Earth observations during space shuttle flight STS‐41: Discovery's mission to planet earth

Abstract

Multi‐temporal ERS‐1 SAR data acquired over a large agricultural region in West Bengal was used to classify kharif crops like rice, jute and sugarcane. Rice crop grown under lowland management practice showed a temporal characteristic. The dynamic range of backscatter was highest for this crop in temporal SAR data. This was used to classify rice using temporal SAR data. Such temporal character was not observed for the other study crops, which may be due to the difference in cultivation practice and crop calendar. Significant increase in backscatter from the ploughed fields was used to derive information on onset and duration of land preparations. Synergistic use of optical remote sensing data and SAR data increased the separability of rice crop from homesteads and permanent vegetation classes.     

Evolution of a Carboniferous carbonate-hosted sphalerite breccia deposit,Isle of Man

A newly discovered, extensive sphalerite-bearing breccia (~7.5 wt.% Zn) is hosted in dolomitised Carboniferous limestones overlying Ordovician–Silurian metasedimentary rocks on the Isle of Man. Although base metal sulphide deposits have been mined historically on the island, they are nearly all quartz vein deposits in the metamorphic basement. This study investigates the origin of the unusual sphalerite breccia and its relationship to basement-hosted deposits, through a combination of petrographic, cathodoluminescence, fluid inclusion, stable isotope and hydrogeologic modelling techniques. Breccia mineralisation comprises four stages, marked by episodes of structural deformation and abrupt changes in fluid temperature and chemistry. In stage I, high-temperature (T _h > 300°C), high-salinity (20–45 wt.% equiv. NaCl) fluid of likely basement origin deposited a discontinuous quartz vein. This vein was subsequently dismembered during a major brecciation event. Stages II–IV are dominated by open-space filling sphalerite, quartz and dolomite, respectively. Fluid inclusions in these minerals record temperatures of ~105–180°C and salinities of ~15–20 wt.% equiv. NaCl. The δ³⁴S values of sphalerite (6.5–6.9‰ Vienna-Canyon Diablo troilite) are nearly identical to those of ore sulphides from mines in the Lower Palaeozoic metamorphic rocks. The δ¹⁸O values for quartz and dolomite indicate two main fluid sources in the breccia’s hydrothermal system, local Carboniferous-hosted brines (~0.5–6.0‰ Vienna standard mean ocean water) and basement-involved fluids (~5.5–11.5‰). Ore sulphide deposition in the breccia is compatible with the introduction and cooling of a hot, basement-derived fluid that interacted with local sedimentary brines.     

Petrography,mineral chemistry,and crystallization history of olivine‐phyric shergottite NWA 6234: A new melt composition

Knowledge of Martian igneous and mantle compositions is crucial for understanding Mars' mantle evolution, including early differentiation, mantle convection, and the chemical alteration at the surface. Primitive magmas provide the most direct information about their mantle source regions, but most Martian meteorites either contain cumulate olivine or crystallized from fractionated melts. The new Martian meteorite Northwest Africa (NWA) 6234 is an olivine‐phyric shergottite. Its most magnesian olivine cores (Fo₇₈) are in Mg‐Fe equilibrium with a magma of the bulk rock composition, suggesting that it represents a melt composition. Thermochemical calculations show that NWA 6234 not only represents a melt composition but is a primitive melt derived from an approximately Fo₈₀ mantle. Thus, NWA 6234 is similar to NWA 5789 and Y 980459 in the sense that all three are olivine‐phyric shergottites and represent primitive magma compositions. However, NWA 6234 is of special significance because it represents the first olivine‐phyric shergottite from a primitive ferroan magma. On the basis of Al/Ti ratio of pyroxenes in NWA 6234, the minor components in olivine and merrillite, and phosphorus zoning of olivine, we infer that the rock crystallized completely at pressures consistent with conditions in Mars' upper crust. The textural intergrowths of the two phosphates (merrillite and apatite) indicate that at a very last stage of crystallization, merrillite reacted with an OH‐Cl‐F‐rich melt to form apatite. As this meteorite crystallized completely at depth and never erupted, it is likely that its apatite compositions represent snapshots of the volatile ratios of the source region without being affected by degassing processes, which contain high OH‐F content.     

Paleosols in Central Illinois as Potential Sources of Ammonium in Groundwater

Glacially buried paleosols of pre-Holocene age were evaluated as potential sources for anomalously large concentrations of ammonium in groundwater in East Central Illinois. Ammonium has been detected at concentrations that are problematic to water treatment facilities (greater than 2.0 mg/L) in this region. Paleosols characterized for this study were of Quaternary age, specifically Robein Silt samples. Paleosol samples displayed significant capacity to both store and release ammonium through experiments measuring processes of sorption, ion exchange, and weathering. Bacteria and fungi within paleosols may significantly facilitate the leaching of ammonium into groundwater by the processes of assimilation and mineralization. Bacterial genetic material (DNA) was successfully extracted from the Robein Silt, purified, and amplified by polymerase chain reaction to produce 16S rRNA terminal restriction fragment length polymorphism (TRFLP) community analyses. The Robein Silt was found to have established diverse and viable bacterial communities. 16S rRNA TRFLP comparisons to well-known bacterial species yielded possible matches with facultative chemolithotrophs, cellulose consumers, nitrate reducers, and actinomycetes. It was concluded that the Robein Silt is both a source and reservoir for groundwater ammonium. Therefore, the occurrence of relatively large concentrations of ammonium in groundwater monitoring data may not necessarily be an indication of only anthropogenic contamination. The results of this study, however, need to be placed in a hydrological context to better understand whether paleosols can be a significant source of ammonium to drinking water supplies.     

Definition of the Spatial Propagator and Implications for Magnetic Field Properties

Solar Physics - We study a quiet-Sun blowout jet which was observed on 2014 May 16 by the instruments on board the Solar Dynamics Observatory (SDO). We find the twin CME as jet-like and bubble-like...     

Bandpass calibration of a wideband spectrometer using coherent pulse injection

We present a relatively simple time domain method for determining the bandpass response of a system by injecting a nanosecond pulse and capturing the system voltage output. A pulse of sub-nanosecond duration contains all frequency components with nearly constant amplitude up to 1 GHz. Hence, this method can accurately determine the system bandpass response to a broadband signal. In a novel variation on this impulse response method, a train of pulses is coherently accumulated providing precision calibration with a simple system. The basic concept is demonstrated using a pulse generator-accumulator setup realised in a Bedlam board which is a high speed digital signal processing unit. The same system was used at the Parkes radio telescope between 2–13 October 2013 and we demonstrate its powerful diagnostic capability. We also present some initial test data from this experiment.     

Trace elements and polycyclic aromatic hydrocarbons (PAHs) concentrations in deep Gulf of Mexico sediments

The concentrations of polycyclic aromatic hydrocarbons (PAHs) and trace elements were determined for surface (top 2 cm) sediment samples collected during the deep Gulf of Mexico benthos (DGoMB) study .These elements and compounds are known to be toxic to organisms at high concentrations and may affect biological communities. There is no indication of major anthropogenic input of the elements Be, Co, Cr, Fe, Si, Tl, V, K, Mg, Ca, Sr and Zn, based on normalization to Al. The concentrations of these metals in the sediment are a function of the relative amounts of trace-metal-rich Mississippi River-derived silicate material and trace-metal-poor plankton-derived carbonate. This is not true for the elements Ba, Ni, Pb, Cd, As, Cu and Mn, whose concentrations show considerable scatter when normalized to Al and a general enrichment. On a normalized basis, Mn is enriched 5–10 fold, Cu and Ni 2–3 fold and Pb 2 fold over Mississippi River-derived material. These enrichments are likely the result of remobilization of metals from depths in the sediment column where reducing conditions exist. The Ba concentrations at selected sites are higher than those of average clay-rich sediments, but are typical of sediments from near oil well platforms in the northern Gulf of Mexico. In the case of Ba, it seems likely that the enrichments, as high as a factor of 10, are due to disposal of oil well drilling mud. The Ba-enriched samples are from the three shallowest water sites in the Mississippi Trough (sites MT1, 2 and 3) and from site C1 and WC5. All are in an area of intense petroleum exploration and development. PAH concentrations are also elevated at MT1, MT3 and C1. The total PAH concentration ranged from not detected (ND) to 1033 ng/g with a mean of 140 ng/g. Even at the sites most enriched in PAHs and trace elements, the concentrations are not at the levels expected to adversely affect the biota. However, these predicted non-effects are based on research using mostly near-shore estuarine species, not on the indigenous species at the sampling sites.     

Reaction pathways for quartz dissolution determined by statistical and graphical analysis of macroscopic experimental data

In light of recent work on the reactivity of specific sites on large (hydr)oxo-molecules and the evolution of surface topography during dissolution, we examined the ability to extract molecular-scale reaction pathways from macroscopic dissolution and surface charge measurements of powdered minerals using an approach that involved regression of multiple datasets and statistical graphical analysis of model fits. The test case (far-from-equilibrium quartz dissolution from 25 to 300 °C, pH 1-12, in solutions with [Na⁺] ? 0.5 M) avoids the objections to this goal raised in these recent studies. The strategy was used to assess several mechanistic rate laws, and was more powerful in distinguishing between models than the statistical approaches employed previously. The best-fit model included three mechanisms—two involving hydrolysis of Si centers by H₂O next to neutral (>Si-OH⁰) and deprotonated (>Si-O⁻) silanol groups, and one involving hydrolysis of Si centers by OH⁻. The model rate law is

     

Palynofacies, coal petrographic facies and depositional environments: Amphitheatre formation (Eocene to Oligocene) and Ravenscrag Formation (Maastrichtian to Paleocene), Canada

Low rank coals from two disparate geological settings have been subjected to petrographic and palynological analysis. The stratigraphic units studied and their locations are the Amphitheatre Formation, St Elias Mountains, Yukon Territory, of Eocene to Oligocene age; and the base of the Ravenscrag Formation, south-central Saskatchewan, of latest Cretaceous to earliest Paleocene age.The depositional setting of the Amphitheatre Formation ranges from distal sand-dominated braided stream and lacustrine environments to proximal gravel-dominated fluvial environments. The coals are low in inertinite (< 6%) and mostly high in huminite (> 85%). In localities with a dominance of angiosperm pollen the relative abundance of eu-ulminite B and densinite is greatest whereas in the ones with a dominantly coniferous pollen assemblage eu-ulminite A is the most prominent maceral. These observations suggest as an immediate cause/effect relationship, an at least partial dependance of present maceral content on floral precursors. This in turn probably reflects a certain combination of depositional environment conditions (pH, Eh, temperature, etc.), that likely controlled the plant community and the preservation of vegetal matter.The depositional environment of coals from the basal part of the Ravenscrag Formation contrasts sharply with that of the Amphitheatre. The Ravenscrag coals formed within a low energy, stable, floodplain environment. Palynological and coal maceral profiles for the basal Ravenscrag Formation coal, which spans the Cretaceous-Tertiary boundary, indicates that the environment of deposition progressed from an open canopied swamp forest with areas of open water, through a phase of low-lying to open water swamps with herbaceous, pterophytic vegetation to, at least locally, raised bogs. The change in coal petrography across the Cretaceous-Tertiary boundary is shown to be relatively minor in comparison to subsequent changes in coal petrography in the earliest Paleocene and to changes that occur in the palynological assemblages across the boundary interval.