Effect of multilayered groundwater mounds on water dynamics beneath a recharge basin: Numerical simulation and assessment of surface injection

Interactions between groundwater mounds caused by a geologic layer contrast affect the efficiency of managed aquifer recharge in arid areas. However, research has rarely examined the roles of groundwater mounding size variations on soil water dynamics in a stratified vadose zone in response to a sustained infiltration source. Numerical experiments were conducted on a two-dimensional vertical-section domain using HYDRUS software to simulate the behaviours of two adjacent (upper and lower) groundwater mounds underlying an infiltration basin subjected to clay loam and sandy alternately-layered soil profiles. The model successfully predicted the volume and extent of perched water and approximated vertical travel times during events generating downward fluxes from the surface injection. The response time of the mounding width (lateral extension) to the surface injection was delayed as compared to that of the mounding height (vertical extension), especially for the lower water mound. The mounding heights and widths show a strongly positive correlation with the infiltration rates of both high- and low-permeability layers where the injected water mounded, while the water storage amounts in the high- and low-permeability layers were governed by the mounding height and width, respectively. Exploratory simulations were then employed to assess the dependence of groundwater mounding behaviours and recharge performances on surface injection strategies. Results suggest that, by reducing injection rate or shortening injection duration, the near-term fraction of the surface injection converted to deep recharge is likely to be increased due to the narrowed groundwater mounding size, which would be limited by the water-retarding effect of layer contrasts. This study has important implications for predicting and understanding multilayered groundwater mounding behaviours and associated water mass balance under the geologic stratification, and is expected to aid in optimizing the infiltration basin operation for aquifer recharge.     

Elsterian‐Holsteinian deposits at Kås Hoved,northern Denmark: sediments,foraminifera, ostracods,and stable isotopes

The coastal cliff section at Kås Hoved in northern Denmark represents one of the largest exposures of marine interglacial deposits in Europe. High‐resolution analyses of sediments, foraminifera, ostracods, and stable isotopes (oxygen and carbon) in glacial‐interglacial marine sediments from this section, as well as from two adjacent boreholes, are the basis for an interpretation of marine environmental and climatic change through the Late Elsterian‐Holsteinian glacial‐interglacial cycle. The overlying glacial deposits show two ice advances during the Saalian and Weichselian glaciations. The assemblages in the initial glacier‐proximal part of the marine Late Elsterian succession reveal fluctuations in the inflow of sediment‐loaded meltwater to the area. This is followed by faunal indication of glacier‐distal, open marine conditions, coinciding with a gradual climatic change from arctic to subarctic environments. Continuous marine sedimentation during the glacial‐interglacial transition is presumably a result of a large‐scale isostatic subsidence caused by the preceding extended Elsterian glaciation. The similarity of the climatic signature of the interglacial Holsteinian and Holocene assemblages in this region indicates that the Atlantic Ocean circulation was similar during these two interglacials, whereas Eemian interglacial assemblages indicate a comparatively high water temperature associated with an enhanced North Atlantic Current. The foraminiferal zones are correlated with other Elsterian‐Holsteinian sites in Denmark, as well as those in the type area for the Holsteinian interglacial in northern Germany and the southern North Sea. Correlation of the NW European Holsteinian succession with the marine isotope stages MIS 7, 9 or 11 is still unresolved.     

Improvement of snowpack simulations in a regional climate model

To improve simulations of regional‐scale snow processes and related cold‐season hydroclimate, the Community Land Model version 3 (CLM3), developed by the National Center for Atmospheric Research (NCAR), was coupled with the Pennsylvania State University/NCAR fifth‐generation Mesoscale Model (MM5). CLM3 physically describes the mass and heat transfer within the snowpack using five snow layers that include liquid water and solid ice. The coupled MM5–CLM3 model performance was evaluated for the snowmelt season in the Columbia River Basin in the Pacific Northwestern United States using gridded temperature and precipitation observations, along with station observations. The results from MM5–CLM3 show a significant improvement in the SWE simulation, which has been underestimated in the original version of MM5 coupled with the Noah land‐surface model. One important cause for the underestimated SWE in Noah is its unrealistic land‐surface structure configuration where vegetation, snow and the topsoil layer are blended when snow is present. This study demonstrates the importance of the sheltering effects of the forest canopy on snow surface energy budgets, which is included in CLM3. Such effects are further seen in the simulations of surface air temperature and precipitation in regional weather and climate models such as MM5. In addition, the snow‐season surface albedo overestimated by MM5–Noah is now more accurately predicted by MM5–CLM3 using a more realistic albedo algorithm that intensifies the solar radiation absorption on the land surface, reducing the strong near‐surface cold bias in MM5–Noah. The cold bias is further alleviated due to a slower snowmelt rate in MM5–CLM3 during the early snowmelt stage, which is closer to observations than the comparable components of MM5–Noah. In addition, the over‐predicted precipitation in the Pacific Northwest as shown in MM5–Noah is significantly decreased in MM5–CLM3 due to the lower evaporation resulting from the longer snow duration. Copyright © 2011 John Wiley & Sons, Ltd.     

A rose by any other name ...?: What members of the general public prefer to call “climate change”

Unlike many other environmental problems, the terms used to describe the phenomenon of increasing atmospheric concentrations of anthropogenic greenhouse gases are many, with multiple and sometimes conflicting meanings. Whether there are meaningful distinctions in public perceptions of “global warming,” “climate change,” and “global climate change” has been a topic of research over the past decade. This study examines public preferences for these terms based on respondent characteristics, including climate change beliefs, political affiliation, and audience segment status derived from the “Global Warming’s Six Americas” classification. Certainty of belief in global warming, political affiliation and audience segment status were found to be the strongest predictors of preference, although “I have no preference” was the modal response. Global warming appears to be a more polarizing term than climate change, preferred most by people already concerned about the issue, and least by people who don’t believe climate change is occurring. Further research is needed to identify which of these two names promotes the engagement of people across the spectrum of climate change beliefs in constructive dialogue about the issue.     

Regional simulations to quantify land use change and irrigation impacts on hydroclimate in the California Central Valley

In this study, the influence of land use change and irrigation in the California Central Valley is quantified using the Pennsylvania State University/National Center for Atmospheric Research fifth generation Mesoscale Model (MM5) coupled with the Community Land Model version 3 (CLM3). The simulations were forced with modern-day and presettlement land use types at 30-km spatial resolution for the period 1 October 1995 to 30 September 1996. This study shows that land use change has significantly altered the structure of the planetary boundary layer (PBL) that affects near-surface temperature. In contrast, many land-use change studies indicate that albedo and evapotranspiration variations are the key processes influencing climate at local-to-regional scales. Our modeling results show that modern-day daily maximum near-surface air temperature (Tmax) has decreased due to agricultural expansion since presettlement. This decrease is caused by weaker sensible heat flux resulting from the lower surface roughness lengths associated with modern-day crops. The lower roughness lengths in the Central Valley also result in stronger winds that lead to a higher PBL. The higher PBL produces stronger sensible heat flux, causing nighttime warming. In addition to land use change, cropland irrigation has also affected hydroclimate processes within the California Central Valley. We generated a 10-member MM5-CLM3 ensemble simulation, where each ensemble member was forced by a fixed volumetric soil water content (SWC) between 3% and 30%, at 3% intervals, over the irrigated areas during a spring?Csummer growing season, 1 March to 31 August 1996. The results show that irrigation lowers the modern-day cropland surface temperature. Daytime cooling is produced by irrigation-related evaporation enhancement. This increased evaporation also dominates the nighttime surface cooling process. Surface cooling and the resulting weaker sensible heat flux further lower the near-surface air temperature. Thus, irrigation strengthens the daytime near-surface air temperature reduction that is caused by land use change, and a similar temperature change is seen for observations over irrigated cropland. Based on our modeling results, the nighttime near-surface warming induced by land use change is alleviated by low-intensity irrigation (17%?<?SWC?<?19%), but such warming completely reverses to a cooling effect under high-intensity irrigation (SWC?>?19%). The land use changes discussed in this study are commonly observed in many regions of the world, and the physical processes identified here can be used to better understand temperature variations over other areas with similar land cover changes.     

Atmospheric circulation anomalies during two persistent north american droughts: 1932�C1939 and 1948�C1957

We use an early twentieth century (1908?C1958) atmospheric reanalysis, based on assimilation of surface and sea level pressure observations, to contrast atmospheric circulation during two periods of persistent drought in North America: 1932?C1939 (the ??Dust Bowl??) and 1948?C1957. Primary forcing for both droughts is believed to come from anomalous sea surface temperatures (SSTs): a warm Atlantic and a cool eastern tropical Pacific. For boreal winter (October?CMarch) in the 1950s, a stationary wave pattern originating from the tropical Pacific is present, with positive centers over the north Pacific and north Atlantic ocean basins and a negative center positioned over northwest North America and the tropical/subtropical Pacific. This wave train is largely absent for the 1930s drought; boreal winter height anomalies are organized much more zonally, with positive heights extending across northern North America. For boreal summer (April?CSeptember) during the 1930s, a strong upper level ridge is centered over the Great Plains; this feature is absent during the 1950s and appears to be linked to a weakening of the Great Plains low-level jet (GPLLJ). Subsidence anomalies are co-located over the centers of each drought: in the central Great Plains for the 1930s and in a band extending from the southwest to the southeastern United States for the 1950s. The location and intensity of this subsidence during the 1948?C1957 drought is a typical response to a cold eastern tropical Pacific, but for 1932?C1939 deviates in terms of the expected intensity, location, and spatial extent. Overall, circulation anomalies during the 1950s drought appear consistent with the expected response to the observed SST forcing. This is not the case for the 1930s, implying some other causal factor may be needed to explain the Dust Bowl drought anomalies. In addition to SST forcing, the 1930s were also characterized by massive alterations to the land surface, including regional-scale devegetation from crop failures and intensive wind erosion and dust storms. Incorporation of these land surface factors into a general circulation model greatly improves the simulation of precipitation and subsidence anomalies during this drought, relative to simulations with SST forcing alone. Even with additional forcing from the land surface, however, the model still has difficulty reproducing some of the other circulation anomalies, including weakening of the GPLLJ and strengthening of the upper level ridge during AMJJAS. This may be due to either weaknesses in the model or uncertainties in the boundary condition estimates. Still, analysis of the circulation anomalies supports the conclusion of an earlier paper (Cook et?al. in Proc Natl Acad Sci 106:4997, 2009), demonstrating that land degradation factors are consistent with the anomalous nature of the Dust Bowl drought.     

TCAT Analysis of Capillary Pressure in Non-equilibrium, Two-fluid-phase, Porous Medium Systems

Standard models of flow of two immiscible fluids in a porous medium make use of an expression for the dependence of capillary pressure on the saturation of a fluid phase. Data to support the mathematical expression is most often obtained through a sequence of equilibrium experiments. In addition to such expressions being hysteretic, recent experimental and theoretical studies have suggested that the equilibrium functional forms obtained may be inadequate for modeling dynamic systems. This situation has led to efforts to express relaxation of a system to an equilibrium capillary pressure in relation to the rate of change of saturation. Here, based on insights gained from the thermodynamically constrained averaging theory (TCAT) we propose that dynamic processes are related to changes in interfacial area between phases as well as saturation. A more complete formulation of capillary pressure dynamics is presented leading to an equation that is suitable for experimental study.     

C 1s K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy for characterizing functional group chemistry of black carbon

Black carbon (BC) is considered ubiquitous in soil organic matter (OM) and therefore plays an important role in soil biogeochemistry. Its complexity, particularly within environmental matrices, presents a challenge for research, primarily as a result of techniques which may favor detection of certain functional group types rather than capturing total sample C. The objective of this study was to utilize carbon (C) 1s near edge X-ray absorption fine edge structure (NEXAFS) spectroscopy to characterize the C chemistry of a broad range of BC materials. Characteristic resonances in the NEXAFS spectra allowed direct molecular speciation of the total C chemistry of the reference materials, environmental matrices and potentially interfering materials, obtained from an earlier BC ring trial. Spectral deconvolution was used to further identify the functional group distribution of the materials. BC reference materials and soils were characterized by a large aromatic C region comprising around 40% of total absorption intensity. We were able to distinguish shale and melanoidin from BC reference materials on the basis of their unique spectral characteristics. However, bituminous coal shared chemical characteristics with BC reference materials, namely high aromaticity of more than 40% identified by way of a broad peak. Lignite also shared similar spectra and functional group distributions to BC reference materials and bituminous coal. We compared the results of spectral deconvolution with the functional group distributions obtained by way of direct polarization magic angle spinning (DPMAS) ¹³C nuclear magnetic resonance (NMR) spectroscopy. Correlations between aromatic type C values for DPMAS ¹³C NMR and NEXAFS gave r² = 0.633 (p < 0.05) and the values for NEXAFS were around 30–40% lower than for ¹³C NMR. Correlations were also drawn between the aromatic C/O-alkyl C ratio values for the two methods (r² = 0.49, p < 0.05). Overall, NEXAFS was applicable for a wide range of environmental materials, such as those measured, although some limitations for the technique were addressed.     

Zircon from historic eruptions in Iceland: reconstructing storage and evolution of silicic magmas

Zoning patterns, U-Th disequilibria ages, and elemental compositions of zircon from eruptions of Askja (1875 AD), Hekla (1158 AD), ?r?faj?kull (1362 AD) and Torfaj?kull (1477 AD, 871 AD, 3100 BP, 7500 BP) provide insights into the complex, extended, histories of silicic magmatic systems in Iceland. Zircon compositions, which are correlated with proximity to the main axial rift, are distinct from those of mid-ocean ridge environments and fall at the low-Hf edge of the range of continental zircon. Morphology, zoning patterns, compositions, and U-Th ages all indicate growth and storage in subvolcanic silicic mushes or recently solidified rock at temperatures above the solidus but lower than that of the erupting magma. The eruptive products were likely ascending magmas that entrained a zircon ??cargo?? that formed thousands to tens of thousands of years prior to the eruptions.