Anatomy of Piton de la Fournaise volcano (La Réunion, Indian Ocean)

The aim of this work is to propose a general model of Piton de la Fournaise volcano using information from geological and geophysical studies. Firstly, we make a graphical compilation of all available geophysical information along a W–E profile. Secondly, we construct a geological section that integrates both the geophysical information and the geological information. The lithosphere beneath Piton de la Fournaise is not significantly flexed, and the crust is underlain by an underplating body, which might represent the deep magma reservoir for La Réunion volcanism. Piton de la Fournaise is a relatively thin volcano lying on a huge volcanic construction attributed mostly to Les Alizés volcano. Indeed, if the differentiated rocks observed at the bottom of the Rivière des Remparts are the top of Les Alizés volcano, the interface with Piton de La Fournaise may be located at about sea level beneath the summit area. The endogenous constructions (intrusive complexes) related to Les Alizés and Piton de la Fournaise volcanoes represent a large volume. The huge intrusive complex of Les Alizés volcano probably rests on the top of the oceanic crust and appears to have a buttressing effect for the present eastern volcano-tectonic activity of Piton de la Fournaise. The early Piton de la Fournaise edifice was built around a focus located beneath the Plaine des Sables area. The center subsequently moved 5–6?km eastward to its current location. The dense, high-velocity body beneath the Plaines des Sables and the western part of the Enclos probably corresponds to the hypovolcanic intrusive complex that developed before the volcanic center shifted to its present-day position. Magma reservoirs may have existed, and may still exist, as illustrated by the March 1998 crisis, at the mechanical and density interface between the oceanic crust and the Les Alizés edifice. Strong evidence also exists for the presence of a shallower magma reservoir located near sea level beneath the summit. The March 1998 pre-eruptive seismic pattern (location and upward migration) seems to be evidence for a transfer of magma between the two reservoirs. The dominant structural feature of the central zone is a collapse structure beneath the summit craters, above the inferred magma reservoir near sea level. The collapsed column constitutes a major mechanical heterogeneity and concentrates most of the seismic, intrusive, and hydrothermal activity because of its higher permeability and weaker mechanical strength.     

Chad Basin: Paleoenvironments of the Sahara since the Late Miocene

Since the mid 1990s, the Mission paléoanthropologique francotchadienne (MPFT) conducts yearly paleontological field investigations of the Miocene-Pliocene of the Chad Basin. This article synthesizes some of the results of the MPFT, with focus on the Chad Basin development during the Neogene. We propose an overview of the depositional paleoenvironments of this part of Africa at different scales of time and space, based on a multidisciplinary approach (sedimentary geology, geomorphology, geophysic, numerical simulations and geochronology). The Miocene-Pliocene paleoenvironments are examined through the sedimentary archives of the early hominids levels and the Holocene Lake Mega-Chad episode illustrates the last major paleoenvironmental change in this area. The sedimentary record of the Chad Basin since the Late Miocene can be schematized as the result of recurrent interactions from lake to desert environments.     

Modeling of cadmium speciation and dynamics in the Seine estuary (France)

A complexation model (MOCO) was used to describe cadmium (Cd) speciation during estuarine transit in the Seine estuary. This model was developed from field data. Laboratory experiments based on the use of¹⁰⁹Cd enabled checking of certain model simplifications and hypotheses and evaluation of parameters which could not be measured directly. MOCO was coupled with a 3D multivariable hydrosedimentary model (SAM3D) to simulate Cd dynamics in the estuary. These results were compared with measurements (dissolved and particulate Cd) obtained during cruises representative of various hydrodynamic conditions. The purpose of this article is to present the modeling approach used, and its expected applications and limits.     

A model of present-day tectonic plate motions from 12 years of DORIS measurements

In the frame of the International DORIS Service (IDS), the Laboratoire d’Etudes en Géophysique et Océanographie Spatiales (LEGOS)/Collecte Localisation Satellites (CLS) Analysis Center (LCA) processes DORIS measurements from the SPOT, TOPEX/Poseidon and Envisat satellites and provides weekly station coordinates of the whole network to the IDS. Based on DORIS measurements, the horizontal and vertical velocities of 57 DORIS sites are computed. The 3D positions and velocities of the stations with linear motion are estimated simultaneously from the 12-year (1993–2004) combined normal equation matrix. We include 35 DORIS sites assumed to be located in the stable zones of 9 tectonic plates. For the motion of these plates, we propose a model (LCAVEL-1) of angular velocities in the ITRF2000 reference frame. Based on external comparison with the most recent global plate models (PB2002, REVEL, GSRM-1 and APKIM2000) and on internal analysis, we estimate an average velocity error of the DORIS solution of less than 3 mm/year. The LCAVEL-1 model presents new insights of the Somalia/Nubia pair of plates, as the DORIS technique has the advantage of having a few stations located on those two plates. We also computed (and provide in this article) the horizontal motion of the sites located close to plate boundaries or in the deformation zones defined in contemporary models. These computations could be used in further analysis for these particular regions of the Earth not moving as rigid plates.     

High-precision VLBI astrometric observations of radio-emitting stars for detection of extra-solar planets

The displacement of a radio-emitting star around the barycenter of a possible planetary system can be measured by astrometric very long baseline interferometry (VLBI) observations. We have observed the radio-emitting star ² CrB at 8 epochs over 5 years by VLBI and fitted its 5 astrometric parameters to the observed coordinates. The post-fit coordinate residuals have an rms scatter of 0.22 milliarcseconds and show no systematic behavior. We use this result to set a limit on the presence of planets around ² CrB and conclude that our present VLBI astrometric precision corresponds to the threshold to detect a Jupiter-like planet around this star. We also discuss the astrometric monitoring program of 11 radio-emitting stars that we are conducting for the Hipparcos space mission and its possible contribution to a long-term planet search program.Paper presented at the Conference onPlanetary Systems: Formation, Evolution, and Detection held 7–10 December, 1992 at CalTech, Pasadena, California, U.S.A.     

Surface modes in the infrared spectrum of hydrous minerals: the OH stretching modes of bayerite

The theoretical infrared (IR) and Raman spectra of bayerite (β-Al(OH)₃) are computed in the density functional theory framework, using the linear response theory. The results are consistent with the occurrence of six non-equivalent OH groups in a bayerite structure with space group P2₁/n. Similar to gibbsite, the transmission powder IR spectrum of bayerite in the region of the OH stretching bands is found to depend on the shape of particles. In particular, the broadening of the strong band observed at about 3,460 cm⁻¹ in the spectrum of Al hydroxides is related to the electrostatic charges occurring at the surface of the polarized dielectric particles. The experimental correlation observed between the shape of this band and morphological parameters has therefore a physical, instead of chemical, origin.