Nanometric solid inclusions in diamond incorporated in garnet and zircon from felsic gneiss of the Kokchetav massif, Kazakhstan, have been examined utilizing electron microscopy and focused ion beam techniques. Host garnet and zircon contain numerous pockets of multiple inclusions, which consist of 1–3 diamond crystals intergrown with quartz, phengite, phlogopite, albite, K‐feldspar, rutile, apatite, titanite, biotite, chlorite and graphite in various combinations. Recalculation of the average chemical composition of the entrapped fluid represented by multiple inclusion pockets indicates that such fluid contained a low wt% of SiO2, suggesting a relatively low‐temperature fluid rather than a melt. Transmission electron microscopy revealed that the diamond contains abundant nanocrystalline inclusions of oxides, rare carbonates and silicates. Within the 15 diamond crystals studied, abundant inclusions were found of SiO2, TiO2, FexOy, Cr2O3, ZrSiO4, and single grains of ThxOy, BaSO4, MgCO3, FeCr2O4 and a stoichiometric Fe‐rich pyroxene. The diversity of trace elements within inclusions of essentially the same stoichiometry suggests that the Kokchetav diamond crystallized from a fluid containing variable amounts of Si, Fe, Ti, Cr, Zr, Ba, Mg and Th and other minor components such as K, Na, P, S, Pb, Zn, Nb, Al, Ca, Cl. Most of the components in crystals included in diamond appear to have their origin in the subducted metasediments, but some of them probably originate from the mantle. It is concluded that Kokchetav diamond most likely crystallized from a COH‐rich multicomponent supercritical fluid at a relatively low temperature (hence the apparently low content of rock‐forming elements), and that the diversity of major and minor components suggests interactions between subducted metasediments and mantle components. 相似文献
Climate impacts on coastal and estuarine systems take many forms and are dependent on the local conditions, including those
set by humans. We use a biocomplexity framework to provide a perspective of the consequences of climate change for coastal
wetland ecogeomorphology. We concentrate on three dimensions of climate change affects on ecogeomorphology: sea level rise,
changes in storm frequency and intensity, and changes in freshwater, sediment, and nutrient inputs. While sea level rise,
storms, sedimentation, and changing freshwater input can directly impact coastal and estuarine wetlands, biological processes
can modify these physical impacts. Geomorphological changes to coastal and estuarine ecosystems can induce complex outcomes
for the biota that are not themselves intuitively obvious because they are mediated by networks of biological interactions.
Human impacts on wetlands occur at all scales. At the global scale, humans are altering climate at rapid rates compared to
the historical and recent geological record. Climate change can disrupt ecological systems if it occurs at characteristic
time scales shorter than ecological system response and causes alterations in ecological function that foster changes in structure
or alter functional interactions. Many coastal wetlands can adjust to predicted climate change, but human impacts, in combination
with climate change, will significantly affect coastal wetland ecosystems. Management for climate change must strike a balance
between that which allows pulsing of materials and energy to the ecosystems and promotes ecosystem goods and services, while
protecting human structures and activities. Science-based management depends on a multi-scale understanding of these biocomplex
wetland systems. Causation is often associated with multiple factors, considerable variability, feedbacks, and interferences.
The impacts of climate change can be detected through monitoring and assessment of historical or geological records. Attribution
can be inferred through these in conjunction with experimentation and modeling. A significant challenge to allow wise management
of coastal wetlands is to develop observing systems that act at appropriate scales to detect global climate change and its
effects in the context of the various local and smaller scale effects. 相似文献
The palaeoenvironment of the Karelian Isthmus area during the Litorina Sea stage of the Baltic Sea history, between 8.0 and 4.5 kyr BP (8.8-5.2 cal. kyr BP), was reconstructed by studying four sites located on the Karelian Isthmus in Russia. Methods included diatom and pollen analyses, sediment lithostratigraphical interpretation and 14C dating. The brackish-water (Litorina) transgression began c. 7.7 kyr BP (8.45 cal. kyr BP) in the Karelian Isthmus area. The transgression maximum occurred between 6.7 and 5.7 kyr BP (7.6-6.5 cal. kyr BP), depending on the glacio-isostatic land uplift rate. Regarding the vegetation, the maximum occurrence of temperate deciduous trees took place at the same time. The transgression was interrupted by a short-lived sea-level standstill during the middle phase of the main transgression, c. 6.3 kyr BP (7.2 cal. kyr BP), on the eastern part of the isthmus. The highest Litorina shoreline is located between 8 and 13 m above present sea-level and the amplitude of the Litorina transgression has varied between 5 and 7 m. The 8.2-kyr cold event is not evident, but the sea-level standstill around 6.3 kyr BP (7.2 cal. kyr BP) could reflect a cool episode at that time in the Karelian Isthmus area. 相似文献
Most ion irradiation experiments relevant to primitive outer Solar System objects have been performed on ice and silicate targets. Here we present the first ion irradiation experiments performed on natural complex hydrocarbons (asphaltite and kerite). These materials are very dark in the visible and have red-sloped spectra in the visible and near-infrared. They may be comparable in composition and structure to refractory organic solids on the surfaces of primitive outer Solar System objects. We irradiated the samples with 15-400 keV H+, N+, Ar++, and He+ ions and measured their reflectance spectra in the range of 0.3-2.5 μm before ion implantation and after each irradiation step. The results show that irradiation-induced carbonization gradually neutralizes the spectral slopes of these red organic solids. This implies a similar space weathering trend for the surfaces of airless bodies optically dominated by spectrally red organic components. The reduction of spectral slope was observed in all experiments. Irradiation with 30 keV protons, which transfers energy to the target mostly via electronic (inelastic) collisions, showed lower efficiency than the heavier ions. We found that spectral alteration in our experiments increased with increasing contribution of nuclear versus electronic energy loss. This implies that nuclear (elastic) energy deposition plays an important role in changing the optical properties of irradiated refractory complex hydrocarbon materials. Finally, our results indicated that temperature variations from 40 K to room temperature did not influence the spectral properties of these complex hydrocarbon solids. 相似文献
A biocide decay model was developed to assess the potential efficacy and environmental impacts associated with using glutaraldehyde to treat unballasted overseas vessels trading on the Laurentian Great Lakes. The results of Monte Carlo simulations indicate that effective glutaraldehyde concentrations can be maintained for the duration of a vessel's oceanic transit (approximately 9-12 days): During this transit, glutaraldehyde concentrations were predicted to decrease by approximately 10% from initial treatment levels (e.g., 500 mgL(-1)). In terms of environmental impacts, mean glutaraldehyde concentrations released at Duluth-Superior Harbor, MN were predicted to be 100-fold lower than initial treatment concentrations, and ranged from 3.2 mgL(-1) (2 SD: 2.74) in April to 0.7 mgL(-1) (2 SD: 1.28) in August. Sensitivity analyses indicated that the re-ballasting dilution factor was the major variable governing final glutaraldehyde concentrations; however, lake surface temperatures became increasingly important during the warmer summer months. 相似文献
Arsenic (As), iron (Fe), and manganese (Mn) contents were measured in sediment nodules and associated pore waters obtained from sediment cores collected from a salt marsh on Pólvora Island (southern Brazil). Sediment cores were obtained when brackish water dominated the estuary, at two different environments: an unvegetated mudflat colonized by crabs (Neohelice granulata), and a low intertidal stand vegetated by Spartina alterniflora. We determined the percentage of nodules in each depth interval of the cores, along with redox potential, and As, Fe, and Mn contents of the nodules. The mineralogy of the nodules was investigated, and results showed they are mainly composed by quartz, phyllosilicates, and amorphous Fe–Mn oxides/oxyhydroxides. Pore water results showed that bioturbation by local crabs supports oxygen penetration to depths of ca. 25 cm below the salt marsh surface, with lower Fe contents in pore water associated with the brackish period. However, S. alterniflora growth appears to have a greater impact on sediment geochemistry of Fe, Mn, and possibly As due to sulfate reduction and the associated decrease in pore water pH. Higher Fe concentrations were observed in the pore waters during the period of brackish water dominance, which also corresponded to the S. alterniflora growth season. The study demonstrates that differences in geochemical conditions (e.g., Fe content) that can develop in salt marsh sediments owing to different types of bioirrigation processes (i.e., bioirrigation driven by crabs versus that related to the growth of S. alterniflora) play important roles in the biogeochemical cycling of As.