steady state is not reached before 10 d when REE occur as REE-humate complexes. The distribution coefficients (K_d^REE) between suspended MnO₂ and solution show no or only very weak positive Ce anomaly or lanthanide tetrad effect when REE occur as humate complexes, unlike the results obtained in experiments with REE occurring as free inorganic species. Monitoring of dissolved organic carbon (DOC) concentrations show that log K_d^REE_organic/K_d^DOC ratios are close to 1.0, implying that the REE and humate remain bound to each other upon adsorption. Most likely, the Ce anomaly reduction/suppression in the organic experiments arises from a combination of two processes: (i) inability of MnO₂ to oxidize Ce(III) because of shielding of MnO₂ surfaces by humate molecules and (ii) Ce(IV) cannot be preferentially removed from solution due to quantitative complexation of the REE by organic matter. We suggest that the lack of lanthanide tetrad effect arises because the adsorption of REE-humate complexes onto MnO₂ occurs dominantly via the humate side of the complexes (anionic adsorption), thereby preventing expression of the differences in Racah parameters for 4f electron repulsion between REE and the oxide surface. The results presented here explain why, despite the development of strongly oxidizing conditions and the presence of MnO₂ in the aquifer, no (or insignificant) negative Ce anomalies are observed in organic-rich waters. The present study demonstrates experimentally that the Ce anomaly cannot be used as a reliable proxy of redox conditions in organic-rich waters or in precipitates formed at equilibrium with organic-rich waters.     

Discrete element model for crack propagation in brittle materials

We propose a discrete element model for brittle rupture. The material consists of a bidimensional set of closed‐packed particles in contact. We explore the isotropic elastic behavior of this regular structure to derive a rupture criterion compatible to continuum mechanics. We introduce a classical criterion of mixed mode crack propagation based on the value of the stress intensity factors, obtained by the analysis of two adjacent contacts near a crack tip. Hence, the toughness becomes a direct parameter of the model, without any calibration procedure. We verify the consistency of the formulation as well as its convergence by comparison with theoretical solutions of tensile cracks, a pre‐cracked beam, and an inclined crack under biaxial stress. Copyright © 2015 John Wiley & Sons, Ltd.     

Segmentation and kinematics of the North America‐Caribbean plate boundary offshore Hispaniola

We explored the submarine portions of the Enriquillo–Plantain Garden Fault zone (EPGFZ) and the Septentrional–Oriente Fault zone (SOFZ) along the Northern Caribbean plate boundary using high‐resolution multibeam echo‐sounding and shallow seismic reflection. The bathymetric data shed light on poorly documented or previously unknown submarine fault zones running over 200 km between Haiti and Jamaica (EPGFZ) and 300 km between the Dominican Republic and Cuba (SOFZ). The primary plate‐boundary structures are a series of strike‐slip fault segments associated with pressure ridges, restraining bends, step overs and dogleg offsets indicating very active tectonics. Several distinct segments 50–100 km long cut across pre‐existing structures inherited from former tectonic regimes or bypass recent morphologies formed under the current strike‐slip regime. Along the most recent trace of the SOFZ, we measured a strike‐slip offset of 16.5 km, which indicates steady activity for the past ~1.8 Ma if its current GPS‐derived motion of 9.8 ± 2 mm a^?1 has remained stable during the entire Quaternary.     

巴芬湾西部和格陵兰岛东部大气经向热量输送协同变化对夏季北极海冰的影响

利用欧洲中心气候再分析资料和美国国家冰雪数据中心北极海冰面积资料，分析了夏季北极海冰面积与前期大气经向热量输送年际变化的联系。结果表明：6月北半球中高纬大气的经向热量输送以瞬变热量形式为主，其中巴芬湾西部（B区）和格陵兰岛东部（G区）是瞬变热量向极区传输的两个通道，二者之间存在反位相的协同变化，且这种协同变化与夏季北极海冰面积变化密切相关。可能的机制为：6月，AD、AO和NAO三种北极大气环流型能够引起巴芬湾西部和格陵兰岛东部瞬变热量输送的协同变化，这种协同变化通过涡旋动力作用激发夏季极区大气表现为AD异常，同时影响途经区域的气温，从而通过热动力作用影响夏季北极海冰。将向极区输送的热量称为暖输送，从极区输出的热量为冷输送，则上述两个区域的瞬变热量协同输送可分为三种情况：B暖G冷、B冷G暖、B和G均冷，而B和G均暖的情况十分罕见。当B区向极区输入、G区输出热量时，有利于太平洋扇区和喀拉海的海冰偏少；当G区输入、B区输出热量时，利于喀拉海和拉普捷夫海海冰偏少；当B区和G区均输出热量时，利于波佛特海南部、喀拉海和拉普捷夫海海冰偏多，反之则相反。     

Soil cracking effects on hydrological and erosive processes: a study case in Mediterranean cultivated vertisols

Shrink–swell soils, such as those in a Mediterranean climate regime, can cause changes in terms of hydrological and erosive responses because of the changing soil water storage conditions. Only a limited number of long‐term studies have focused on the impacts on both hydrological and erosive responses and their interactions in an agricultural environment. In this context, this study aims to document the dynamics of cracks, runoff and soil erosion within a small Mediterranean cultivated catchment and to quantify the influence of crack processes on the water and sediment supplied to a reservoir located at the catchment outlet using water and sediment measurements at a cultivated field outlet as baseline. Detailed monitoring of the presence of topsoil cracks was conducted within the Kamech catchment (ORE OMERE, Tunisia), and runoff and suspended sediment loads were continuously measured over a long period of time (2005–2012) at the outlets of a field (1.32 ha) and a catchment (263 ha). Analysis of the data showed that topsoil cracks were open approximately half of the year and that the rainfall regime and water table level conditions locally control the seasonal cracking dynamics. Topsoil cracks appeared to seriously affect the generation of runoff and sediment concentrations and, consequently, sediment yields, with similar dynamics observed at the field and catchment outlets. A similar time lag in the seasonality between water and sediment delivery was observed at these two scales: although the runoff rates were globally low during the presence of topsoil cracks, most sediment transport occurred during this period associated with very high sediment concentrations. This study underlines the importance of a good prediction of runoff during the presence of cracks for reservoir siltation considerations. In this context, the prediction of cracking effects on runoff and soil erosion is a key factor for the development of effective soil and water management strategies and downstream reservoir preservation. Copyright © 2016 John Wiley & Sons, Ltd.     

High-resolution fluvial records of Holocene environmental changes in the Sahel: the Yamé River at Ounjougou (Mali,West Africa)

The Yamé river, in the Bandiagara Plateau, Dogon Country, Mali, is characterised by extensive alluvial sedimentary records, particularly in the 1 km long Ounjougou reach where Holocene floodplain pockets are inset in the Pleistocene formations. These alluvial records have been investigated via geomorphologic fieldwork and sedimentologic and micromorphologic analyses and are supported by 79 radiocarbon dates. The alluvial deposits of the valley floor correspond to a vertical accretion of 3–10 m. The reconstruction of fluvial style changes provides evidence of four main aggradation periods. From 11,500 to 8760 cal. BP, the alluvial architecture and grain-size parameters indicate a wandering river. This period included phases of pulsed high-energy floods and avulsion related to a northward shift of the summer monsoon to around 14°N after 11,500 cal. BP. From 7800 to 5300 cal. BP, a swampy floodplain environment with standing water pools within a Sudanian savanna/woodland mosaic corresponds to the culmination of the Holocene humid period. From 3800 cal. BP onwards, rhythmic sedimentation attests to an increase in the duration and/or intensity of the dry season, giving a precise date for the local termination of the Holocene Optimum period. During the last two millennia and for the first time during the Holocene, the alluvial formations are progressively restricted whereas the colluvial deposits increase, indicating strong soil erosion and redeposition within the watershed related to an increase in human impact. Four major periods are characterised by incision (I1: ante 11,500, I2: 8760–7800; I3: 6790–6500 cal. BP; I4; 2400–1700 cal. BP) pointing to dramatic changes in fluvial style. They result from high-energy flood flows during dry spells and confirm the capacity of the floodplain pocket in the upstream reach of the Sahelian belt to record rapid Holocene climatic change.     

Projected rainfall and temperature changes over Malaysia at the end of the 21st century based on PRECIS modelling system

This study investigates projected changes in rainfall and temperature over Malaysia by the end of the 21st century based on the Intergovernmental Panel on Climate Change (IPCC) Special Report on Emission Scenarios (SRES) A2, A1B and B2 emission scenarios using the Providing Regional Climates for Impacts Studies (PRECIS). The PRECIS regional climate model (HadRM3P) is configured in 0.22° × 0.22° horizontal grid resolution and is forced at the lateral boundaries by the UKMO-HadAM3P and UKMOHadCM3Q0 global models. The model performance in simulating the present-day climate was assessed by comparing the modelsimulated results to the Asian Precipitation - Highly-Resolved Observational Data Integration Towards Evaluation (APHRODITE) dataset. Generally, the HadAM3P/PRECIS and HadCM3Q0/PRECIS simulated the spatio-temporal variability structure of both temperature and rainfall reasonably well, albeit with the presence of cold biases. The cold biases appear to be associated with the systematic error in the HadRM3P. The future projection of temperature indicates widespread warming over the entire country by the end of the 21st century. The projected temperature increment ranges from 2.5 to 3.9°C, 2.7 to 4.2°C and 1.7 to 3.1°C for A2, A1B and B2 scenarios, respectively. However, the projection of rainfall at the end of the 21st century indicates substantial spatio-temporal variation with a tendency for drier condition in boreal winter and spring seasons while wetter condition in summer and fall seasons. During the months of December to May, ~20-40% decrease of rainfall is projected over Peninsular Malaysia and Borneo, particularly for the A2 and B2 emission scenarios. During the summer months, rainfall is projected to increase by ~20-40% across most regions in Malaysia, especially for A2 and A1B scenarios. The spatio-temporal variations in the projected rainfall can be related to the changes in the weakening monsoon circulations, which in turn alter the patterns of regional moisture convergences in the region.     

基于GeoSOT剖分编码的不动产单元统一标识模型研究

针对现有不动产单元编码存在空间位置信息模糊的问题,以寻求更加直接反映空间位置的不动产编码为目标,在对现有不动产单元编码深入研究的基础上,提出了基于GeoSOT网格编码的不动产单元模型、编码方法,以及该模型与空间位置信息转换方案。试验证明,基于GeoSOT的不动产单元编码更加直观,具有很好的实用性。