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301.
Scott D. Woodruff Henry F. Diaz Steven J. Worley Richard W. Reynolds Sandra J. Lubker 《Climatic change》2005,73(1-2):169-194
Many surface marine meteorological observations (∼125 million) from ships' logbooks have been assembled in the International
Comprehensive Ocean-Atmosphere Data Set (ICOADS) back to the late 18th century. We describe the makeup of the available data
before 1950, and a recent update for that period incorporating a variety of US and international sources – focusing on the
background, digitization, and processing of the US Maury Collection, which provides the earliest data (mainly 1830–1860) currently
blended into ICOADS. We also describe planned data and metadata additions to early ICOADS. Among these, the new Climatological
Database for the World's Oceans (CLIWOC) will extend and enhance coverage for 1750–1854. Prospects for data improvements and
homogeneity enhancements to further benefit climate research are also discussed. 相似文献
302.
Drying of masonry specimens was monitored by means of a two-dimensional (2D) magnetic resonance imaging (MRI) technique. The
external surfaces stayed wet for longer if NaCl was present instead of pure water only. This corroborates many practical observations
that salts aggravate dampness in masonry. A slower evaporation process and not hygroscopicity was the cause. That suggests
that salt-induced dampness may, in general, arise simply from changes in the drying process of masonry materials. That also
implies that the height and depth at which crystallization occurs in walls may depend on the relative equilibrium humidity
(RHeq) and other properties of salts that influence drying of porous materials. Evaporation rates of free surfaces of pure
water and saturated NaCl solution were measured by a gravimetric technique. The results indicate that slow drying of salt-contaminated
materials is not due only to the lower RHeq of salt solutions. The effective surface of evaporation is likely to be reduced
perhaps due to blocking of pores by salt crystals. Final salt-distribution maps of the specimens show that: (a) salts may
affect the inner materials of the masonry, even in evaporation-induced processes that lead crystallization to occur predominantly
on the external surface; (b) distinct internal distribution patterns occur if masonry composition varies.
Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users. 相似文献
303.
Enrique Peña González Joaquín Suárez López Jordi Delgado Martín Alfredo Jácome Burgos Jerónimo Puertas Agudo 《Environmental Geology》2006,50(6):823-834
The cutting operations of dimension stone at quarries produce a large amount of fines that, in turn, cause a negative environmental impact over local surface waters. This article presents a detailed analysis of the mobilized contamination associated with runoff waters in a large granite quarry (~200 ha) which is located in Porriño (Galicia, NW Spain), the most important production centre of dimension stone in Spain. There, an intensive monitoring survey was developed in order to characterize the hydrology of the system as well as the release and transport of pollutants. This was accomplished by means of different control sections for the flow and by the collection of 52 random water samples. Automatic samplers were also used to collect 192 water samples associated with runoff generated by significant rain events. For each of the samples collected, a wide battery of analytic determinations was performed, including solid loads, turbidity, organic pollution, nutrient and selected metals. Upon careful examination it has been possible to obtain different parameters related to the contamination control, like the “event mean concentration” (EMC), maximum concentrations and specific sediment loads. Moreover, a comprehensive statistical study including parameter correlation and cumulative probability analyses helped to understand the pollutant mobilization behaviour within the quarry system. It can be concluded that mobilized contamination shows the anomalous presence of some metals, whose concentrations are in excess when compared to the natural rock. This excess metal amount must be attributed to an anthropogenic source associated to mining and cutting operations. 相似文献
304.
Chemical composition and nutrient concentrations of 39 relatively poorly known Patagonian lakes (38–50°S and from 70° to 68°W) are described and analysed using principal component analysis (PCA). The general relationships between nutrients (total phosphorus, bioavailable phosphorus and dissolved inorganic nitrogen) and plankton biomass are examined.We seek to demonstrate that the extreme oligotrophy characterising many lakes and reservoirs of the Argentine Patagonian region of South America owes more to nitrogen deficiency than to a shortage of available phosphorus. The data show a range of trophic conditions with variable water chemistry characteristics.The first two axes of the PCA ordination explain most of the variance (63%). The first component of the variance in the environmental data is a trophic gradient, with positive correlations with the concentrations of nutrients (TP, SRP, DIN) and electrical conductivity and a negative correlation with transparency. For all the reservoirs considered, the calculated annual, summer and winter chlorophyll-a carrying capacities of the available phosphorus were consistently and significantly (P<0.05) in excess of observations but maximum chlorophyll-a values correlate with DIN availability. Indeed the chlorophyll-a carrying capacities, as an index of the resource-sustainable maximum biomass, of the available nitrogen gives a better predictive yield relationship than does P. Our findings are remarkable in so far as the general expectation that dinitrogen-fixing phytoplankton should thrive in the absence of dissolved inorganic nitrogen, at least to the supportive limits of the available phosphorus, is unfulfilled. 相似文献
305.
Robert J. Diaz Donald C. Rhoads James A. Blake Roy K. Kropp Kenneth E. Keay 《Estuaries and Coasts》2008,31(6):1184-1197
A combination of methods (infaunal grabs and sediment profile cameras) were used to monitor the response of Boston Harbor
benthic habitats to reductions in wastewater associated with movement of the outfalls to the mouth of the harbor and then
offshore. From 1992 to 2006, there was strong evidence that benthic habitats within Boston Harbor have shifted from a more
anaerobic state to a more aerobic state and that these changes are directly related to changes in carbon loading associated
with outfall placement and improvements in wastewater treatment. Over the period of 1992 to 2000, when the ocean outfall started
to operate, there was >90% reduction in organic loadings to Boston Harbor from 11,400 to 1,200 t C per year. There were also
corresponding decreases in primary production due to reduced nutrient loadings. The most apparent change in harbor benthos
was the widespread increase in 1992 and subsequent decline by 2005 in Ampelisca spp. tube mats. The long-term increase in thickness of the apparent color redox potential discontinuity layer was consistent
with reductions in organic loading and increases in bioturbation. The optimal organic loading for maintaining large areas
of amphipod tube mats and high bioturbation rates was around 500 g C per square meter per year. Above and below this level,
the area of tube mats in Boston Harbor declined. 相似文献
306.
307.
Salt decay is a very destructive mechanism that affects frequently the porous building materials of our architectural heritage. Sodium sulfate is one of the salts found in this context. It usually demonstrates high destructive power in salt crystallization tests because it can crystallize not only during evaporative processes but also when the temperature drops or when the salt solution comes into contact with pre-existing crystals. However, the use of extreme temperatures or successive wet/dry cycles also makes these tests unrepresentative of reality. To verify whether sodium sulfate can also be so destructive in field conditions, we have performed crystallization tests consisting of a single isothermal drying event. Three natural stones, relevant for the architectural heritage, were used for the purpose: Bentheimer sandstone, Ançã limestone, and a current Portuguese limestone of low porosity. The stones gave rise to distinct salt decay patterns: efflorescence, multilayer delamination and unilayer delamination, respectively. These morphological alterations were characterized at the micrometer scale by a new method based on what we have called the alteration kinetics curve. Such curve is calculated from topographic profiles obtained by a non-contact optical technique. The multilayer and unilayer delamination decay were also monitored by time-lapse photography. The work led us to conclude that sodium sulfate can indeed be also very destructive in field-representative conditions. Moreover, it showed that the optical method can be a valuable aid in the development of more realistic salt crystallization tests. 相似文献
308.
Jordi A Ferrer MI Vizoso G Orfila A Basterretxea G Casas B Alvarez A Roig D Garau B Martínez M Fernández V Fornés A Ruiz M Fornós JJ Balaguer P Duarte CM Rodríguez I Alvarez E Onken R Orfila P Tintoré J 《Marine pollution bulletin》2006,53(5-7):361-368
The oil spill from Prestige tanker showed the importance of scientifically based protocols to minimize the impacts on the environment. In this work, we describe a new forecasting system to predict oil spill trajectories and their potential impacts on the coastal zone. The system is formed of three main interconnected modules that address different capabilities: (1) an operational circulation sub-system that includes nested models at different scales, data collection with near-real time assimilation, new tools for initialization or assimilation based on genetic algorithms and feature-oriented strategic sampling; (2) an oil spill coastal sub-system that allows simulation of the trajectories and fate of spilled oil together with evaluation of coastal zone vulnerability using environmental sensitivity indexes; (3) a risk management sub-system for decision support based on GIS technology. The system is applied to the Mediterranean Sea where surface currents are highly variable in space and time, and interactions between local, sub-basin and basin scale increase the non-linear interactions effects which need to be adequately resolved at each one of the intervening scales. Besides the Mediterranean Sea is a complex reduced scale ocean representing a real scientific and technological challenge for operational oceanography and particularly for oil spill response and search and rescue operations. 相似文献
309.
Patrick Raimbault Wilfried Pouvesle Frdric Diaz Nicole Garcia Richard Sempr 《Marine Chemistry》1999,66(3-4)
We developed a simple and reliable method which allows simultaneous determination of organic forms of carbon (DOC), nitrogen (DON) and phosphorus (DOP) dissolved in seawater. Conversion of dissolved organic matter (DOM) to inorganic products (carbon dioxide, nitrate+nitrite and soluble reactive phosphate) is performed by a persulfate wet-oxidation in low alkaline condition. After oxidation, the concentration of the inorganic products dissolved in the sample was measured automatically by colorimetry using a 3-channel Technicon AutoAnalyzer system. A number of pure organic compounds were tested in the concentration range encountered in coastal and open ocean, indicating a high efficiency of the digestion procedure. The recovery range is similar to that obtained by other wet-oxidation procedures and by high-temperature catalytic oxidation techniques. Direct comparisons with usual methods used for separate determination of DOC, DON and DOP indicated a high efficiency of the procedure. Reproducibility tests demonstrated a very good precision (around 5%) for lagoonal and coastal waters, while precision was sometimes around 10–25% in oligotrophic oceanic waters, especially for DOP where values approached limits of detection for measuring phosphate. This method is highly suitable for routine analysis and especially appropriate for shipboard work. 相似文献
310.
Diaz John Carnevale Shannon Millett Cheryl Abd-Elrahman Amr Britt Katie 《Natural Hazards》2020,103(2):1905-1916
Natural Hazards - Natural ecosystems are characterized as dynamic systems that evolve through natural patterns of disturbance. Land managers can work within this system of natural disturbance by... 相似文献