Radiogenic lead mobility in the Shea Creek unconformity-related uranium deposit (Saskatchewan,Canada): migration pathways and Pb loss quantification

The average Pb/U ratio of the Shea Creek unconformity-type uranium deposit has been estimated at 0.071±0.015. The calculation was performed on a volume enclosing the orebody to take into account the possible radiogenic lead migration within the ore zone. Despite this precaution, this ratio is significantly lower than the expected ratio (0.211) assuming a main U deposition around 1315 Ma, as suggested by previous UPb isotopic dating. Although part of the radiogenic lead can be trapped as galena within the orebody, about 60% of Pb have migrated more than 700 m away from the orebody, preferentially along the unconformity. To cite this article: P. Kister et al., C. R. Geoscience 336 (2004).     

Tectonothermal chronology within a blueschist-eclogite complex, west-central Spitsbergen, Svalbard: Evidence from and Rb---Sr mineral ages

A high-pressure, relatively low-temperature metamorphic complex is exposed at Motalafjella, Spitsbergen. White mica concentrates from the complex record variably discordant age spectra in which apparent ages systematically increase throughout low-temperature portions of the analyses and define intermediate- and high-temperature plateaux. Phengitic concentrates record plateau ages of c. 470 Ma whereas paragonitic concentrates yield c. 460 Ma plateaux. These ages are interpreted to date diachronous cooling through different argon closure temperatures following the high-pressure metamorphism. The slight discordance displayed in low-temperature portions of the experiments is interpreted to reflect a partial rejuvenation of intracrystalline argon systems during an c. 400–425 Ma thermal overprint associated with late Caledonian tectonothermal activity. White mica concentrates and associated whole-rocks yield Rb---Sr mineral + whole-rock ages from 457 ± 11 Ma to 474 ± 11 Ma. These are interpreted to date post-metamorphic cooling through Sr blocking temperatures. Because similar ages are recorded by both K---Ar and Rb---Sr isotopic systems, relatively rapid post-metamorphic cooling is implied. This and relatively rapid depressurization during uplift indicate that the and Rb---Sr mineral ages likely closely date the peak metamorphism.The high pressure complex is unconformably overlain by variably cleaved, Upper Ordovician-Lower Silurian flysch which was deformed into regional recumbent folds prior to deposition of unconformably overlying Early Devonian molasse. Two penetratively cleaved slate samples display internally discordant whole-rock age spectra with ages increasing from c. 100 Ma to c. 470 Ma. The spectral discordance is interpreted to reflect the combined effects of: (1) a polymineralic character: (2) a detrital source similar in age to the Motalafjella complex; and (3) a partial, post-Paleozoic thermal rejuvenation of the detrital mica argon systems. No thermal overprint associated with Late Silurian cleavage formation appears to be recorded. This agrees with textural characteristics which suggest that the cleavage largely developed through pressure-solution assisted, grain-boundary sliding.     

Amorce de la Sédimentation Synorogénique dans les PyrénéesVarisques. Données Chronologiques; Implications Paléogéographiques

Conodont associations and recent macrofaunal discoveries, allow us to date the beginning of detrital deposits going with the Variscan uplift in the Pyrenean marine basins during the Lower Carboniferous. Thus, the establishing of synorogenic conditions seems to have progressed from the East to the West; there appears the picture of a kind of north-Pyrenean axis already individualized in the wide Cantabrico-Pyrenean foreland.     

U–Pb zircon (TIMS and SIMS) and Sm–Nd whole-rock geochronology of the Gour Oumelalen granulitic basement, Hoggar massif, Tuareg shield, Algeria

Two major granulitic units are recognized in the Gour Oumelalen area. One of the units is composed partially of Archean gneisses (Red Gneiss complex) with U–Pb zircon SIMS and TIMS ages of approximately 2.7 Ga. Although they were formed from 3.0- to 3.2-Ga-old precursors, as indicated by Nd model ages, we find no evidence of any older history (≈3.5 Ga) as suggested by previous Pb–Pb ages. The other formation (Gour Oumelalen supergroup) is a metasedimentary sequence at least partly of Paleoproterozoic age, as indicated by zircon dates of a metavolcanic rock at approximately 2.2 Ga. A later magmatic event is recorded at approximately 1.9 Ga in both units and related to coeval granulite-facies metamorphism that affected both units. Nd model ages at approximately 2.0 Ga suggest an accretion of juvenile crust formation at that time. The existence of T_DM Nd model ages intermediate between 2.5 and 2.9 Ga could result from the mixing of 3.2 and 2.0-Ga-old material or may reflect separate events.     

Biogeochemical and ecological functioning of the low-salinity water lenses in the region of the Rhone River freshwater influence,NW Mediterranean Sea

A quasi-synoptic survey of a eulerian small grid was carried out twice during mid-spring 2002 in the Gulf of Lions, NW Mediterranean Sea. Analysis of hydrological core parameters reveal for the first time, in the region of freshwater influence (ROFI) of the Rhone River, the presence of low-salinity water (LSW) lenses. The present work details the biogeochemical and ecological functioning of the two LSW lenses from a combined analysis of nutrients and organic matter content, taxonomic assemblages of phytoplankton, primary productivity measurements and nitrogen regeneration fluxes. During the first survey, the lens observed is only detached in part from the Rhone River plume and is considered as a juvenile lens. In contrast, the second lens is totally detached from the plume forming a confined 3D structure with a large vertical development and is considered as having a more advanced maturity. A second survey, 4 days later, provided the opportunity to propose a complete sequence of ecological functioning of the LSW lenses, from their formation to a late stage of maturity just before dispersion. Nitrate contents and dissolved organic matter remain in high concentrations during the juvenile stages while the little available phosphate is rapidly exhausted. In such, an unbalanced-nutrient environment picoplankton appear to out-compete bacterioplankton for phosphate and other resources such as ammonium. In turn, the dominance of such prokaryotic assemblages could have involved the rapid development of microzooplankton. The sudden increase in phosphate observed in a more advanced stage of lens maturity is attributed to intense P-regeneration driven by the large abundance of microzooplankton. This top-down control does not seem to enable the prokaryotic assemblages to bloom again but the high concentrations of phosphate and nitrate favour the development of larger phytoplankton. These autotrophic communities rapidly exhaust nutrients and then decline in the confined ecosystem of the LSW lens that subsequently evolves towards oligotrophic conditions. In the observed last stage, small-sized phytoplankton again dominates the microbial assemblages and the trophic regime is mainly based on regenerated production. The long lifetime of the LSW lens compared to that of the Rhone River plume enables a deep transformation of the initial characteristics of the Rhone River freshwaters both in terms of nutrients balance and microbial food webs, especially through trophic cascading effects. Hence, we show that the LSW lenses have the potential to transfer nutrients and organic matter offshore but the nature (inorganic vs. organic) of the dominant compound exported will depend on the maturity of the lens at the time of its dispersion.     

Petrography,Geochemistry and Physical Properties of a Continuous Extrusive Section from the Sarami Massif,Semail Ophiolite

As opposed to ocean crustal drilling that often yields a discontinuous core, ophiolites provide a unique opportunity to study continuous sections of oceanic basalts. In order to provide high frequency constraints on the construction of the upper oceanic crust, a continuous 280 m thick volcanic transect was sampled in the Semail ophiolite in Oman. The analyzed section is located in the Sarami Massif, in the central part of the ophiolite, and exposed along Wadi Shaffan. A multidisciplinary study was carried out after sampling in the field. Core measurements including porosity, grain density, compressional velocity, magnetic susceptibility and electrical resistivity for over 100 samples from this transect have been made. Geochemical analyses including major, trace and Rare Earth Elements were also performed on 23 selected samples from this transect. The Wadi Shaffan transect appears as composed of two main petrological and geochemical members providing the main lithostratigraphic signal. The boundary between the two sequences is marked by the presence of a massive flow unit equating to the most primitive lava and across which significant changes in mineralogy and texture are observed. The physical properties equally record significant changes. In all, the section is characterized by chemical compositions coherent with that of V1-Geotime volcanism and appears as built through two main sequences of volcanic activity. The magnetic susceptibility profile correlated to geochemical variations present the most detailed evolution allowing to individualize a succession of at least 4 volcanic phases. These phases are interpreted as magmatic cycles characterized by differentiation processes, allowing one to place high frequency constraints on the volcanic behavior of fast spreading ridges. Some of the physical properties also reflect this series of differentiation trends, as noticed in the past from downhole measurements recorded in the context of deep ocean drilling into the crust.     

Sediment Yield During Late Glacial and Holocene periods in the Lac Chambon Watershed,Massif Central,France

A sediment budget for the Late Glacial and Holocene periods was calculated for the Lac Chambon watershed which is located in a formerly glaciated temperate crystalline mountain area. It appears that over 15 500 years: (1) 69 per cent of eroded particles have been displaced by gravity processes and then stored within the watershed, compared to 31 per cent that have been displaced by running water and evacuated outward; (2) the mean mechanical erosion due to gravity processes on the slopes amounted to 16·1 ±6 m and only developed on a quarter of the watershed surface, whereas the mean mechanical erosion due to running water amounted 1·24 ± 0·37 m and involved the whole watershed surface. The mean sediment yields due to gravity processes on slopes were 2300 ± 1360, 1770 ± 960 and 380 ± 100 m³ km⁻³ a⁻¹, respectively, for basalts, and basic and acidic trachyandesites. Values of sediment yield due to running water were 49±15, 120±36 and 79±24 m³ km⁻² a⁻¹, respectively, during the Bôlling–Allerôd, the Younger Dryas and the Pre-Boreal–Boreal periods. They were 56±17 and 166±50 m³ km⁻² a⁻¹ during the Sub-Atlantic period before and after 1360 a BP , respectively. These values reflect variations in the natural environment and the impact of human-induced deforestation. © 1997 by John Wiley & Sons, Ltd.     

Analytic theory of Titan’s Schumann resonance: Constraints on ionospheric conductivity and buried water ocean

This study presents an approximate model for the atypical Schumann resonance in Titan’s atmosphere that accounts for the observations of electromagnetic waves and the measurements of atmospheric conductivity performed with the Huygens Atmospheric Structure and Permittivity, Wave and Altimetry (HASI–PWA) instrumentation during the descent of the Huygens Probe through Titan’s atmosphere in January 2005. After many years of thorough analyses of the collected data, several arguments enable us to claim that the Extremely Low Frequency (ELF) wave observed at around 36 Hz displays all the characteristics of the second harmonic of a Schumann resonance. On Earth, this phenomenon is well known to be triggered by lightning activity. Given the lack of evidence of any thunderstorm activity on Titan, we proposed in early works a model based on an alternative powering mechanism involving the electric current sheets induced in Titan’s ionosphere by the Saturn’s magnetospheric plasma flow. The present study is a further step in improving the initial model and corroborating our preliminary assessments. We first develop an analytic theory of the guided modes that appear to be the most suitable for sustaining Schumann resonances in Titan’s atmosphere. We then introduce the characteristics of the Huygens electric field measurements in the equations, in order to constrain the physical parameters of the resonating cavity. The latter is assumed to be made of different structures distributed between an upper boundary, presumably made of a succession of thin ionized layers of stratospheric aerosols spread up to 150 km and a lower quasi-perfect conductive surface hidden beneath the non-conductive ground. The inner reflecting boundary is proposed to be a buried water–ammonia ocean lying at a likely depth of 55–80 km below a dielectric icy crust. Such estimate is found to comply with models suggesting that the internal heat could be transferred upwards by thermal conduction of the crust, while convective processes cannot be ruled out.     

Variations de l’âge des sédiments calcaires et « Culm » carbonifère dans la chaîne varisque du Sud de la France : migration de l’orogenèse varisque

Résumé

Dans le Sud de la France et les Pyrénées espagnoles, les calcaires sous-jacents aux roches détritiques du Culm carbonifère ont fait l’objet d’une datation systématique par conodontes. Il en ressort que le dépôt de ces niveaux carbonates s’est poursuivi de plus en plus tardivement de l’Est vers l’Ouest : du Viséen inférieur (V3b) en Montagne Noire, au Namurien supérieur (G2) en Pays basque.

Les roches détritiques à caractère flyschoïde du Culm remanient, localement, des éléments de calcaire de plate-forme. La datation de ces éléments par foraminifères, algues, pseudo-algues et végétaux supérieurs montre qu’ils sont de plus en plus récents d’Est en Ouest : leur âge s’échelonne du Viséen 3bp-Namurien A en Montagne Noire, au Westphalien C (Kachirien) au Pays basque (Massif des Cinco-Villas).

Ces divers résultats montrent que les manifestations tectoniques, responsables des premiers épandages détritiques du Culm puis de la resédimentation des calcaires de plate-forme dans le bassin, ont commencé de plus en plus tardivement de la Montagne Noire au Pays basque.

Dans sa branche Sud, l’orogenèse varisque, si l’on s’en tient à la position actuelle de ses segments observables, a migré progressivement du Nord vers le Sud, en Montagne Noire et dans le Massif de Mouthoumet, puis vers l’Ouest, des Pyrénées centrales aux Pyrénées orientales.     

Weathering of a Quaternary glass-rich basalt in Bakrit,Middle Atlas Mountains,Morocco. Comparison with a glass-poor basalt

Abstract

We compared the disintegration processes and mineralogic and chemical evolution pathways of two Quaternary basalts at Bakrit and Ifrane, weathered in the same physiographic and hydrologic conditions, but differing in texture according to the quantity of glass present. At Bakrit, quite abundant glass favoured the formation of a microfissure network throughout the rock and its disintegration without any distinct weathering front. As a result, basaltic sand with polymineral grains and a clayey-silty matrix were produced. At Ifrane, weathering of a glass-poor basalt produced only a clayey-silty saprolite. In glass-rich basalts, secondary minerals formed in microfissures and were 2/1 clay-mineral rich. In glass-poor basalts, secondary minerals formed mainly within primary minerals and were 1/1 clay-mineral rich. Because glass could be easily dissolved, it protected the minerals of close chemical composition, especially the plagioclases. The order of basalt-mineral weathering (olivine, labrador, augite, Fe-Ti oxides) was modified when glass was abundant (glass, olivine, augite, labrador, Fe-Ti oxides). © Elsevier, Paris