酶法催化餐饮废油制备生物柴油的研究

以废物资源转化为宗旨,利用固定化脂肪酶催化餐饮废油与乙醇反应制备生物柴油,通过实验获得最佳酯化反应条件:反应温度47℃、有机溶剂为正己烷、醇油比3∶1,5次投加乙醇,酶用量为0.3g,反应时间32h时,生物柴油产率可达81%。     

大洋粘土制备白炭黑后的铝回收实验研究

为了回收大洋粘土制备白炭黑后残液中的Al3 ,并获得氧化铝超细粉体,实验选用NH3.H2O为沉淀剂,在常温下采用沉淀法使残液中Al3 以氢氧化铝形式沉淀并去除其它杂质离子,然后将得到的沉淀在1200℃灼烧,保温1h。利用IR和XRD测试了产物的物相组成和结构,证实实验可以获得纯度较高的α-Al2O3;而SEM和粒度分析结果显示产物粒度细小,部分颗粒可以达到纳米级;BET结果显示Al2O3的比表面积可达32m2/g。根据氧化铝结构和性能等优选的实验条件为大洋粘土的进一步开发利用提供了参考依据。     

层状介质高频电磁场响应及位移电流影响

所讨论的电磁场频率介于传统的低频电磁法和雷达频率之间。在这个频率范围内,传导电流和位移电流都是不可忽略的。采用高密度采样算法计算水平层状磁偶线圈模型的电磁响应,通过对归一化的电磁响应在不同地电情况的模拟,比较分析了高频电磁场响应特征以及位移电流对高频电磁响应的贡献。     

致密砂岩孔隙度计算方法

鄂尔多斯盆地北部下二叠系下石盒子组为纵横向变化大,岩性、孔隙结构等复杂的河流相地层,很难用统一的计算公式来完成对孔隙度的计算。采用多元统计分析、散点图和孔隙度对比图来确定其孔隙度。运用上述方法,比较精确地确定鄂尔多斯盆地北部下二叠系下石盒子组的孔隙度,对鄂尔多斯盆地油气储量的估计,提供一个很好的基础资料。     

Detrital Zircon of 4100 Ma in Quartzite in Burang, Tibet

A detrital zircon aged 4.1 Ga is discovered by the SHRIMP U-Pb method in a quartzite in Burang County, western Tibet. This is presently the oldest single-grain detrital zircon in China. The Th-U ratios of the two testing points of the 〉4.0 Ga zircon are between 0.76 and 0.86, indicating their magmatic origin. This discovery has offered an important age for investigating the geological evolution of the Qinghai-Tibet Plateau.     

Evolution from Oceanic Subduction to Continental Collision: a Case Study from the Northern Tibetan Plateau Based on Geochemical and Geochronological Data

Two apparently distinct, sub-parallel, paleo-subduction zonescan be recognized along the northern margin of the Tibetan Plateau:the North Qilian Suture Zone (oceanic-type) with ophioliticmélanges and high-pressure eclogites and blueschistsin the north, and the North Qaidam Belt (continental-type) inthe south, an ultrahigh-pressure (UHP) metamorphic terrane comprisingpelitic and granitic gneisses, eclogites and garnet peridotites.Eclogites from both belts have protoliths broadly similar tomid-ocean ridge basalts (MORB) or oceanic island basalts (OIB)in composition with overlapping metamorphic ages (480–440Ma, with weighted mean ages of 464 ± 6 Ma for North Qilianand 457 ± 7 Ma for North Qaidam), determined by zirconU–Pb sensitive high-resolution ion microprobe dating.Coesite-bearing zircon grains in pelitic gneisses from the NorthQaidam UHP Belt yield a peak metamorphic age of 423 ±6 Ma, 40 Myr younger than the age of eclogite formation, anda retrograde age of 403 ± 9 Ma. These data, combinedwith regional relationships, allow us to infer that these twoparallel belts may represent an evolutionary sequence from oceanicsubduction to continental collision, and continental underthrusting,to final exhumation. The Qilian–Qaidam Craton was probablya fragment of the Rodinia supercontinent with a passive marginand extended oceanic lithosphere in the north, which was subductedbeneath the North China Craton to depths >100 km at c. 423Ma and exhumed at c. 403 Ma (zircon rim ages in pelitic gneiss). KEY WORDS: HP and UHP rocks; subduction belts; zircon SHRIMP ages; Northern Tibetan Plateau     

济阳坳陷CO0_2气藏同位素地球化学特征及成因

济阳坳陷CO2气藏主要发育在高青-平南深断裂中南段和阳信次级凹陷西北缘及商店火山岩穹隆构造内。气藏中CO2气体浓度为69%~97%,δ13CCO2值为-5.67‰~-3.35‰,CH4/3He值为(1.01~5.65)×108,3He/4He值为(2.80~4.49)×10-6,即R/Ra为2.00~3.21,40Ar/36Ar值为317~1791,CO2/3He值为(0.25~2.61)×109。以上地球化学数据表明,济阳坳陷气藏中CO2主要来源于地幔,且幔源CO2在成藏过程中有损失,或者有壳源CO2的加入,特别是部分碳酸盐岩变质成因CO2的加入。在对CO2气来源定性分析的基础上,还需要在各来源的定量区分和CO2气藏的成藏及其与岩浆活动的时空匹配关系等方面作进一步的研究。     

重力斜导数方法在时间域中的理论模型与研究

Miller和Singh在1994年首次提出了斜导数(Tilt梯度)的定义,J.Derek Fairhead和Chris M.Green又于2004年在斜导数的基础上提出了Tilt梯度水平导数的概念。国内学者已对斜导数及斜导数水平导数展开研究,设定了多体模型、无限延伸倾斜脉模型、有限延伸倾斜台阶模型及埋深相同无限延伸垂直厚板及薄板模型,得出一些结论。针对一些地质体产状的判断,提出非绝对值斜导数水平导数的新概念,并应用于理论模型中验证,得出正确的结论。在上述理论模型基础上补充了断层模型和无限延伸倾斜台阶模型,应用非绝对值水平导数的理论解释地质体的产状,并对上述模型提出新的观点和看法。