Tripartite climate reversal in Central Europe 5600-5300 years ago

The history of variations in water level of Lake Constance, as reconstructed from sediment and pollen analysis of a sediment sequence from the archaeological site of Arbon-Bleiche 3, shows an abrupt rise in lake level dendrochronologically dated to 5375 yr ago (5320 yr relative to AD 1950). This event, paralleled by the destruction of the Neolithic village by fire, provoked the abandonment of this prehistoric lake-shore location established in the former shallow bay of Arbon-Bleiche, and was the last of a series of three episodes of successively higher lake level, the first occurring at 5600-5500 cal yr B.P. The dendrochronologically dated rise event was synchronous with an abrupt increase in atmospheric ¹⁴C. This supports the hypothesis of an abrupt climate change forced by varying solar activity. Moreover, the three successive episodes of higher lake level between 5600 and 5300 cal yr B.P. at Arbon-Bleiche 3 coincided with climatic cooling and/or changes in moisture conditions in various regions of both hemispheres. This period corresponds to the mid-Holocene climate transition (onset of the Neoglaciation) and suggests inter-hemispheric linkages for the climate variations recorded at Arbon-Bleiche 3. This mid-Holocene climate reversal may have resulted from complex interactions between changes in orbital forcing, ocean circulation and solar activity. Finally, despite different seasonal hydrological regimes, the similarities between lake-level records from Lake Constance and from Jurassian lakes over the mid-Holocene period point to time scale as a crucial factor in considering the possible impact of climate change on environments.     

Elucidation of different forms of organic carbon in marine sediments from the Atlantic coast of Spain using thermal analysis coupled to isotope ratio and quadrupole mass spectrometry

Analysis of river, estuary and marine sediments from the Atlantic coast of Spain using thermogravimetry–differential scanning calorimetry–quadrupole mass spectrometry–isotope ratio mass spectrometry (TG–DSC–QMS–IRMS) was used to (a) distinguish bulk chemical hosts for C within a sediment and humic acid fraction, (b) track C pools with differing natural C isotope ratios and (c) observe variation with distance from the coast. This is the first application of such a novel method to the characterisation of organic matter from marine sediments and their corresponding humic acid fractions. Using thermal analysis, a labile, a recalcitrant and a refractory carbon pool can be distinguished. Extracted humic fractions are mainly of recalcitrant nature. The proportion of refractory carbon is greatest in marine sediments and humic acid fractions. Quadrupole mass spectrometry confirmed that the greatest proportion of m/z 44 (CO₂) and m/z 18 (H₂O) were detected at temperatures associated with recalcitrant carbon (510–540 °C). Isotope analysis detected progressive enrichment in δ¹³C for the sediment samples with an increase in marine influence. Isotopic heterogeneity in the refractory organic matter in marine sediments could be due to products of anthropogenic origin or natural combustion products. Isotope homogeneity of humic acids confirms the presence of terrigenous C in marine sediments, allowing the terrestrial input to be characterised.     

Phytoliths as indicators of pedogenesis and paleoenvironmental changes in the Brazilian cerrado

This paper presents the preliminary results of phytolith analyses of a peat located in the cerrado of the Uberaba municipality, State of Minas Gerais, Brazil. The phytolith soil sequence is discussed by comparison with phytolith assemblages extracted from dominant plants (Cyperaceae and Poaceae). Increasing mean age of phytolith assemblages with depth is assumed. Poaceae Cuneiform bulliform cell, Parallelepiped bulliform cell and Elongate smooth long cell types dominate up to 80 cm, rapidly drop to 42% at 80 cm and regularly decrease from 42% to 2% upwards. Cyperaceae Rondel concave type shows the inverse trend, being dominant in the upper part of the profile. This pattern can be assigned to increasing selective dissolution of the Cyperaceae phytolith type with depth, or/and to a decrease of water stress suffered by the grasses, leading to a decrease of bulliform cell silicification. Soil processes and paleo-environmental changes hypotheses are discussed.     

Comparative study of sampling methods and in situ and laboratory analysis for shallow-water submarine hydrothermal systems

A primary aim for sampling of submarine hydrothermal vents is to minimize inclusion of ambient seawater. Here, we compare the results of three different sampling methods (air displacement, two-valve bottle, and syringes) for shallow submarine systems. Mixing of hydrothermal fluid with seawater is unavoidable; however, calculations based on linear mixing models allow estimation of the hydrothermal fluid end-member composition. The results show that sampling with a two-valve bottle and syringes are the best options because they allow collection of samples with a large proportion of hydrothermal fluid. Additionally, we compare the results of in situ and laboratory analyses of the fluid samples, and demonstrate that determination of chemical composition in situ is the best option for some components, as re-equilibration affects some component concentrations (i.e. bicarbonate). Conversely, silica determination in situ usually underestimates the concentration in the fluid, as it does not account for polymeric silica. Other components can be measured either in the field or in the laboratory.     

The bimodal rift-related Juscelândia volcanosedimentary sequence in central Brazil: Mesoproterozoic extension and Neoproterozoic metamorphism

The Barro Alto Complex and Juscelândia volcanosedimentary sequence are exposed in the central part of the Neoproterozoic Brasília belt of central Brazil. The former is a large (approximately 150 km long), boomerang-shaped, mafic-ultramafic, layered complex formed by two different intrusions metamorphosed under granulite facies. These rocks are tectonically overlain by rocks of the Juscelândia volcanosedimentary sequence, represented mainly by biotite-gneiss and amphibolite, or amphibolite facies metamorphic equivalents of rhyolite and basalt, respectively. New SIMS U–Pb zircon data and Sm–Nd isochron data presented herein help clarify the igneous and metamorphic evolution of the Juscelândia volcanosedimentary sequence, as well as its relationship with the Barro Alto Complex. Zircon grains from two biotite gneisses were analyzed by SIMS (SHRIMP) and indicate Mesoproterozoic dates, approximately 1.28 Ga, interpreted as the time of bimodal volcanism in a tectonic setting transitional between a continental rift and an ocean basin. Metamorphism is constrained by Sm–Nd garnet-whole-rock isochrons for garnet amphibolite and pelitic schists of the Juscelândia sequence, as well as for clinopyroxene-garnet amphibolite and garnet granulite of the Barro Alto Complex, which give ages between 0.74 and 0.76 Ga, in agreement with SIMS dates for metamorphic zircon rims. These new data are significant, because they establish that a single metamorphic event affected both the Barro Alto Complex and the Juscelândia sequence. Based on these new data, we present a modified tectonic model for the Brasília belt.     

An Albian–Cenomanian unconformity in the northern Andes: Evidence and tectonic significance

The Villeta Group of Colombia and equivalent stratigraphic units of Venezuela and Ecuador comprise marine sequences ranging from Albian to Santonian in age. Deposition of the Villeta Group was presumed to take place entirely in quiet tectonic conditions in a passive margin setting that occupied NW South America. From a large database of 2D/3D seismic, well, surface geology, and biostratigraphic data, we present evidence for intra-Villeta (mostly late Albian–Cenomanian) deformation in parts of the Upper Magdalena Valley and Eastern Cordillera of Colombia, controlled by transpressional fault reactivation, produced by transpressional fault reactivation and thrusting that resulted in an angular unconformity. This event has been largely unnoticed in the literature, but previously scattered evidence supports our observations, suggesting regionally extensive tectonism. Published fission-track age determinations and other geologic evidence from Colombia and Venezuela suggest significant uplifts around 80–100 m.y., which may reflect changes in the subduction regime, with compressional deformation in certain regions and extensional deformation in others. A late Albian onset of compressional deformation along the Colombian and Peruvian segments of the Andes may be related to the opening of the South Atlantic Ocean at equatorial latitudes. Identification of tectonic activity with development of an unconformity in intra-Villeta times provides new insights into understanding the evolution of the Upper Magdalena Valley and adjacent areas of Colombia and western Venezuela and creates new possibilities for hydrocarbon exploration, with additional trapping phases, better reservoir preservation by early migration and secondary porosity, and ultimately facies changes with stratigraphic potential.     

Effects of magnetic interactions in anisotropy of magnetic susceptibility: Models, experiments and implications for igneous rock fabrics quantification

Besides granites of the ilmenite series, in which the anisotropy of magnetic susceptibility (AMS) is mainly controlled by paramagnetic minerals, the AMS of igneous rocks is commonly interpreted as the result of the shape-preferred orientation of unequant ferromagnetic grains. In a few instances, the anisotropy due to the distribution of ferromagnetic grains, irrespective of their shape, has also been proposed as an important AMS source. Former analytical models that consider infinite geometry of identical and uniformly magnetized and coaxial particles confirm that shape fabric may be overcome by dipolar contributions if neighboring grains are close enough to each other to magnetically interact. On these bases we present and experimentally validate a two-grain macroscopic numerical model in which each grain carries its own magnetic anisotropy, volume, orientation and location in space. Compared with analytical predictions and available experiments, our results allow to list and quantify the factors that affect the effects of magnetic interactions. In particular, we discuss the effects of (i) the infinite geometry used in the analytical models, (ii) the intrinsic shape anisotropy of the grains, (iii) the relative orientation in space of the grains, and (iv) the spatial distribution of grains with a particular focus on the inter-grain distance distribution. Using documented case studies, these findings are summarized and discussed in the framework of the generalized total AMS tensor recently introduced by Cañon-Tapia (Cañon-Tapia, E., 2001. Factors affecting the relative importance of shape and distribution anisotropy in rocks: theory and experiments. Tectonophysics, 340, 117–131.). The most important result of our work is that analytical models far overestimate the role of magnetic interaction in rock fabric quantification. Considering natural rocks as an assemblage of interacting and non-interacting grains, and that the effects of interaction are reduced by (i) the finite geometry of the interacting clusters, (ii) the relative orientation between interacting grains, (iii) their heterogeneity in orientation, shape and bulk susceptibility, and (iv) their inter-distance distribution, we reconcile analytical models and experiments with real case studies that minimize the role of magnetic interaction onto the measured AMS. Limitations of our results are discussed and guidelines are provided for the use of AMS in geological interpretation of igneous rock fabrics where magnetic interactions are likely to occur.     

Modèles géostatistiques de concentrations ou de débits le long des cours d'eau

Estimating concentrations or flow rates along a stream network requires specific models. Two classes of models, recently proposed in the literature, are generalized, to the intrinsic case in particular. We present a global construction by ‘streams’, i.e. on the whole set of paths between sources and outlet. Combining stationary or intrinsic one-dimensional random functions leads to stationary or intrinsic models on segments, with discontinuities at the forks. A construction from outlet to sources, leads to stationary or intrinsic models on each stream, without any discontinuity at the forks. The linear variogram is found as a particular case. The extension to the linear model of coregionalization is immediate, allowing a multivariate modelling of concentrations. To cite this article: C. de Fouquet, C. Bernard-Michel, C. R. Geoscience 338 (2006).     

Zircon geochronology and Sm–Nd isotopic study: Further constraints for the Archean and Paleoproterozoic geodynamical evolution of the southeastern Guiana Shield, north of Amazonian Craton, Brazil

The eastern part of the Guiana Shield, northern Amazonian Craton, in South America, represents a large orogenic belt developed during the Transamazonian orogenic cycle (2.26–1.95 Ga), which consists of extensive areas of Paleoproterozoic crust and two major Archean terranes: the Imataca Block, in Venezuela, and the here defined Amapá Block, in the north of Brazil.

Pb-evaporation on zircon and Sm–Nd on whole rock dating were provided on magmatic and metamorphic units from southwestern Amapá Block, in the Jari Domain, defining its long-lived evolution, marked by several stages of crustal accretion and crustal reworking. Magmatic activity occurred mainly at the Meso-Neoarchean transition (2.80–2.79 Ga) and during the Neoarchean (2.66–2.60 Ga). The main period of crust formation occurred during a protracted episode at the end of Paleoarchean and along the whole Mesoarchean (3.26–2.83 Ga). Conversely, crustal reworking processes have dominated in Neoarchean times. During the Transamazonian orogenic cycle, the main geodynamic processes were related to reworking of older Archean crust, with minor juvenile accretion at about 2.3 Ga, during an early orogenic phase. Transamazonian magmatism consisted of syn- to late-orogenic granitic pulses, which were dated at 2.22 Ga, 2.18 Ga and 2.05–2.03 Ga. Most of the ε_Nd values and T_DM model ages (2.52–2.45 Ga) indicate an origin of the Paleoproterozoic granites by mixing of juvenile Paleoproterozoic magmas with Archean components.

The Archean Amapá Block is limited in at southwest by the Carecuru Domain, a granitoid-greenstone terrane that had a geodynamic evolution mainly during the Paleoproterozoic, related to the Transamazonian orogenic cycle. In this latter domain, a widespread calc-alkaline magmatism occurred at 2.19–2.18 Ga and at 2.15–2.14 Ga, and granitic magmatism was dated at 2.10 Ga. Crustal accretion was recognized at about 2.28 Ga, in agreement with the predominantly Rhyacian crust-forming pattern of the eastern Guiana Shield. Nevertheless, T_DM model ages (2.50–2.38 Ga), preferentially interpreted as mixed ages, and ε_Nd < 0, point to some participation of Archean components in the source of the Paleoproterozoic rocks. In addition, the Carecuru Domain contains an oval-shaped Archean granulitic nucleus, named Paru Domain. In this domain, Neoarchean magmatism at about 2.60 Ga was produced by reworking of Mesoarchean crust, as registered in the Amapá Block. Crustal accretion events and calc-alkaline magmatism are recognized at 2.32 Ga and at 2.15 Ga, respectively, as well as charnockitic magmatism at 2.07 Ga.

The lithological association and the available isotopic data registered in the Carecuru Domain suggests a geodynamic evolution model based on the development of a magmatic arc system during the Transamazonian orogenic cycle, which was accreted to the southwestern border of the Archean Amapá Block.