Photocatalytic splitting of seawater effected by (Ni–ZnO)@C nanoreactors

Novel photocatalysts i.e., metallic nickel and zinc oxide nanoparticles embedded in the carbon-shell ((Ni–ZnO)@C) have been used for photocatalytic splitting of seawater to generate H₂. The (Ni–ZnO)@C core–shell nanoparticles having the Zn/Ni ratios of 0–3 were prepared by carbonization of Ni²⁺- and Zn²⁺-β-cyclodextrin at 673 K for 2 h. To increase the collision frequency of water and photoactive sites within the carbon-shell, Ni and ZnO are partially etched from the (Ni–ZnO)@C core–shell to form yolk–shell nanoparticles with a H₂SO₄ solution (2 N). By X-ray diffraction spectroscopy, mainly Ni and ZnO crystallites are observed in the core– and yolk–shell nanoparticles. The sizes of the Ni and ZnO in the (Ni–ZnO)@C nanoreactors are between 7 and 23 nm in diameters determined by TEM and small angel scattering spectroscopy. Under a 5-h UV–Vis light irradiation, 5.01 μmol/hg_cat of H₂ are yielded from photocatalytic splitting of seawater effected by (Ni–ZnO)@C nanoreactors.     

Comparison of carbon cycle between the western Pacific subarctic and subtropical time-series stations: highlights of the K2S1 project

A comparative study of ecosystems and biogeochemistry at time-series stations in the subarctic gyre (K2) and subtropical region (S1) of the western North Pacific Ocean (K2S1 project) was conducted between 2010 and 2013 to collect essential data about the ecosystem and biological pump in each area and to provide a baseline of information for predicting changes in biologically mediated material cycles in the future. From seasonal chemical and biological observations, general oceanographic settings were verified and annual carbon budgets at both stations were determined. Annual mean of phytoplankton biomass and primary productivity at the oligotrophic station S1 were comparable to that at the eutrophic station K2. Based on chemical/physical observations and numerical simulations, the likely “missing nutrient source” was suggested to include regeneration, meso-scale eddy driven upwelling, meteorological events, and eolian inputs in addition to winter vertical mixing. Time-series observation of carbonate chemistry revealed that ocean acidification (OA) was ongoing at both stations, and that the rate of OA was faster at S1 than at K2 although OA at K2 is more critical for calcifying organisms.     

Phytoplankton community structure in Otsuchi Bay,northeastern Japan,after the 2011 off the Pacific coast of Tohoku Earthquake and tsunami

The tsunami caused by the 2011 off the Pacific coast of Tohoku Earthquake seriously damaged the Pacific coast of northeastern Japan. In addition to its direct disturbance, a tsunami can indirectly affect coastal pelagic ecosystems via topographical and environmental changes. We investigated seasonal changes in the phytoplankton community structure in Otsuchi Bay, northeastern Japan, from May 2011, which was 2 months after the tsunami, to May 2013. The phytoplankton species composition in May 2011 was similar to that observed in May 2012 and 2013. The present results are consistent with the dominant species and water-mass indicator species of phytoplankton in past records. These results suggest that there was no serious effect of the tsunami on the phytoplankton community in Otsuchi Bay. Community analysis revealed that two distinct seasonal communities appeared in each year of the study period. The spring–summer community was characterized by warm-water Chaetoceros species, and dinoflagellates appeared from May to September. The fall–winter community was characterized by cold neritic diatoms, which appeared from November to March. The succession from the spring–summer community to the fall–winter community took place within a particular water mass, and the fall–winter community appeared in both the surface water and the Oyashio water mass, suggesting that water-mass exchange is not the only factor that determines the phytoplankton community structure in Otsuchi Bay.     

Epigenetic salt accumulation and water movement in the active layer of central Yakutia in eastern Siberia

Observations of soil moisture and salt content were conducted from May to August at Neleger station in eastern Siberia. Seasonal changes of salt and soil moisture distribution in the active layer of larch forest (undisturbed) and a thermokarst depression known as an alas (disturbed) were studied. Electric conductivity EC_e of the intact forest revealed higher concentrations that increased with depth from the soil surface into the active layer and the underlying permafrost: 1 mS cm^?1 at 1·1 m, to 2·6 mS cm^?1 at 160 cm depth in the permafrost. However, a maximum value of 5·4 mS cm^?1 at 0·6 m depth was found in the dry area of the alas. The concentration of ions, especially Na⁺, Mg²⁺, Ca²⁺, SO₄^2? and HCO₃^? in the upper layers of this long‐term disturbed site, indicates the upward movement of ions together with water. A higher concentration of solutes was found in profiles with deeper seasonal thawing. The accumulation of salts in the alas occurs from spring through into the growing season. The low concentration of salt in the surface soil layers appears to be linked to leaching of salts by rainfall. There are substantial differences between water content and electric conductivity of soil in the forest and alas. Modern salinization of the active layer in the alas is epigenetic, and it happens in summer as a result of spring water collection and high summer evaporation; the gradual salt accumulation in the alas in comparison with the forest is controlled by the annual balance of water and salts in the active layer. Present climatic trends point to continuous permafrost degradation in eastern Siberia increasing the risk of surface salinization, which has already contributed to changing the landscape by hindering the growth of forest. Copyright © 2006 John Wiley & Sons, Ltd.     

A distinction technique between volcanic and tectonic depression structures based on the restoration modeling of gravity anomaly: a case study of the Hohi volcanic zone, central Kyushu, Japan

In this study, we propose a numerical modeling technique which restores the gravity anomaly of tectonic origin and identifies the gravity low of caldera origin. The identification is performed just by comparing the restored gravity anomalies with the observed gravity anomalies, thus we do not need detailed geophysical and geological information around the buried caldera. The technique has been successfully applied to distinguish the gravity low originated in the buried Shishimuta caldera from other gravity lows in the Hohi volcanic zone, central Kyushu in Japan.     

Neotectonics of the Eastern Korean Margin Inferred from Back-arc Rifting Structure

Earthquakes occur frequently in the continental shelf and slope area of the Korean Peninsula in the East Sea (Japan Sea) although they are mostly not large in magnitude. This area constitutes the eastern Korean margin, marking a transitional structure from rifted continental crust to oceanic crust that resulted from lithospheric extension into breakup in a back-arc. We reviewed how the crustal structure of the eastern Korean margin was emplaced to understand its correlation with the present seismicity. Back-arc extension that caused rifting and breakup at the Korean margin took place sequentially from the northern to southern parts in the Late Oligocene through the Early Miocene. The stress regime of the Korean margin switched from extension to compression in the Middle Miocene, resulting from the collision of the Philippine Sea Plate with the Japan Arc. The structural lineations at the Korean margin inherited from backarc rifting and breakup are interpreted to be prone to earthquakes by showing a close spatial correlation with ongoing seismicity. The changing geometry of the estimated locus of breakup at the Korean margin that follows a curvilinear path appears to induce diverse focal mechanisms of the earthquakes under the present compressive stress field.     

Effects of the copepod community structure on fecal pellet flux in Kagoshima bay,a deep,semi-enclosed embayment

Seasonal changes in the shape and size composition of fecal pellets were investigated with sediment trap samples from 50 and 150 m in Kagoshima Bay to evaluate how the mesozooplankton community affects fecal pellet flux. Deep vertical mixing was evident in March, and thermal stratification was developed above 50 m in June, August and November. Chlorophyll a, suspended particulate organic carbon (POC) and copepod abundance were uniform throughout the water column during the seasonal mixing and concentrated above 50 m in the stratified seasons. Calanoids were the most predominant copepods in March and poecilostomatoids composed more than 45% of the copepod community in June, August and November. Fecal pellet fluxes at 50 and 150 m were the highest in March, nearly half of POC flux. The relative contribution declined considerably in the other months, especially for less than 4% of POC flux in August. The decline was corresponded to the predominance of cyclopoids and poecilostomatoids. Cylindrical pellets dominated the fecal matters at both depths throughout the study period, while larger cylindrical pellets nearly disappeared at 150 m in June, August and November. Copepod incubation revealed that cylindrical and oval pellets were egested by calanoids and the other copepods, respectively. We suggest that cylindrical fecal pellets produced by calanoid copepods contribute to feces flux but the predominance of poecilostomatoids and/or cyclopoids decreases feces flux via the increase of oval pellets and fragmentation of larger cylindrical pellets.