Behavior of Trace Elements during Oxidation of Sphalerite of the Irinovskoe Hydrothermal Sulfide Field (13°20′ N,Mid-Atlantic Ridge)

Geology of Ore Deposits - The formation of present-day seafloor sulfide deposits is accompanied by their continuous oxidation and crystallization of insoluble Fe oxyhydroxides, which absorb metals...     

Pb‐isotope compositions of the Tasik Chini volcanic‐hosted massive sulfide deposit,Central Belt of Peninsular Malaysia: Implication for source region and tectonic setting

Lead isotope data of sulfides and host volcanic rocks from the Bukit Botol and Bukit Ketaya deposits, the two representative deposits of the Tasik Chini volcanic‐hosted massive sulfide (VHMS) deposit, Central Belt of Peninsular Malaysia, are reported. Lead isotope compositions of the associated sulfide minerals and volcanic rocks from the Bukit Botol deposit exhibit homogeneous and less radiogenic values (²⁰⁶Pb/²⁰⁴Pb showing a range of composition from 18.14 to 18.20, ²⁰⁷Pb/²⁰⁴Pb between 15.52 and 15.59 and ²⁰⁸Pb/²⁰⁴Pb from 37.96 to 38.35). Similarly, the Pb isotopic compositions of the host volcanic rocks from the Bukit Ketaya deposit yielded a narrow range to those of the sulfide samples (²⁰⁶Pb/²⁰⁴Pb from 18.04 to 18.20, ²⁰⁷Pb/²⁰⁴Pb between 15.43 and 15.57 and ²⁰⁸Pb/²⁰⁴Pb of 37.96 to 38.30). The uniform Pb‐isotope compositions of the sulfides in the ore horizon and the host volcanic rocks from both deposits suggest a derivation from a similar source reservoir and mineralization processes. In the framework of the tectonic model for the Central Belt of Peninsular Malaysia, both deposits display a range of lead isotopic compositions originated from mixing of bulk crust/juvenile arc and minor mantle sources, which are typical for VHMS deposits in an island arc–back arc setting.     

A high‐resolution record of mire development and climatic change spanning the Late‐glacial–Holocene boundary at Church Moss,Davenham (Cheshire,England)

Excavations of deposits filling a closed basin within glacial drift at Church Moss, Davenham, near Northwich (Cheshire, England) revealed a sequence of Late‐glacial and Early Holocene sediments. Analyses of pollen and plant and invertebrate macrofossils were undertaken, together with loss‐on‐ignition analyses and a programme of AMS radiocarbon dating, to provide a record of changing biostratigraphy and climatic and ecological regimes. The infilling of features identified as frost‐cracks in the till flooring the basin gave remains that reflected conditions of extreme cold towards the end of the Devensian. The pollen record from a 3.5 m sequence of peat towards the deepest part of the basin, supported by radiocarbon dates, shows that organic deposition was initiated during the Late‐glacial Interstadial and continued into the early part of the Holocene. There was some evidence for a cool episode during the interstadial, with amelioration prior to the rapid onset of the tundra conditions of the Loch Lomond Stadial. Following the stadial, amelioration was rapid. There was evidence from both central and marginal sequences for a mosaic of fen dominated by sedges and often also mosses, with short‐lived small pools through much of the succession. Change to terrestrial conditions proceeded intermittently, probably as a result of subsidence caused by solution of underlying salt‐bearing strata. Copyright © 2000 John Wiley & Sons, Ltd.     

Coordinated Ocean-ice Reference Experiments (COREs)

Coordinated Ocean-ice Reference Experiments (COREs) are presented as a tool to explore the behaviour of global ocean-ice models under forcing from a common atmospheric dataset. We highlight issues arising when designing coupled global ocean and sea ice experiments, such as difficulties formulating a consistent forcing methodology and experimental protocol. Particular focus is given to the hydrological forcing, the details of which are key to realizing simulations with stable meridional overturning circulations.The atmospheric forcing from [Large, W., Yeager, S., 2004. Diurnal to decadal global forcing for ocean and sea-ice models: the data sets and flux climatologies. NCAR Technical Note: NCAR/TN-460+STR. CGD Division of the National Center for Atmospheric Research] was developed for coupled-ocean and sea ice models. We found it to be suitable for our purposes, even though its evaluation originally focussed more on the ocean than on the sea-ice. Simulations with this atmospheric forcing are presented from seven global ocean-ice models using the CORE-I design (repeating annual cycle of atmospheric forcing for 500 years). These simulations test the hypothesis that global ocean-ice models run under the same atmospheric state produce qualitatively similar simulations. The validity of this hypothesis is shown to depend on the chosen diagnostic. The CORE simulations provide feedback to the fidelity of the atmospheric forcing and model configuration, with identification of biases promoting avenues for forcing dataset and/or model development.     

Lead isotope data from selected galena occurrences in the North Eifel and North Sauerland,Germany

The isotopic ratios of Pb have been determined from 33 galena samples collected from a variety of occurrences in the north Eifel and north Sauerland. On the basis of the data presented, it is not possible to distinguish between the isotopic characteristics of galena-Pb from veins, carbonate cavity-filling and sandstone-hosted disseminated mineralisation in the north Eifel. In the north Sauerland, Saxonian (late Mesozoic-Tertiary) disseminated Pb mineralisation in Cretaceous-Tertiary sediments is generally more radiogenic than Saxonian vein mineralisation in Paleozoic country rocks. Variscan vein-type mineralisation (Ramsbeck, Ebbe Mountains) proved to have the least radiogenic Pb. The results are discussed in terms of potential sources of the Pb, and are compared to other data reported from European deposits.     

Quantifying channel development and sediment transfer following chute cutoff in a wandering gravel-bed river

Three-dimensional morphological adjustment in a chute cutoff (breach) alluvial channel is quantified using Digital Elevation Model (DEM) analysis for a ca. 0.7 km reach of the River Coquet, Northumberland, UK. Following cutoff in January 1999, channel and bar topography was surveyed using a Total Station on five occasions between February 1999 and December 2000. Analysis of planform change coupled with DEM differencing elucidates channel and barform development following cutoff, and enables quantification of sediment transfers associated with morphological adjustment within the reach. This exercise indicates an initial phase of bed scour, followed by a period characterised by extensive bank erosion and lateral channel migration where erosion (including bed scour) totalled some 15,000 m³ of sediment. The channel in the post-cutoff, disequilibrium state is highly sensitive to relatively low-magnitude floods, and provision of accommodation space by bank erosion encouraged extensive lateral bar development. Bar development was further facilitated by infilling of channels abandoned by repeated within-reach avulsion and large-scale aggradation of sediment lobes deposited by higher magnitude floods. Calculations indicate that at least 6600 m³ of sediment was deposited on emerging bars within the reach over the survey period, and >2300 m³ deposited within the channel. Sediment losses from the reach may have exceeded 6500 m³.     

Mapping hydraulic biotopes using terrestrial laser scan data of water surface properties

For more than a decade, habitat mapping using biotopes (in‐channel hydraulically‐defined habitats) has underpinned aquatic conservation in the UK through (a) providing baseline information on system complexity and (b) allowing environmental and ecological change to be monitored and evaluated. The traditional method used is the subjective river habitat or corridor survey. This has recently been revised to include the floodplain via GeoRHS, but issues still exist concerning development of a national database due to the labour intensive nature of the data collection, subjectivity issues between samplers, temporal changes, the fuzzy nature of perceived habitats and habitat boundaries. This paper takes an innovative approach to biotope definition using high resolution spatial data to define water surface roughness for two representative reaches of the River South Tyne, Cumbria, and the River Rede, Northumberland, UK. Data was collected using a terrestrial laser scanner (TLS) and hydraulic variability simply expressed through assigning a local standard deviation value to a set of adjacent water surface values. Statistical linkage of these data with biotope locations defined visually in the field allowed complete mapping of the surveyed reach defining habitat and biotope areas to the fine scale resolution of the TLS data. Despite issues of data loss due to absorption and transmission through the water, the reflected signal generated an extremely detailed and objective map of the water surface roughness, which may be compared with known biotope locations as defined by visual identification in the field. The TLS accuracy achieved in the present study is comparable with those obtained using hyperspectral imagery: with 84% of the pool/glide/marginal deadwater amalgamated biotope, 88% of riffles, 57% of runs and 50% of the amalgamated cascade/rapid biotope successfully plotted. It is clear from this exercise that biotope distribution is more complex than previously mapped using subjective techniques, and based upon the water surface roughness delimiters presented in this study, the amalgamation of pools with glides and marginal deadwaters, riffles with unbroken standing waves, and cascades with rapids, is proposed. Copyright © 2010 John Wiley & Sons, Ltd     

Criteria for the detection of hydrothermal ecosystem faunas in ores of massive sulfide deposits in the Urals

The ore-formational, ore-facies, lithological, and mineralogical-geochemical criteria are defined for the detection of hydrothermal ecosystem fauna in ores of the volcanic-hosted massive sulfide deposits in the Urals. Abundant mineralized microfauna is found mainly in massive sulfide mounds formed in the jasperous basalt (Buribai, Priorsk, Yubileinoe, Sultanov), rhyolite–basalt (Yaman-Kasy, Blyava, Komosomol’sk, Sibai, Molodezhnoe, Valentorsk), and the less common serpentinite (Dergamysh) formations of the Urals (O–D2). In the ore-formational series of the massive sulfide deposits, probability of the detection of mineralized fauna correlates inversely with the relative abundance of felsic volcanic rocks underlying the ores. This series is also marked by a gradual disappearance of colloform pyrite, marcasite, isocubanite, pyrrhotite, and pyrite pseudomorphoses after pyrrhotite; increase of the amount of bornite, fahlores, and barite; decrease of contents of Se, Te, Co, and Sn in chalcopyrite and sphalerite; and decrease of Tl, As, Sb, and Pb in the colloform pyrite. Probability of the detection of mineralized fauna in the morphogenetic series of massive sulfide deposits decreases from the weakly degraded sulfide mounds to the clastic stratiform deposits. The degradation degree of sulfide mounds and fauna preservation correlates with the attenuation of volcanic intensity, which is reflected in the abundance of sedimentary and volcanosedimentary rocks and the depletion of effusive rocks in the geological sections.