The amino acid composition of the Sutter's Mill CM2 carbonaceous chondrite

We determined the abundances and enantiomeric compositions of amino acids in Sutter's Mill fragment #2 (designated SM2) recovered prior to heavy rains that fell April 25–26, 2012, and two other meteorite fragments, SM12 and SM51, that were recovered postrain. We also determined the abundance, enantiomeric, and isotopic compositions of amino acids in soil from the recovery site of fragment SM51. The three meteorite stones experienced terrestrial amino acid contamination, as evidenced by the low d/l ratios of several proteinogenic amino acids. The d/l ratios were higher in SM2 than in SM12 and SM51, consistent with rain introducing additional l‐ amino acid contaminants to SM12 and SM51. Higher percentages of glycine, β‐alanine, and γ‐amino‐n‐butyric acid were observed in free form in SM2 and SM51 compared with the soil, suggesting that these free amino acids may be indigenous. Trace levels of d +l‐ β‐aminoisobutyric acid (β‐AIB) observed in all three meteorites are not easily explained as terrestrial contamination, as β‐AIB is rare on Earth and was not detected in the soil. Bulk carbon and nitrogen and isotopic ratios of the SM samples and the soil also indicate terrestrial contamination, as does compound‐specific isotopic analysis of the amino acids in the soil. The amino acid abundances in SM2, the most pristine SM meteorite analyzed here, are approximately 20‐fold lower than in the Murchison CM2 carbonaceous chondrite. This may be due to thermal metamorphism in the Sutter's Mill parent body at temperatures greater than observed for other aqueously altered CM2 meteorites.     

An investigation of sand–dust storm events and land surface characteristics in China using NOAA NDVI data

Observations from 560 weather stations in China show that sand–dust storms occur most frequently in April in north China. The region consists of Sub-dry Mid Temperate, Dry Mid Temperate, Sub-dry South Temperate and Dry South Temperate Zones and much of the land surface is desert or semi-desert: it is relatively dry with minimal rainfall and a high annual mean temperature. In most regions of China, the annual mean frequency of sand–dust events decreased sharply between 1980 and 1997 and then increased from 1997 to 2000. Statistical analyses demonstrate that the frequency of sand–dust storms correlates highly with wind speed, which in turn is strongly related to land surface features; on the other hand, a significant correlation between storm events and other atmospheric quantities such as precipitation and temperature was not observed. Accordingly, land surface cover characteristics (vegetation, snowfall and soil texture) may play a significant role in determining the occurrence of sand–dust storms in China. Analysis of Normalized Difference Vegetation Index derived from National Oceanic and Atmospheric Administration and Empirical Orthogonal Function show that since 1995 surface vegetation cover in large areas of Northern China has significantly deteriorated. Moreover, a high correlation is shown to exist among the annual occurrence of sand–dust storms, surface vegetation cover and snowfall. This suggests that the deterioration of surface vegetation cover may strongly influence the occurrence of sand–dust storms in China. Soils with coarse and medium textures are found to be more associated with sand–dust storms than other soils.     

Assessment of the interstellar processes leading to deuterium enrichment in meteoritic organics

Abstract— The presence of isotopic anomalies is the most unequivocal demonstration that meteoritic material contains circumstellar or interstellar components. In the case of organic compounds in meteorites and interplanetary dust particles (IDPs), the most useful isotopic tracer has been deuterium (D). We discuss four processes that are expected to lead to D enrichment in interstellar materials and describe how their unique characteristics can be used to assess their relative importance for the organics in meteorites. These enrichment processes are low‐temperature gas phase ion‐molecule reactions, low‐temperature gas‐grain reactions, gas phase unimolecular photodissociation, and ultraviolet photolysis in D‐enriched ice mantles. Each of these processes is expected to be associated with distinct regiochemical signatures (D placement on the product molecules, correlation with specific chemical functionalities, etc.), especially in the molecular population of polycyclic aromatic hydrocarbons (PAHs). We describe these differences and discuss how they may be used to delineate the various interstellar processes that may have contributed to meteoritic D enrichments. We also briefly discuss how these processes may affect the isotopic distributions in C, O, and N in the same compounds.     

Geochemical characteristics of crustal anatexis during the formation of migmatite at the Southern Sierra Nevada,California

We provide data on the geochemical and isotopic consequences of nonmodal partial melting of a thick Jurassic pelite unit at mid-crustal levels that produced a migmatite complex in conjunction with the intrusion of part of the southern Sierra Nevada batholith at ca. 100 Ma. Field relations suggest that this pelitic migmatite formed and then abruptly solidified prior to substantial mobilization and escape of its melt products. Hence, this area yields insights into potential mid-crustal level contributions of crustal components into Cordilleran-type batholiths. Major and trace-element analyses in addition to field and petrographic data demonstrate that leucosomes are products of partial melting of the pelitic protolith host. Compared with the metapelites, leucosomes have higher Sr and lower Sm concentrations and lower Rb/Sr ratios. The initial ⁸⁷Sr/⁸⁶Sr ratios of leucosomes range from 0.7124 to 0.7247, similar to those of the metapelite protoliths (0.7125–0.7221). However, the leucosomes have a much wider range of initial ε_Nd values, which range from −6.0 to −11.0, as compared to −8.7 to −11.3 for the metapelites. Sr and Nd isotopic compositions of the leucosomes, migmatites, and metapelites suggest disequilibrium partial melting of the metapelite protolith. Based on their Sr, Nd, and other trace-element characteristics, two groups of leucosomes have been identified. Group A leucosomes have relatively high Rb, Pb, Ba, and K₂O contents, Rb/Sr ratios (0.15<Rb/Sr<1.0), and initial ε_Nd values. Group B leucosomes have relatively low Rb, Pb, Ba, and K₂O contents, Rb/Sr ratios (<0.15), and initial ε_Nd values. The low Rb concentrations and Rb/Sr ratios of the group B leucosomes together suggest that partial melting was dominated by water-saturated or H₂O-fluxed melting of quartz + feldspar assemblage with minor involvement of muscovite. Breakdown of quartz and plagioclase with minor contributions from muscovite resulted in low Rb/Sr ratios characterizing both group A and group B leucosomes. In contrast, group A leucosomes have greater contributions from K-feldspar, which is suggested by: (1) their relatively high K concentrations, (2) positive or slightly negative Eu anomalies, and (3) correlation of their Pb and Ba concentrations with K₂O contents. It is also shown that accessory minerals have played a critical role in regulating the partitioning of key trace elements such as Sm, Nd, Nb, and V between melt products and residues during migmatization. The various degrees of parent/daughter fractionations in the Rb–Sr and Sm–Nd isotopic systems as a consequence of nonmodal crustal anatexis would render melt products with distinct isotopic signatures, which could profoundly influence the products of subsequent mixing events. This is not only important for geochemical patterns of intracrustal differentiation, but also a potentially important process in generating crustal-scale as well as individual pluton-scale isotopic heterogeneities.     

Hydrogeological and Gasgeochemical Earthquake Precursors – A Review for Application

Even if earthquake precursory signals can be identified, how can they be useful? This paper investigates relationships among the attributes of 229 proposed earthquake related gasgeochemical and hydrogeological precursory signals, and applies these results to improve future earthquake prediction strategies. Sub-groups of these reported signals and relationships between sub-groups are established using parameters, including earthquake magnitude, signal duration, precursory time, and epicentral distance to the monitoring site (original studies are used wherever possible to improve data quality). A strong correlation (r=0.86) between signal duration and precursory time was identified. This suggests a relationship between the investigated precursory signals and tectonic processes related to the referenced earthquakes. Moreover, these signals are categorized into four groups, reflecting differences in monitoring station densities, measurement methods and physical processes related to signal occurrence: (a) radon exhalation from the earth’s crust, (b) exhalation of other gases (helium, argon and others), (c) temporal variation in water level or discharge of springs and (d) temporal variation in temperature and dissolved ions in the water of the monitoring sites. In addition, boundary functions are used to separate signal group subsets. Finally, it is shown how these boundary functions can be used in the context of an earthquake prediction strategy by identifying potential minimum magnitudes and maximum epicentral distances from the monitoring site.     

Tidal currents,energy flux and bottom boundary layer thickness in the Clyde Sea and North Channel of the Irish Sea

A high-resolution three-dimensional model of the Clyde Sea and the adjacent North Channel of the Irish Sea is used to compute the major diurnal and semidiurnal tides in the region, the associated energy fluxes and thickness of the bottom boundary layer. Initially, the accuracy of the model is assessed by performing a detailed comparison of computed tidal elevations and currents in the region, against an extensive database that exists for the M₂, S₂, N₂, K₁ and O₁ tides. Subsequently, the model is used to compute the tidal energy flux vectors in the region. These show that the major energy flux is confined to the North Channel region, with little energy flux into the Clyde Sea. Comparison with the observed energy flux in the North Channel shows that its across-channel distribution and its magnitude are particularly sensitive to the phase difference between elevation and current. Consequently, small changes in the computed values of these parameters due to slight changes of the order of the uncertainty in the open-boundary values to the model, can significantly influence the computed energy flux. The thickness of the bottom boundary layer in the region is computed using a number of formulations. Depending upon the definition adopted, the empirical coefficient C used to determine its thickness varies over the range 0.1 to 0.3, in good agreement with values found in the literature. In the North Channel, the boundary layer thickness occupies the whole water depth, and hence tidal turbulence produced at the sea bed keeps the region well mixed. In the Clyde Sea, the boundary layer thickness is a small fraction of the depth, and hence the region stratifies.Responsible Editor: Phil Dyke