Increasing Use of Human-Dominated Habitats as CO<Subscript>2</Subscript> Emissions Warm and Acidify Oceans

Urban and artificial structures are increasingly added to the world’s coasts during a time in which changing climate is forecast to drive shifts in naturally occurring habitats. We ask whether the role of artificial structures as marine habitats will increase in importance relative to their natural counterparts, particularly as natural habitats are negatively affected by ocean warming and acidification. To evaluate this model, we contrasted use of natural (kelp forest and turfing algae) and artificial habitat (plastic pier-piling) by a nest-building amphipod (Cymadusa pemptos) under current and future climate conditions of CO₂ and temperature. Under future conditions, amphipod populations in mesocosms increased, but this did not lead to greater proportional colonization of kelp and turf. Instead, colonization doubled in artificial habitats, and there was increasing production and occupation of nests on artificial habitats relative to natural habitats. In an age when human modification of natural substrata is increasingly cited as an agent of wildlife decline, understanding the future role of artificial habitats as replacement dwellings for natural habitats is critical. We pioneer an understanding of the future role of natural and artificial habitats, identifying the possibility that the role of urban structures as marine habitats may only increase.     

Machine Learning Predictions of pH in the Glacial Aquifer System,Northern USA

A boosted regression tree model was developed to predict pH conditions in three dimensions throughout the glacial aquifer system of the contiguous United States using pH measurements in samples from 18,386 wells and predictor variables that represent aspects of the hydrogeologic setting. Model results indicate that the carbonate content of soils and aquifer materials strongly controls pH and, when coupled with long flowpaths, results in the most alkaline conditions. Conversely, in areas where glacial sediments are thin and carbonate-poor, pH conditions remain acidic. At depths typical of drinking-water supplies, predicted pH >7.5—which is associated with arsenic mobilization—occurs more frequently than predicted pH <6—which is associated with water corrosivity and the mobilization of other trace elements. A novel aspect of this model was the inclusion of numerically based estimates of groundwater flow characteristics (age and flowpath length) as predictor variables. The sensitivity of pH predictions to these variables was consistent with hydrologic understanding of groundwater flow systems and the geochemical evolution of groundwater quality. The model was not developed to provide precise estimates of pH at any given location. Rather, it can be used to more generally identify areas where contaminants may be mobilized into groundwater and where corrosivity issues may be of concern to prioritize areas for future groundwater monitoring.     

Effect of vegetation cover and sediment type on 3D subsurface structure and shear strength in saltmarshes

The vulnerability of saltmarshes to lateral erosion at their margin depends on the local biogeomorphological properties of the substrate. In particular, the 3D architecture of pore and root systems is expected to influence shear strength, with repercussions for the wider-scale stability of saltmarshes. We apply X-ray computed microtomography (μCT) to visualize and quantify subsurface structures in two UK saltmarshes at Tillingham Farm, Essex (silt/clay rich substrate) and Warton Sands (sand-rich substrate), with four types of ground cover: bare ground, Spartina spp, Salicornia spp and Puccinellia spp. We extracted μCT structural parameters that characterize pore and root morphologies at each station, and compared them with field measurements of shear strength using a principal component analysis and correlation tests. The 3D volumes show that species-dependent variations in root structures, plant colonization events and bioturbation activity control the morphology of macropores, while sediment cohesivity determines the structural stability and persistence of these pore structures over time, even after the vegetation has died. Areas of high porosity and high mean pore thickness were correlated to lower values of shear strength, especially at Tillingham Farm, where well-connected vertical systems of macropores were associated with current or previous colonization by Spartina spp. However, while well-connected systems of macropores may lower the local deformation threshold of the sediment, they also encourage drainage, promote vegetation growth and reduce the marsh vulnerability to hydrodynamic forces. The highest values of shear strength at both sites were found under Puccinellia spp, and were associated with a high density of mesh-like root structures that bind the sediment and resist deformation. Future studies of marsh stability should ideally consider time series of vegetation cover, especially in silt/clay-dominated saltmarshes, in order to consider the potential effect of preserved buried networks of macropores on water circulation, marsh functioning and cliff-face erosion.     

Deep‐sea channel evolution and stratigraphic architecture from inception to abandonment from high‐resolution Autonomous Underwater Vehicle surveys offshore central California

The Lucia Chica channel system is an avulsion belt with four adjacent channels that progressively avulsed to the north‐east from a single, upslope feeder channel. Avulsion occurred from underfilled channels, leaving open channels that were reactivated by flows stripped from younger, adjacent channels. Differences in relief (height from channel thalweg to levée crest), sinuosity and levée stratigraphy between adjacent channels correspond to relative channel age, and indicate a change in channel morphology and architecture with time. Potential triggers for the change over time include differences in gradient, flow behaviour and characteristics, and channel evolution. Gradient does not appear to be a major control on channel formation and avulsion because adjacent channels formed on the same gradient. Based on available ultra‐high‐resolution remote imaging obtained with an Autonomous Underwater Vehicle, differences in adjacent channel morphology are interpreted to be primarily a result of differences in channel maturity. The interpreted sequence of channel maturity involves erosional channel inception through scouring and incipient channels (defined by linear trains of scours) prior to development of continuous thalwegs. Channel narrowing, formation and growth of levées, increasing channel relief and development of sinuosity occurred as channels evolved. The evolutionary sequence interpreted from the high‐resolution Lucia Chica dataset provides a unique perspective on intrinsic controls of architecture for single channel elements. In addition to helping bridge the gap between outcrop and industry‐standard reflection‐seismic data resolutions and scopes, interpretations in this study also expose potential problems with hierarchical classifications in three‐dimensional imaging of distributary systems, and provide potentially important analogues for evolutionary morphologies not resolved in other deep‐water channel systems.     

An investigation of lead chromate (crocoite-PbCrO4) and other inorganic pigments in aged traffic paint samples from Hamilton,Ohio: implications for lead in the environment

Traffic paint samples collected from roads in the City of Hamilton, Butler County, OH, USA were investigated to determine whether or not pigments are hazardous and are of environmental concern. Powder X-ray diffraction (XRD) and scanning electron microscopy (SEM) indicate that white and gray paint samples are dominated by calcite, rutile, anatase and quartz and blue traffic paint samples are dominated by calcite and barite. XRD and SEM indicate that most yellow traffic paints have lead chromate (crocoite-PbCrO₄) with common particle sizes that are typically 125–350 nm in length and 75–200 nm in width. Larger aggregates of several micrometers in diameter are also observed. The solubility of PbCrO₄ (1.34 × 10^?7 mol/L at 25 °C) combined with an increase in solubility with exposure to 0.05–0.25 M NaCl and CaCl₂ road treatments solutions as demonstrated by basic batch experiments likely makes PbCrO₄ from traffic paint a potential source for lead pollution in surface water and groundwater that is not fully recognized.     

The causes of land-use and land-cover change: moving beyond the myths

Common understanding of the causes of land-use and land-cover change is dominated by simplifications which, in turn, underlie many environment-development policies. This article tracks some of the major myths on driving forces of land-cover change and proposes alternative pathways of change that are better supported by case study evidence. Cases reviewed support the conclusion that neither population nor poverty alone constitute the sole and major underlying causes of land-cover change worldwide. Rather, peoples’ responses to economic opportunities, as mediated by institutional factors, drive land-cover changes. Opportunities and constraints for new land uses are created by local as well as national markets and policies. Global forces become the main determinants of land-use change, as they amplify or attenuate local factors.     

Regime shifts: Can ecological theory illuminate the mechanisms?

“Regime shifts” are considered here to be low-frequency, high-amplitude changes in oceanic conditions that may be especially pronounced in biological variables and propagate through several trophic levels. Three different types of regime shift (smooth, abrupt and discontinuous) are identified on the basis of different patterns in the relationship between the response of an ecosystem variable (usually biotic) and some external forcing or condition (control variable). The smooth regime shift is represented by a quasi-linear relationship between the response and control variables. The abrupt regime shift exhibits a nonlinear relationship between the response and control variables, and the discontinuous regime shift is characterized by the trajectory of the response variable differing when the forcing variable increases compared to when it decreases (i.e., the occurrence of alternative “stable” states). Most often, oceanic regime shifts are identified from time series of biotic variables (often commercial fish), but this approach does not allow the identification of discontinuous regime shifts. Recognizing discontinuous regime shifts is, however, particularly important as evidence from terrestrial and freshwater ecosystems suggests that such regime shifts may not be immediately reversible. Based on a review of various generic classes of mathematical models, we conclude that regime shifts arise from the interaction between population processes and external forcing variables. The shift between ecosystem states can be caused by gradual, cumulative changes in the forcing variable(s) or it can be triggered by acute disturbances, either anthropogenic or natural. A protocol for diagnosing the type of regime shift encountered is described and applied to a data set on Georges Bank haddock, from which it is concluded that a discontinuous regime shift in the abundance of haddock may have occurred. It is acknowledged that few, if any, marine data are available to confirm the occurrence of discontinuous regime shifts in the ocean. Nevertheless, we argue that there is good theoretical evidence for their occurrence as well as some anecdotal evidence from data collection campaigns and that the possibility of their occurrence should be recognized in the development of natural resource management strategies.     

IRTF spectra for 17 asteroids from the C and X complexes: A discussion of continuum slopes and their relationships to C chondrites and phyllosilicates

In order to gain further insight into their surface compositions and relationships with meteorites, we have obtained spectra for 17 C and X complex asteroids using NASA’s Infrared Telescope Facility and SpeX infrared spectrometer. We augment these spectra with data in the visible region taken from the on-line databases. Only one of the 17 asteroids showed the three features usually associated with water, the UV slope, a 0.7 μm feature and a 3 μm feature, while five show no evidence for water and 11 had one or two of these features. According to DeMeo et al. (2009), whose asteroid classification scheme we use here, 88% of the variance in asteroid spectra is explained by continuum slope so that asteroids can also be characterized by the slopes of their continua. We thus plot the slope of the continuum between 1.8 and 2.5 μm against slope between 1.0 and 1.75 μm, the break at ∼1.8 μm chosen since phyllosilicates show numerous water-related features beyond this wavelength. On such plots, the C complex fields match those of phyllosilicates kaolinite and montmorillonite that have been heated to about 700 °C, while the X complex fields match the fields for phyllosilicates montmorillonite and serpentine that have been similarly heated. We thus suggest that the surface of the C complex asteroids consist of decomposition products of kaolinite or montmorillonite while for the X complex we suggest that surfaces consist of decomposition products of montmorillonite or serpentine. On the basis of overlapping in fields on the continuum plots we suggest that the CI chondrites are linked with the Cgh asteroids, individual CV and CR chondrites are linked with Xc asteroids, a CK chondrite is linked with the Ch or Cgh asteroids, a number of unusual CI/CM meteorites are linked with C asteroids, and the CM chondrites are linked with the Xk asteroids. The associations are in reasonable agreement with chondrite mineralogy and albedo data.