On the limits of using combined U-series/ESR method to date fossil teeth from two Early Pleistocene archaeological sites of the Orce area (Guadix-Baza basin,Spain)

The combined U-series/electron spin resonance (ESR) dating method was applied to nine teeth from two Early Pleistocene archaeological sites located in the Orce area (Guadix-Baza Basin, Southern Spain): Fuente Nueva-3 (FN-3) and Barranco León (BL). The combination of biostratigraphy and magnetostratigraphy places both sites between the Olduvai and Jaramillo subchrons (1.78–1.07 Ma).Our results highlight the difficulty of dating such old sites and point out the limits of the combined U-series/ESR dating method based on the US model. We identified several sources of uncertainties that may lead to inaccurate age estimates. Seven samples could not be dated because the dental tissues had (²³⁰Th/²³⁴U) activity ratios higher than equilibrium, indicating that uranium had probably leached from these tissues. It was however possible to calculate numerical estimates for two of the teeth, both from FN-3. One yielded a Middle Pleistocene age that seems to be strongly underestimated; the other provided an age of 1.19 ± 0.21 Ma, in agreement with data obtained from independent methods. The latter result gives encouragement that there are samples that can be used for routine dating of old sites.     

Assessing aquifer vulnerability to pollutants by electrical resistivity tomography (ERT) at a nitrate vulnerable zone in NE Spain

There is an increasing demand for groundwater vulnerability maps which illustrate the exposure of aquifers against pollution. These maps show areas of greatest potential for groundwater contamination on the basis of local subsurface conditions. Parameters affecting vulnerability are mainly permeability and thickness of each protective layer. For unconsolidated sediments, the permeability is strongly related to the clay content, which can be deduced from indirect resistivity methods, like electrical-imaging. Such geophysical methods can be of great help in groundwater vulnerability studies because they disturb neither the structure nor the dynamics of the soil. Sensibility analysis was performed of the electrical resistivity tomography method for accurately mapping soil media. Managers and public administrators may effectively use this method for assessing the potential risk of groundwater contamination. In the studied zone, electrical resistivity exhibits a wide range of variability that can be easily correlated to soil parameters, such as clay content and hydraulic conductivity. A numerical index of protection has been assessed from the geophysical information derived from 2D electrical resistivity tomography. This work represents a preliminary approach on the natural vulnerability evaluation of shallow aquifers at the Empordà basin (NE Spain) that is highly affected by diffuse pollution by nitrates.     

Study of the interaction between U(VI) and the anoxic corrosion products of carbon steel

The objective of this study was to investigate the removal mechanism of U(VI) from groundwater by magnetite as the main product of anoxic steel corrosion. For this purpose, a systematic sequence of batch experiments was conducted to focus the active role of magnetite in the reduction of U under different conditions. Results indicated that under anoxic conditions U(VI) was sorbed at the magnetite surface, whereas under reducing conditions at different H₂(g) pressures, U was present in tetravalent form as amorphous UO₂.     

Age and sources of gold mineralization in the Marmato mining district, NW Colombia: A Miocene–Pliocene epizonal gold deposit

Epigenetic gold mineralization occurs in the Marmato mining district, within the Calima Terrain of the Setentrional Andes, Colombia. Regional rocks associated with this mineralization include: graphite- and chlorite-schists of the Arquia Complex; metamorphosed during the Cretaceous, Miocene sandstones, shales and conglomerates of the Amagá Formation; as well as pyroclastic rocks (clasts of basalt, andesites and mafic lavas) and subvolcanic andesitic/dacitic bodies of the Combia Formation (9 to 6 Ma). The subvolcanic Marmato stock hosts mesothermal and epithermal low-sulfidation Au–Ag ores in the form of distensional veins, stockwork, and quartz veinlets within brecciated zones. Ore minerals are pyrite, sphalerite and galena with subordinate chalcopyrite, arsenopyrite, pyrrhotite, argentite and native gold/electrum.Sericitized plagioclase from a porphyry dacite yielded a K–Ar age of 5.6 ± 0.6 Ma, interpreted as the age of ore deposition. This is in close agreement with the age of reactivation of the Cauca–Romeral Fault System (5.6 ± 0.4 Ma), which bounds the Calima Terrain. A porphyry andesite–dacite (6.7 ± 0.1 Ma), hosting the Au–Ag veins, shows a measured ⁸⁷Sr/⁸⁶Sr between 0.70440 and 0.70460, ε_Nd between + 2.2 and + 3.2 and ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios of 18.964 to 19.028; 15.561 to 15.570; and 38.640 to 38.745, respectively. The ⁸⁷Sr/⁸⁶Sr and ε_Nd values of rocks from the Arquia Group range from 0.70431 to 0.73511 and − 12.91 to + 10.0, respectively, whereas the corresponding Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb) range from 18.948 to 19.652; 15.564 to 15.702; and 38.640 to 38.885, respectively. ⁸⁷Sr/⁸⁶Sr and ε_Nd values obtained on sulfides from the gold quartz veins, which occur at shallow and intermediate levels, range from 0.70500 to 0.71210 and from − 1.11 to + 2.40. In the deepest veins, ε_Nd values lie between + 1.25 and + 3.28 and the ⁸⁷Sr/⁸⁶Sr of calcite and pyrite fall between 0.70444 and 0.70930. The ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios of all mineralization are in the ranges 18.970 to 19.258; 15.605 to 15.726 and 38.813 to 39.208, respectively. Carbonates have an average ⁸⁷Sr/⁸⁶Sr ratio of 0.70445, which is within the range of values measured in the host dacite. The Sr isotopic data indicate that carbonic fluids have a restricted hydrothermal circulation within the host igneous body, while the Sr, Pb and Nd isotopic compositions of the sulfides suggest that the fluids not only circulated within the Marmato stock, but also throughout the Arquia Complex, inferring that these rocks offer a potential target for mineral exploration. Based on geological and geochronological evidence, the epizonal Marmato gold ores formed during the Miocene to Pliocene, as a result of cooling of the Marmato stock and reactivation along a crustal-scale fault zone related to thermal processes in an accretionary oceanic–continental plate orogen.     

Evolutionary and pulsational properties of white dwarf stars

White dwarf stars are the final evolutionary stage of the vast majority of stars, including our Sun. Since the coolest white dwarfs are very old objects, the present population of white dwarfs contains a wealth of information on the evolution of stars from birth to death, and on the star formation rate throughout the history of our Galaxy. Thus, the study of white dwarfs has potential applications in different fields of astrophysics. In particular, white dwarfs can be used as independent reliable cosmic clocks, and can also provide valuable information about the fundamental parameters of a wide variety of stellar populations, such as our Galaxy and open and globular clusters. In addition, the high densities and temperatures characterizing white dwarfs allow these stars to be used as cosmic laboratories for studying physical processes under extreme conditions that cannot be achieved in terrestrial laboratories. Last but not least, since many white dwarf stars undergo pulsational instabilities, the study of their properties constitutes a powerful tool for applications beyond stellar astrophysics. In particular, white dwarfs can be used to constrain fundamental properties of elementary particles such as axions and neutrinos and to study problems related to the variation of fundamental constants. These potential applications of white dwarfs have led to renewed interest in the calculation of very detailed evolutionary and pulsational models for these stars. In this work, we review the essentials of the physics of white dwarf stars. We enumerate the reasons that make these stars excellent chronometers, and we describe why white dwarfs provide tools for a wide variety of applications. Special emphasis is placed on the physical processes that lead to the formation of white dwarfs as well as on the different energy sources and processes responsible for chemical abundance changes that occur along their evolution. Moreover, in the course of their lives, white dwarfs cross different pulsational instability strips. The existence of these instability strips provides astronomers with a unique opportunity to peer into their internal structure that would otherwise remain hidden from observers. We will show that this allows one to measure stellar masses with unprecedented precision and to infer their envelope thicknesses, to probe the core chemical stratification, and to detect rotation rates and magnetic fields. Consequently, in this work, we also review the pulsational properties of white dwarfs and the most recent applications of white dwarf asteroseismology.     

Vulnerability of simple reinforced concrete buildings to damage by rockfalls

A procedure is presented for investigating the response of reinforced concrete buildings to rockfall impact. The method considers a single rock hit on the basement columns, and it includes four steps: (a) calculation of the probability of a rock impact on a member of the load-bearing system, taking into account the block size and the design of the structure; (b) evaluation of the response of one or more structural elements to the hit based on element capacity; (c) in the case of structural element failure, assessment of the robustness of the whole structural system, calculating the potential for progressive collapse; and (d) calculation of a damage index (DI), which is the ratio of structural elements that fail to the total number of structural elements. The proposed method is applied to a reinforced concrete building for a range of rockfall paths and intensities. The analysis has been carried out for a 2-m-diameter block and velocities < 3.5 m/s. The possible damage range is found to be highly variable, with DI values ranging from 0.01 to 1 depending on the impact location and block velocity.     

The Cali meteorite fall: A new H/L ordinary chondrite

Abstract— The fall of the Cali meteorite took place on 6 July 2007 at 16 h 32 ± 1 min local time (21 h 32 ± 1 min UTC). A daylight fireball was witnessed by hundreds of people in the Cauca Valley in Colombia from which 10 meteorite samples with a total mass of 478 g were recovered near 3°24.3′N, 76°30.6′W. The fireball trajectory and radiant have been reconstructed with moderate accuracy. From the computed radiant and from considering various plausible velocities, we obtained a range of orbital solutions that suggest that the Cali progenitor meteoroid probably originated in the main asteroid belt. Based on petrography, mineral chemistry, magnetic susceptibility, thermoluminescence, and bulk chemistry, the Cali meteorite is classified as an H/L4 ordinary chondrite breccia.