Epiphytic diatoms as flood indicators

The hydroecology of floodplain lakes is strongly regulated by flood events. The threat of climate warming and increasing human activities requires development of scientific methods to quantify changes in the frequency of short-lived flood events, because they remain difficult to identify using conventional paleolimnological and monitoring approaches. We developed an approach to detect floods in sediment records by comparing the abundance and composition of epiphytic diatom communities in flooded and non-flooded ponds of the Peace-Athabasca Delta (PAD), Canada, that grew on submerged macrophytes (Potamogeton zosteriformis, P. perfoliatus) and an artificial substrate (polypropylene sheets) during the open-water season of 2005. Analysis of similarity tests showed that epiphytic diatom community composition differs significantly between flooded and non-flooded ponds. After accounting for the “pond effect,” paired comparisons of the three substrates determined that variation in community composition between the artificial substrate and macrophytes was similar to that between the macrophyte taxa. Similarity percentage analysis identified diatom taxa that discriminate between flooded and non-flooded ponds. The relative abundance of ‘strong flood indicator taxa’ was used to construct an event-scale flood record spanning the past 180 years using analyses of sedimentary diatom assemblages from a closed-drainage pond (PAD 5). Results were verified by close agreement with an independent paleoflood record from a nearby flood-prone oxbow pond (PAD 54) and historical records. Comparison of epiphytic diatoms in flooded and non-flooded lakes in this study provides a promising approach to detect changes in flood frequency, and may have applications for reconstructing other pulse-type disturbances such as hurricanes and pollutant spills.     

Industrial Land Development and Manufacturing Deconcentration in Greater Jakarta

Abstract

Industrial land development has become a key feature of urbanization in Greater Jakarta, one of the largest metropolitan areas in Southeast Asia. Following Suharto's market-oriented policy measures in the late 1980s, private developers have dominated the land development projects in Greater Jakarta. The article investigates the extent to which these private industrial centers have effectively reduced the domination of Jakarta in shaping the entire metropolitan structure. The analysis indicates that major suburban industrial centers have captured most of the manufacturing employment that has dispersed from Jakarta. The industrial centers have now increasingly specialized and diversified. It is likely that a polycentric metropolitan structure will emerge in the future.     

Erodibility of soft freshwater sediments in Markermeer: the role of bioturbation by meiobenthic fauna

The Markermeer is a large and shallow man-made freshwater lake in the Netherlands, characterized by its high turbidity. As part of a study aiming to mitigate this high turbidity, we studied the water–bed exchange processes of the lake’s muddy bed. The upper centimeter’s–decimeter’s of the lake bed sediments mainly consists of soft anoxic mud. Recent measurements have proved the existence of a thin oxic layer on top of this soft anoxic mud. This oxic layer, which is much easier to be eroded than the anoxic mud, is believed to be related with Markermeer’s high-turbidity levels. Our hypothesis is that the thin oxic layer develops from the anoxic mud, enhanced by bioturbation. Actually, we will demonstrate that it is the bioturbated state of the bed that increases its erodability, and not the oxidation state of the sediments. In particular, we will refer to bioturbation caused by meiobenthic fauna. The objective of this study is therefore to determine the influence of the development of the thin oxic layer on the water–bed exchange processes, as well as to establish the role of bioturbation on those processes. This is done by quantifying the erosion rate as a function of bed shear stresses, and at different stages of the development of the oxic layer. Our experiments show that bioturbation increases the rate at which Markermeer sediments are eroded by almost an order of magnitude. The short-term fine sediment dynamics in Markermeer are found to be driven by the complex and highly dynamic interactions between physics, chemistry, and biology. Finally, the long-term fine sediment dynamics are driven by the erosion of the historical deposits in the lake’s bed, which is only possible after bioturbation, and which leads to an increase of the stock of sediments in the lake’s muddy bed.     

Coastal flood risks and seasonal tourism: analysing the effects of tourism dynamics on casualty calculations

Since coastal tourism is one of the fastest growing sectors of tourism industry, coastal areas have become increasingly vulnerable in the case of flooding. While in recent years a number of different methods have been put forward to map coastal flood risks, the implications of tourism dynamics for the assessment of human casualties has remained largely overlooked in these models. This chapter examines to what extent the ignorance of (residential) coastal tourism may bias the calculations of human casualties. To this end, a case study has been conducted on the Belgian coast. Both the dynamic nature of coastal tourism and the behaviour of residential tourists in storm surge scenarios are considered. The results of this study show that including tourism dynamics in flood risk management is justified and appropriate, depending on the tourist attractiveness of the flood-prone area and its temporal fluctuations.     

Trace metal assessment in soils in a small city and its rural surroundings,Pensacola, FL,USA

This study assesses the origin and pollution of trace metals in surface soils in a region with contrasting land uses (urban vs. rural). Principal component analysis (PCA) reveals that Cr and Ni are predominantly of geogenic origin. These two trace metals are also the only ones with statistically significant correlations with soil particle size and organic matter content. Copper, Pb and Zn, and possibly Hg, are of anthropogenic origin, but their concentrations rarely reach levels described as strongly polluted by pollution indexes. The concentrations of these anthropogenic trace metals are statistically not different in urban and rural areas, except for Pb that is higher in the urban area. This general lack of a difference between the two land uses indicates that the influence of this small urban area on trace metal concentrations in soils is minor. Lead and Zn have the most, but still a modest number, of strongly polluted sites, mainly in an industrial part of the city. GIS analysis shows that, based on the pollution load index (PLI), overall concentrations of trace metals also reach their highest levels in that industrial area. These observations indicate that the influence of industry on trace metal pollution in soil exceeds that of other urban activities in the region. Local background concentrations were found to be very different from general crustal background concentrations. This demonstrates the importance of the careful selection of a background type in studies like this.     

Sedimentary Deposits from the 17 July 2006 Western Java Tsunami,Indonesia: Use of Grain Size Analyses to Assess Tsunami Flow Depth,Speed, and Traction Carpet Characteristics

The 2006 western Java tsunami deposited a discontinuous sheet of sand up to 20 cm thick, flooded coastal southern Java to a depth of at least 8 m and inundated up to 1 km inland. In most places the primarily heavy mineral sand sheet is normally graded, and in some it contains complex internal stratigraphy. Structures within the sand sheet probably record the passage of up to two individual waves, a point noted in eyewitness accounts. We studied the 2006 tsunami deposits in detail along a flow parallel transect about 750 m long, 15 km east of Cilacap. The tsunami deposit first becomes discernable from the underlying sediment 70 m from the shoreline. From 75 to 300 m inland the deposit has been laid down in rice paddies, and maintains a thickness of 10–20 cm. Landward of 300 m the deposit thins dramatically, reaching 1 mm by 450 m inland. From 450 m to the edge of deposition (around 700 m inland) the deposit remains <1 mm thick. Deposition generally attended inundation—along the transect, the tsunami deposited sand to within about 40 m of the inundation limit. The thicker part of the deposit contains primarily sand indistinguishable from that found on the beach 3 weeks after the event, but after about 450 m (and roughly coinciding with the decrease in thickness) the tsunami sediment shifts to become more like the underlying paddy soil than the beach sand. Grain sizes within the deposit tend to fine upward and landward, although overall upward fining takes place in two discrete pulses, with an initial section of inverse grading followed by a section of normal grading. The two inversely graded sections are also density graded, with denser grains at the base, and less dense grains at the top. The two normally graded sections show no trends in density. The inversely graded sections show high density sediment to the base and become less dense upward and represents traction carpet flows at the base of the tsunami. These are suggestive of high shear rates in the flow. Because of the grain sorting in the traction carpet, the landward-fining trends usually seen in tsunami deposits are masked, although lateral changes of mean sediment grain size along the transect do show overall landward fining, with more variation as the deposit tapers off. The deposit is also thicker in the more seaward portions than would be produced by tsunamis lacking traction carpets.     

Rhizofiltration of a Heavy Metal (Lead) Containing Wastewater Using the Wetland Plant Carex pendula

Rhizofiltration is a subset technique of phytoremediation which refers to the approach of using plant biomass for removing contaminants, primarily toxic metals, from polluted water. The effective implementation of this in situ remediation technology requires experimental as well as conceptual insight of plant–water interactions that control the extraction of targeted metal from polluted water resources. Therefore, pot and simulation experiments are used in this study to investigate the rhizofiltration of a lead containing wastewater using plants of Carex pendula, a common wetland plant found in Europe. The metal contaminant extraction along with plant growth and water uptake rates from a wastewater having varying Pb concentration is studied experimentally for 2 wk. The temporal distribution of the metal concentration in the wastewater and the accumulated metal in different compartments of C. pendula at the end are analyzed using atomic absorption spectrometry. Parameters of the metal uptake kinetics are deduced experimentally for predicting the metal removal by root biomass. Further, mass balance equations coupled with the characterized metal uptake kinetics are used for simulating the metal partitioning from the wastewater to its accumulation in the plant biomass. The simulated metal content in wastewater and plant biomass is compared with the observed data showing a good agreement with the later. Results show that C. pendula accumulates considerable amounts of lead, particularly in root biomass, and can be considered for the cleanup of lead contaminated wastewaters in combination with proper biomass disposal alternatives. Also, the findings can be used for performing further non‐hydroponics experiment to mimic the real wetland conditions more closely.     

Provisional Elemental Values for IAEA‐Sewage Sludge by Instrumental Neutron Activation Analysis

The International Atomic Energy Agency (IAEA) organised a proficiency test (PT), IAEA‐CU‐2010‐02, for the determination of elements in sewage sludge. The PT sample was analysed by semi‐absolute standardless k₀‐instrumental neutron activation analysis (k₀‐INAA). Results for seven elements (As, Co, Cr, Fe, Hg, Se, Zn) were submitted to the IAEA by our laboratory. All of our results were scored ‘acceptable’ by the ‘result evaluation criteria’ adopted by the IAEA. The same analytical methodology produced quantitative results for twenty‐six additional elements. In total, thirty‐six elements were determined with uncertainty varying from 4 to 11%. This paper presents the provisional mass fractions of twenty‐six additional elements (Ag, Al, Br, Ca, Ce, Cl, Dy, Eu, Ga, Hf, I, K, La, Mg, Mn, Na, Rb, Sb, Sc, Sm, Ta, Tb, Th, V, U, W) not reported by the IAEA. The analytical methodology was discussed with important sources of spectral, nuclear and fission‐product interferences. It was shown that the important components of uncertainties were the k₀ factor, Q₀ factor, detector efficiency, mass and counting statistics. The methodology was validated by analysing the IAEA‐S7 reference material.     

The volcanic acidification of glacial Lake Caviahue,Province of Neuquen,Argentina

Lake Caviahue (northern Patagonia, Argentina) is a large glacial lake acidified by volcanic fluids from Copahue volcano. The lake and the feeding rivers were sampled annually from 1997 till early 2006, including the eruptive period of 2000. Lake Caviahue waters evolved over time, with the most concentrated waters in 2000 during the eruptive period, followed by gradual dilution that was interrupted by renewed acidification in 2003–2004. Inversion of the lake water data and application of a dynamic non-steady state model for the lake provides our best quantitative estimates for the variation in element fluxes over the 9-year period. The model flux results agree well with most of the measured fluxes. The Copahue hydrothermal system had gently declining element fluxes between 1997 and mid-1999, although the lake was still becoming more concentrated. About 2–3 months before the 2000 eruption, element fluxes increased strongly, but the hydrothermal fluxes almost shutoff directly after the main eruptive events. The fluxes of several elements recovered post-2001, with an increase in element fluxes in 2003–2004; the lake became more dilute between 2004 and 2006. The intrusion of new magma into the hydrothermal system just prior to the 2000 eruption led to enhanced water rock interaction, with higher concentrations of the rock forming elements in the fluids, and the hot spring flow rate increased as a result of the higher pressure in the reservoir. The fluids became saturated in alunite and jarosite, and they were already saturated with anhydrite. Precipitation of these minerals possibly led to a decreased permeability of the hydrothermal reservoir, leading to the strongly reduced element fluxes just after the eruption. In addition, K, Al and S were retained in the newly precipitated minerals as well, further diminishing their export. The acidification in 2003–2004 may have resulted from a new small intrusion of magma or resulted from seismic activity that created new permeability and fresh rock surfaces for water rock interaction. The volcano is a significant source of toxic trace elements such as F, As, B and Li as well as a nutrient (P) for the local watershed. Monitoring of the hydrothermal fluids in the river that drains Copahue, especially the S/Cl, Mg/Cl and Mg/K values as well as the magnitude of the element fluxes would provide the best information for eruption forecasting for this volcano.     

The role of iron and sulfur in the visual appearance of lake sediment varves

Easily discernible sediment varves (annual laminations) may be formed in temperate zone lakes, and reflect seasonal changes in the composition of the accumulating material derived from the lake and its catchment (minerogenic and organic material). The appearance of varves may also be influenced by chemical processes. We assessed the role of iron (Fe) and sulfur (S) in the appearance of varves in sediments from Lake Nylandssjön in northern Sweden. We surveyed Fe in the lake water and established whether there is internal transport of Fe within the sediment. We used a unique collection of seven stored freeze cores of varved sediment from the lake, collected from 1979 to 2004. This suite of cores made it possible to follow long-term changes in Fe and S in the sediment caused by processes that occur in the lake bottom when the sediment is ageing. We compared Fe and S concentrations using X-ray fluorescence spectroscopy (XRF) in specific years in the different cores. No diagenetic front was found in the sediment and the data do not suggest that there is substantial vertical transport of Fe and S in the sediment. We also modeled Fe and S based on thermodynamic, limnological, and sediment data from the lake. The model was limited to the five components H⁺, e^?, Fe³⁺, SO₄ ^2?, H₂CO₃ and included the formation of solid phases such as Fe(OH)₃ (amorphous), FeOOH (aged, microcrystalline), FeS and FeCO₃. Modeling showed that there are pe (redox) ranges within which either FeS or Fe(OH)₃/FeOOH is the only solid phase present and there are pe ranges within which the two solid phases co-exist, which supports the hypothesis that blackish and grey-brownish layers that occur in the varves were formed at the time of deposition. This creates new possibilities for deciphering high-temporal-resolution environmental information from varves.