Isotopic and trace-element profiles across the New Britain island arc,Papua New Guinea

New Pb-, Sr-, and Nd-isotopic data have been obtained for the rocks of volcanoes overlying a wide range of depths (100–580 km) to the Wadati-Benioff Zone (WBZ) in the New Britain island arc, Papua New Guinea. Well-defined trends consistent with two-component mixing are observed in combined Pb-isotope/trace-element plots. One of the components is believed to represent a slab contribution whose isotopic signature, unlike those noted for several other arcs, appears to be dominated by subducted, altered, oceanic crust rather than by sediment. This conclusion is consistent with the results of a recent Be–B study of New Britain rocks. The influence of the slab component is considered to decrease as depth to the WBZ increases. Higher abundances of high-field-strength elements correlate with increasing depths to the WBZ, and may be indicative of smaller degrees of partial melting of the mantle wedge as WBZ depths increase. Abundances of other incompatible elements appear to reflect a complex interplay between the slab-derived flux and melting process.     

Considerations for the Design of In Situ Vapor Extraction Systems: Radius of Influence vs. Zone of Remediation

When designing in situ soil vapor extraction systems, the number and placement of vapor extraction wells arc typically based on the radius of influence determined from some combination of pilot test data, theoretical considerations, and experience. In this report, we examine common methods used to determine the radius of influence, and through examples we illustrate how effective this remedial design approach is. Significant conclusions arc the following: (a) systems designed by radius of influence-based approaches may never achieve desired remedial goals: (b) systems designed by radius of influence-based approaches may result in longer operation times and higher total costs than a system that incorporates remedial goals and some level of fundamentally based predictive modeling: and (c) at best, the radius of influence-based approach ensures containment of contaminant vapors.     

Miocene-Pliocene half-graben evolution, detachment faulting and late-stage core complex uplift from reflection seismic data in south-east Arizona

Reflection seismic data show that the late Cenozoic Safford Basin in the Basin and Range of south-eastern Arizona, is a 4.5-km-deep, NW-trending, SW-dipping half graben composed of middle Miocene to upper Pliocene sediments, separated by a late Miocene sequence boundary into lower and upper basin-fill sequences. Extension during lower basin-fill deposition was accommodated along an E-dipping range-bounding fault comprising a secondary breakaway zone along the north-east flank of the Pinaleño Mountains core complex. This fault was a listric detachment fault, active throughout the mid-Tertiary and late Cenozoic, or a younger fault splay that cut or merged with the detachment fault. Most extension in the basin was accommodated by slip on the range-bounding fault, although episodic movement along antithetic faults temporarily created a symmetric graben. Upper-plate movement over bends in the range-bounding fault created rollover structures in the basin fill and affected deposition within the half graben. Rapid periods of subsidence relative to sedimentation during lower basin-fill deposition created thick, laterally extensive lacustrine or alluvial plain deposits, and restricted proximal alluvian-fan deposits to the basin margins. A period of rapid extension and subsidence relative to sediment influx, or steepening of the upper segment of the range-bounding fault at the start of upper basin-fill deposition resulted in a large downwarp over a major fault bend. Sedimentation was restricted to this downwarp until filled. Episodic subsidence during upper basin-fill deposition caused widespread interbedding of lacustrine and fluvial deposits. Northeastward tilting along the south-western flank of the basin and north-eastward migration of the depocentre during later periods of upper basin-fill deposition suggest decreased extension rates relative to late-stage core complex uplift.     

The biogeochemical sulfur cycle in the marine boundary layer over the Northeast Pacific Ocean

The major components of the marine boundary layer biogeochemical sulfur cycle were measured simultaneously onshore and off the coast of Washington State, U.S.A. during May 1987. Seawater dimethylsulfide (DMS) concentrations on the continental shelf were strongly influenced by coastal upwelling. Concentration further offshore were typical of summer values (2.2 nmol/L) at this latitude. Although seawater DMS concentrations were high on the biologically productive continental shelf (2–12 nmol/L), this region had no measurable effect on atmospheric DMS concentrations. Atmospheric DMS concentrations (0.1–12 nmol/m³), however, were extremely dependent upon wind speed and boundary layer height. Although there appeared to be an appreciable input of non-sea-salt sulfate to the marine boundary layer from the free troposphere, the local flux of DMS from the ocean to the atmosphere was sufficient to balance the remainder of the sulfur budget.     

Regional hydrogeological screening characteristics used for siting near-surface waste-disposal facilities in Oklahoma,U.S.A.

The Oklahoma Geological Survey has developed several maps and reports for preliminary screening of the state of Oklahoma to identify areas that are generally acceptable or unacceptable for disposal of a wide variety of waste materials. These maps and reports focus on the geologic and hydrogeologic parameters that must be evaluated in the screening process. One map (and report) shows the outcrop distribution of 35 thick shale or clay units that are generally suitable for use as host rocks for surface disposal of wastes. A second map shows the distribution of unconsolidated alluvial and terrace-deposit aquifers, and a third map shows the distribution and hydrologic character of bedrock aquifers and their recharge areas. These latter two maps show the areas in the state where special attention must be exercised in permitting storage or disposal of waste materials that could degrade the quality of groundwater. State regulatory agencies and industry are using these maps and reports in preliminary screening of the state to identify potential disposal sites. These maps in no way replace the need for site-specific investigations to prove (or disprove) the adequacy of a site to safely contain waste materials.     

Gravity profiles across the Cheyenne Belt, a precambrian crustal suture in southeastern Wyoming

Geologic discontinuities across the Cheyenne Belt of southeastern Wyoming have led to interpretations that this boundary is a major crustal suture separating the Archaean Wyoming Province to the north from accreted Proterozoic island arc terrains to the south. Gravity profiles across the Cheyenne Belt in three Precambrian-cored Laramide uplifts show a north to south decrease in gravity values of 50–100 mgal. These data indicate that the Proterozoic crust is more felsic (less dense) and/or thicker than Archaean crust. Seismic refraction data show thicker crust (48–54 km) in Colorado than in Wyoming (37–41 km). We model the gravity profiles in two ways: 1) thicker crust to the south and a south-dipping ramp in the Moho beneath and just south of the Cheyenne Belt; 2) thicker crust to the south combined with a mid-crustal density decrease of about 0.05 g/cm³. Differences in crustal thickness may have originated 1700 Ma ago because: 1) the gravity gradient is spatially related to the Cheyenne Belt which has been immobile since about 1650 Ma ago; 2) the N-S gradient is perpendicular to the trend of gravity gradients associated with local Laramide uplifs and sub-perpendicular to regional long-wavelength Laramide gradients and is therefore probably not a Laramide feature. Thus, gravity data support the interpretation that the Cheyenne Belt is a Proterozoic suture zone separating terrains of different crustal structure. The gravity “signature” of the Cheyenne Belt is different from “S”-shaped gravity anomalies associated with Proterozoic sutures of the Canadian Shield which suggests fundamental differences between continent-continent and island arc-continent collisional processes.