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111.
The role of biodegradation and photo-oxidation in the transformation of terrigenous organic matter 总被引:1,自引:0,他引:1
Xiaojuan Feng Katherine M. Hills Andr J. Simpson Joann K. Whalen Myrna J. Simpson 《Organic Geochemistry》2011,42(3):262-274
Microbial and photochemical decomposition are two major processes regulating organic matter (OM) transformation in the global carbon cycle. However, photo-oxidation is not as well understood as biodegradation in terms of its impact on OM alteration in terrigenous environments. We examined microbial and photochemical transformation of OM and lignin derived phenols in two plant litters (corn leaves and pine needles). Plant litter was incubated in the laboratory over 3 months and compositional changes to OM were measured using nuclear magnetic resonance (NMR) and gas chromatography-mass spectrometry. We also examined the susceptibility of soil organic matter (SOM) to ultraviolet (UV) radiation. Solid-state 13C NMR spectra showed that O-alkyl type structures (mainly from carbohydrates) decreased during biodegradation and the loss of small carbohydrates and aliphatic molecules was observed by solution-state 1H NMR spectra of water extractable OM from biodegraded litters. Photochemical products were detected in the aliphatic regions of NaOH extracts from both litter samples by solution-state 1H NMR. Photo-oxidation also increased the solubility of SOM, which was attributed to the enhanced oxidation of lignin derived phenols and photochemical degradation of macromolecular SOM species (as observed by diffusion edited 1H NMR). Overall, our data collectively suggests that while biodegradation predominates in litter decomposition, photo-oxidation alters litter OM chemistry and plays a role in destabilizing SOM in soils exposed to UV radiation. 相似文献
112.
113.
Katherine H. Joy David A. Kring Donald D. Bogard David S. McKay Michael E. Zolensky 《Geochimica et cosmochimica acta》2011,75(22):7208-7225
The lunar regolith is exposed to irradiation from the solar wind and to bombardment by asteroids, comets and inter-planetary dust. Fragments of projectiles in the lunar regolith can potentially provide a direct measure of the sources of exogenous material being delivered to the Moon. Constraining the temporal flux of their delivery helps to address key questions about the bombardment history of the inner Solar System.Here, we use a revised antiquity calibration (after Eugster et al., 2001) that utilises the ratio of trapped 40Ar/36Ar (‘parentless’ 40Ar derived from radioactive decay of 40K, against solar wind derived 36Ar) to semi-quantitatively calculate the timing of the assembly of the Apollo 16 regolith breccias. We use the trapped 40Ar/36Ar ratios reported by McKay et al. (1986). Our model indicates that the Apollo 16 ancient regolith breccia population was formed between ∼3.8 and 3.4 Ga, consistent with regoliths developed and assembled after the Imbrium basin-forming event at ∼3.85 Ga, and during a time of declining basin-forming impacts. The material contained within the ancient samples potentially provides evidence of impactors delivered to the Moon in the Late-Imbrian epoch. We also find that a young regolith population was assembled, probably by local impacts in the Apollo 16 area, in the Eratosthenian period between ∼2.5 and 2.2 Ga, providing insights to the sources of post-basin bombardment. The ‘soil-like’ regolith breccia population, and the majority of local Apollo 16 soils, were likely closed in the last 2 Ga and, therefore, potentially provide an archive of projectile types in the Eratosthenian and Copernican periods. 相似文献
114.
Production of n-alkyl lipids in living plants and implications for the geologic past 总被引:2,自引:0,他引:2
Aaron F. Diefendorf Katherine H. Freeman Heather V. Graham 《Geochimica et cosmochimica acta》2011,75(23):7472-7485
Leaf waxes (i.e., n-alkyl lipids or n-alkanes) are land-plant biomarkers widely used to reconstruct changes in climate and the carbon isotopic composition of the atmosphere. There is little information available, however, on how the production of leaf waxes by different kinds of plants might influence the abundance and isotopic composition of n-alkanes in sedimentary archives. This lack of information increases uncertainty in interpreting n-alkyl lipid abundance and δ13C signals in ancient settings. We provide here n-alkyl abundance distributions and carbon isotope fractionation data for deciduous and evergreen angiosperm and gymnosperm leaves from 46 tree species, representing 24 families. n-Alkane abundances are significantly higher in angiosperms than gymnosperms; many of the gymnosperm species investigated did not produce any n-alkanes. On average, deciduous angiosperms produce 200 times more n-alkanes than deciduous gymnosperms. Although differences between angiosperms and gymnosperms dominate the variance in n-alkane abundance, leaf life-span is also important, with higher n-alkane abundances in longer-lived leaves. n-Alkanol abundances covary with n-alkanes, but n-alkanoic acids have similar abundances across all plant groups. Isotopic fractionation between leaf tissue and individual alkanes (εlipid) varies by as much as 10‰ among different chain lengths. Overall, εlipid values are slightly lower (−4.5‰) for angiosperm than for gymnosperm (−2.5‰) n-alkanes. Angiosperms commonly express slightly higher Δleaf (photosynthetic discrimination) relative to gymnosperms under similar growth conditions. As a result, angiosperm n-alkanes are expected to be generally 3-5‰ more depleted in 13C relative to gymnosperm alkanes for the same locality. Differences in n-alkane production indicate the biomarker record will largely (but not exclusively) reflect angiosperms if both groups were present, and also that evergreen plants will likely be overrepresented compared with deciduous ones. We apply our modern lipid abundance patterns and εlipid results to constrain the magnitude of the carbon isotope excursion (CIE) at the onset of the Paleocene-Eocene Thermal Maximum (55.8 Ma). When Bighorn Basin (WY) sediment n-alkanes are interpreted in context of floral changes and modern n-alkane production estimates for angiosperms and gymnosperms, the CIE is greater in magnitude (−5.6‰) by ∼1‰ compared to previous estimates that do not take into account n-alkane production. 相似文献
115.
Katherine E. Wright Stephen E. Grasby Charles Williamson John Spear Alexis S. Templeton 《Applied Geochemistry》2011
The authors are studying microbial sulfur redox metabolisms in a glacial environment. The energy available from sulfur redox reactions at this site has been calculated using geochemical data obtained from the site. DNA has been extracted from the same site and is being analyzed for the presence and relative quantities of sulfur redox genes, to determine whether bioenergetic calculations can predict the sulfur redox reactions that microbes are in fact utilizing. 相似文献
116.
Batibeniz Fulden Ashfaq Moetasim nol Bar Turuncoglu Ufuk Utku Mehmood Shahid Evans Katherine J. 《Climate Dynamics》2020,54(9):4109-4127
Climate Dynamics - We employ a Lagrangian based moisture back trajectory method on an ensemble of four reanalysis datasets to provide a comprehensive understanding of moisture sources over the... 相似文献
117.
Romain Tartèse Mahesh Anand Katherine H. Joy Ian A. Franchi 《Meteoritics & planetary science》2014,49(12):2266-2289
We have investigated the H and Cl systematics in apatite from four brecciated lunar meteorites. In Northwest Africa (NWA) 4472, most of the apatites contain ~2000–6000 ppm H2O with δD between ?200 and 0‰, except for one grain isolated in the matrix, which contains ~6000 ppm H2O with δD of ~500–900‰. This low‐δD apatite contains ~2500–7500 ppm Cl associated with δ37Cl of ~15–20‰, while the high‐δD grain contains ~2500 ppm Cl with δ37Cl of ~7–15‰. In NWA 773, apatites in a first group contain ~700–2500 ppm H2O with δD values averaging around ~0 ± 100‰, while apatites in a second group contain ~5500–16500 ppm H2O with δD ~250 ± 50‰. In Sayh al Uhaymir (SaU) 169 and Kalahari (Kal) 009, apatites are similar in terms of their H2O contents (~600–3000 ppm) and δD values (?100 to 200‰). In SaU 169, apatites contain ~6000–10,000 ppm Cl, characterized by δ37Cl of ~5–12‰. Overall, most of the analyzed apatite grains have δD within the range reported for carbonaceous chondrites, similar to apatite analyzed in ancient (>3.9 Ga) lunar magmatic. One grain in NWA 4472 has H and Cl isotope compositions similar to apatite from mare basalts. With an age of 4.35 Ga, this grain could be a representative of the oldest known lunar volcanic activity. Finally, since numerous evolved clasts in NWA 773 formed through silicate liquid immiscibility, the apatite grains with extremely high H2O contents, reaching pure hydroxylapatite composition, could provide insights into the effects of such process on the evolution of volatiles in lunar magmas. 相似文献
118.
We present time–resolved optical spectroscopy of the famous X-ray binary SS 433. We obtained 61 medium resolution spectra spread over three months and thus cover roughly five orbits and about half a precession phase. We used various emission lines, that we attribute to the accretion disc, to determine the radial velocities of the compact component. They are of course modulated with the orbital period but in addition show a variation of the system velocity on a longer time scale. With the present data it is not possible to determine whether this is a transient effect or a periodic variation, although we present various possible interpretations of this effect. 相似文献
119.
George Mark A. Silversides Katherine L. Zigman John Melkumyan Arman 《Mathematical Geosciences》2021,53(7):1567-1585
Mathematical Geosciences - When modelling a stratified orebody, accurately representing the dip and dip direction is important for accurate resource estimation. In the banded iron formation-hosted... 相似文献
120.
Mathematical Geosciences - In the banded iron formation-hosted iron ore deposits in the Hamersley Range of Western Australia, the stratigraphic boundaries are generally modelled using data from... 相似文献