Towed vehicle observations of thin layer structure and a low-salinity intrusion in Northern Monterey Bay,CA

Thin phytoplankton layers are common features in the coastal environment; however sampling these fine-scale optical features across broad horizontal scales remains a challenge. To investigate the horizontal spatial structure of thin phytoplankton layers, we performed an overnight survey in northern Monterey Bay, CA, USA using a SeaSciences Acrobat towed-vehicle. Physical and optical measurements were collected between the surface and near-bottom-depths along four parallel, across-shore transects. Three coherent chlorophyll features were observed: (1) a broad, sub-surface patch at the offshore end, (2) a near-surface patch at the nearshore end, and (3) a deep patch located between the nearshore and offshore patches. The offshore and nearshore patch were separated by a change in seafloor slope and a region of compressed, shoaling isopycnals. Both the offshore and nearshore features were located at the pycnocline, had similar optical properties, and were co-located with a low-salinity intrusion. The deep chlorophyll patch had associated physical and optical properties that were distinct from the patches at the pycnocline. The results from this study further underscore the heterogeneous horizontal spatial structure of thin layers and also add to the growing evidence suggesting that low-salinity intrusions may be strongly linked to the formation of thin phytoplankton layers over the northern shelf of Monterey Bay.     

Strontium isotopic evidence for prehistoric transport of gray‐ware ceramic materials in the eastern Grand Canyon region,USA

Through a novel application of strontium (Sr) isotopic analysis, we evaluate geological sources for prehistoric ceramics in the eastern Grand Canyon region of northern Arizona, focusing on two gray‐ware traditions in the Upper Basin of the Coconino Plateau. Building on a conceptual framework for the general potential of Sr isotopes in the analysis of geological materials, we suggest that the eastern Grand Canyon is specifically well suited archaeologically and geologically for: (1) exploring the utility of Sr isotopes for ceramic provenance research and (2) testing long‐standing hypotheses that gray‐ware ceramics were invariably made with local materials. Sr isotopic compositions indicate that the ceramic samples represent at least three different geological sources, and that different raw materials were used in the manufacture of the two gray‐ware traditions found in the Upper Basin. One of the gray‐ware traditions is not compositionally consistent with local geology, indicating that either the ceramics or the raw materials were transported at least 20 km to the Upper Basin. © 2011 Wiley Periodicals, Inc.     

Age and geochemistry of volcanic rocks from the Hikurangi and Manihiki oceanic Plateaus

Here we present the first radiometric age data and a comprehensive geochemical data set (including major and trace element and Sr-Nd-Pb-Hf isotope ratios) for samples from the Hikurangi Plateau basement and seamounts on and adjacent to the plateau obtained during the R/V Sonne 168 cruise, in addition to age and geochemical data from DSDP Site 317 on the Manihiki Plateau. The ⁴⁰Ar/³⁹Ar age and geochemical data show that the Hikurangi basement lavas (118-96 Ma) have surprisingly similar major and trace element and isotopic characteristics to the Ontong Java Plateau lavas (ca. 120 and 90 Ma), primarily the Kwaimbaita-type composition, whereas the Manihiki DSDP Site 317 lavas (117 Ma) have similar compositions to the Singgalo lavas on the Ontong Java Plateau. Alkalic, incompatible-element-enriched seamount lavas (99-87 Ma and 67 Ma) on the Hikurangi Plateau and adjacent to it (Kiore Seamount), however, were derived from a distinct high time-integrated U/Pb (HIMU)-type mantle source. The seamount lavas are similar in composition to similar-aged alkalic volcanism on New Zealand, indicating a second wide-spread event from a distinct source beginning ca. 20 Ma after the plateau-forming event. Tholeiitic lavas from two Osbourn seamounts on the abyssal plain adjacent to the northeast Hikurangi Plateau margin have extremely depleted incompatible element compositions, but incompatible element characteristics similar to the Hikurangi and Ontong Java Plateau lavas and enriched isotopic compositions intermediate between normal mid-ocean-ridge basalt (N-MORB) and the plateau basement. These younger (∼52 Ma) seamounts may have formed through remelting of mafic cumulate rocks associated with the plateau formation. The similarity in age and geochemistry of the Hikurangi, Ontong Java and Manihiki Plateaus suggest derivation from a common mantle source. We propose that the Greater Ontong Java Event, during which ∼1% of the Earth’s surface was covered with volcanism, resulted from a thermo-chemical superplume/dome that stalled at the transition zone, similar to but larger than the structure imaged presently beneath the South Pacific superswell. The later alkalic volcanism on the Hikurangi Plateau and the Zealandia micro-continent may have been part of a second large-scale volcanic event that may have also triggered the final breakup stage of Gondwana, which resulted in the separation of Zealandia fragments from West Antarctica.     

Photolysis of 2,4-Dinitrotoluene and 2,6-Dinitrotoluene in Seawater

The purpose of this experiment was to determine the rate of photolysis for 2,4-dinitrotoluene (2,4-DNT) and 2,6-dinitrotoluene (2,6-DNT) in salt water and pure water, examine the influence of salt concentration on the photolysis rate, and to identify the products of the photolysis of 2,4-DNT and 2,6-DNT in seawater. For the photolysis of 2,4-DNT in pure water, the half-life was longer than 100 h, whereas the photolysis half-life in salt water was ~15 h. For 2,6-DNT, the pure water photolysis half-life was close to 20 h, but the salt water photolysis half-life was only 5 h. The photolysis rate for 2,6-DNT in seawater was affected by the ionic strength of the parent solution and was independent of the identity of the salt. The photolysis of both DNTs in seawater resulted in a complex mixture of products that exhibit a distinct yellow color. Analysis by gas and liquid chromatography mass spectroscopy (GCMS, LCMS) following liquid–liquid extraction or solid phase extractions resulted in the confirmation of the corresponding dinitrobenzaldhydes and dinitrobenzoic acids as photolysis products and a probable azoxy compound among the photolysis products in seawater.     

Evaluating a nonionic surfactant as a tool to improve water availability in irrigated cotton

Nonionic surfactants have been well researched in turf grass environments as a tool to ameliorate water‐repellant conditions. However, few studies have evaluated the risks and benefits of nonionic surfactant applications in row‐crop agricultural systems. The objective of this study was to evaluate the impact of a nonionic surfactant on cotton (Gossypium hirsutum L.) production on a Faceville loamy sand (fine, kaolinitic thermic Typic Kandiudult) in the coastal plain region of Georgia. The experiment consisted of two components: (1) on‐site rainfall simulation and (2) agronomic cotton field trials. Treatments were designed to test the impact of rate and frequency of surfactant applications using six combinations of application rates and timings. For the rainfall simulation component, only the control (0·0 L ha^?1) and high rate (0·51 L ha^?1) of surfactant applications were evaluated. During the field trial, soil water content, cotton stand counts, and yield were measured. Rainfall simulations showed that the addition of surfactant increased runoff, decreased infiltration, and promoted surface sealing. Despite the demonstrated potential for water loss, agronomic field trials showed that crop yields were not significantly different between surfactant‐treated and untreated plots. No differences in soil water content were observed between treatments at 5 and 15 cm depths; however, soil water content was significantly higher in untreated control plots at the 30 cm depth. Data demonstrate the need for clarification of soil physical/chemical properties and surfactant interactions that may lend themselves to the creation of surface seals and how these seals impact soil/water conservation and crop yield. Published in 2009 by John Wiley & Sons, Ltd.     

Study by MOA of extrasolar planets in gravitational microlensing events of high magnification

A search for extrasolar planets was carried out in three gravitational microlensing events of high magnification, MACHO  98–BLG–35  , MACHO  99–LMC–2  and OGLE  00–BUL–12  . Photometry was derived from observational images by the MOA and OGLE groups using an image subtraction technique. For MACHO  98–BLG–35  , additional photometry derived from the MPS and PLANET groups was included. Planetary modelling of the three events was carried out in a supercluster computing environment. The estimated probability for explaining the data on MACHO  98–BLG–35  without a planet is <1 per cent. The best planetary model has a planet of mass ∼(0.4–1.5)× M _Earth at a projected radius of either ∼1.5 or ∼2.3 au. We show how multiplanet models can be applied to the data. We calculate exclusion regions for the three events and find that Jupiter-mass planets can be excluded with projected radii from as wide as about 30 au to as close as around 0.5 au for MACHO  98–BLG–35  and OGLE  00–BUL–12  . For MACHO  99–LMC–2  , the exclusion region extends out to around 10 au and constitutes the first limit placed on a planetary companion to an extragalactic star. We derive a particularly high peak magnification of ∼160 for OGLE  00–BUL–12  . We discuss the detectability of planets with masses as low as Mercury in this and similar events.     

The MOA catalogue of eclipsing binary stars in the Small Magellanic Cloud

We present a catalogue of 167 eclipsing binary stars in the Small Magellanic Cloud (SMC) derived from the data base of time-series photometry for 400 000 SMC stars acquired by the Microlensing Observations in Astrophysics (MOA) project during 1997. We print coordinates, ephemerides, magnitudes and light curves for the 35 new detections; similar data and finding charts are available electronically for the whole catalogue. The majority of periods lie within the range 0.4 to 20 d; six systems are possibly eccentric while 14 are probably or certainly so. The majority of the newly identified systems lie in the outer regions of the SMC.     

The discovery of a persistent quasi-periodic oscillation in the intermediate polar TX Col

We report on the detection of an ∼5900 s quasi-periodic variation in the extensive photometry of TX Col spanning 12 yr. We discuss five different models to explain this period. We favour a mechanism where the quasi-periodic variation results from the beating of the Keplerian frequency of the 'blobs' orbiting in the outer accretion disc with the spin frequency and from modulated accretion of these 'blobs' taking place in a shocked region near the disc/magnetosphere boundary.     

Pacific Atmospheric Sulfur Experiment (PASE): dynamics and chemistry of the south Pacific tropical trade wind regime

The Pacific Atmospheric Sulfur Experiment (PASE) was a comprehensive airborne study of the chemistry and dynamics of the tropical trade wind regime (TWR) east of the island of Kiritibati (Christmas Island, 157º, 20?? W, 2º 52?? N). Christmas Island is located due south of Hawaii. Geographically it is in the northern hemisphere yet it is 6?C12º south of the intertropical convergence zone (ITCZ) which places it in the southern hemisphere meteorologically. Christmas Island trade winds in August and September are from east south east at 3?C15 ms^?1. Clouds, if present, are fair weather cumulus located in the middle layer of the TWR which is frequently labeled the buffer layer (BuL). PASE provided clear support for the idea that small particles (80 nm) were subsiding into the tropical trade wind regime (TWR) where sulfur chemistry transformed them to larger particles. Sulfur chemistry promoted the growth of some of these particles until they were large enough to activate to cloud drops. This process, promoted by sulfur chemistry, can produce a cooling effect due to the increase in cloud droplet density and changes in cloud droplet size. These increases in particle size observed in PASE promote additional cooling due to direct scattering from the aerosol. These potential impacts on the radiation balance in the TWR are enhanced by the high solar irradiance and ocean albedo of the TWR. Finally because of the large area involved there is a large factional impact on earth??s radiation budget. The TWR region near Christmas Island appears to be similar to the TWR that persists in August and September, from southwest of the Galapagos to at least Christmas Island. Transport in the TWR between the Galapagos and Christmas involves very little precipitation which could have removed the aerosol thus explaining at least in part the high concentrations of CCN (??300 at 0.5% supersaturation) observed in PASE. As expected the chemistry of sulfur in the trade winds was found to be initiated by the emission of DMS into the convective boundary layer (BL, the lowest of three layers). However, the efficiency with which this DMS is converted to SO₂ has been brought into further question by this study. This unusual result has come about as result of our using two totally different approaches for addressing this long standing question. In the first approach, based on accepted kinetic rate constants and detailed steps for the oxidation of DMS reflecting detailed laboratory studies, a DMS to SO₂ conversion efficiency of 60?C73% was determined. This range of values lies well within the uncertainties of previous studies. However, using a completely different approach, involving a budget analysis, a conversion value of 100% was estimated. The latter value, to be consistent with all other sulfur studies, requires the existence of a completely independent sulfur source which would emit into the atmosphere at a source strength approximately half that measured for DMS under tropical Pacific conditions. At this time, however, there is no credible scientific observation that identifies what this source might be. Thus, the current study has opened for future scientific investigation the major question: is there yet another major tropical marine source of sulfur? Of equal importance, then, is the related question, is our global sulfur budget significantly in error due to the existence of an unknown marine source of sulfur? Pivotal to both questions may be gaining greater insight about the intermediate DMS oxidation species, DMSO, for which rather unusual measurements have been reported in previous marine sulfur studies. The 3 pptv bromine deficit observed in PASE must be lost over the lifetime of the aerosol which is a few days. This observation suggests that the primary BrO production rate is very small. However, considering the uncertainties in these observations and the possible importance of secondary production of bromine radicals through aerosol surface reactions, to completely rule out the importance of bromine chemistry under tropical conditions at this time cannot be justified. This point has been brought into focus from prior work that even at levels of 1 pptv, the effect of BrO oxidation on DMS can still be quite significant. Thus, as in the case of DMS conversion to SO₂, future studies will be needed. In the latter case there will need to be a specific focus on halogen chemistry. Such studies clearly must involve specific measurements of radical species such as BrO.