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671.
The separation between the reference surfaces for orthometric heights and normal heights—the geoid and the quasigeoid—is typically in the order of a few decimeters but can reach nearly 3 m in extreme cases. The knowledge of the geoid–quasigeoid separation with centimeter accuracy or better, is essential for the realization of national and international height reference frames, and for precision height determination in geodetic engineering. The largest contribution to the geoid–quasigeoid separation is due to the distribution of topographic masses. We develop a compact formulation for the rigorous treatment of topographic masses and apply it to determine the geoid–quasigeoid separation for two test areas in the Alps with very rough topography, using a very fine grid resolution of 100 m. The magnitude of the geoid–quasigeoid separation and its accuracy, its slopes, roughness, and correlation with height are analyzed. Results show that rigorous treatment of topographic masses leads to a rather small geoid–quasigeoid separation—only 30 cm at the highest summit—while results based on approximations are often larger by several decimeters. The accuracy of the topographic contribution to the geoid–quasigeoid separation is estimated to be 2–3 cm for areas with extreme topography. Analysis of roughness of the geoid–quasigeoid separation shows that a resolution of the modeling grid of 200 m or less is required to achieve these accuracies. Gravity and the vertical gravity gradient inside of topographic masses and the mean gravity along the plumbline are modeled which are important intermediate quantities for the determination of the geoid–quasigeoid separation. We conclude that a consistent determination of the geoid and quasigeoid height reference surfaces within an accuracy of few centimeters is feasible even for areas with extreme topography, and that the concepts of orthometric height and normal height can be consistently realized and used within this level of accuracy.  相似文献   
672.
673.
The formation of sub-seafloor gas hydrates in marine environments can be described as a coupled transport and thermodynamic process inside a host sediment matrix undergoing structural evolution. The transport processes are driven by the sedimentary load and induced overpressure gradients, controlled by sediment permeability. In order to accurately model the resulting fluid flow profile, the decrease of sediment permeability during hydrate precipitation has to be taken into account, which affects both the transport of solutes and sediment compaction. In this paper, we investigate how total hydrate abundance is affected by regions of low permeability which deflect the flow field in their vicinity. For this purpose, a two-dimensional numerical hydrate system model was set up which permits to quantify this effect in scenarios where changes in water depth cause lateral variations of the thickness of the hydrate stability field, as well as of hydrate saturation and sediment permeability. The microscopic structure of gas hydrate crystals in the host sediment matrix defines the evolution of the permeability reduction during hydrate formation. Grain-coating precipitates have a stronger tendency to clog flow paths through pore throats than do pore-filling precipitates. Our results clearly show that these pore-scale processes affect the large-scale flow field and hydrate abundance. The sensitivity depends on the model geometry and, for a 5° slope of the seafloor, 4.1% relative difference is predicted for the hydrate saturation according to different porosity-permeability relationships.  相似文献   
674.
675.
Diatomite associated with the Kolubara Coal Basin was studied to better understand early stage silica diagenesis of shallow water deposits. The Kolubara Basin consists of Neogene siliciclastic rocks, diatomite, marlstone and rare carbonates. Palaeozoic metamorphic and Mesozoic sedimentary and igneous basement rocks are transgressively overlain by Upper Miocene sandstone, siltstone, shale and mudstone. This Upper Miocene section is transgressively overlain by the Pontian section, which contains diatomite and coal beds. White and grey diatomite forms beds 0.7-2.2 m thick that are continuous over an area of about 2 km2. Siliceous rocks vary in composition from diatomite (81-89 per cent SiO2) to diatom-bearing shale (58-60 per cent SiO2). Siliceous deposits are laminated in places, with the laminae defined by variations in clay minerals, organic matter and diatoms. Diatomite shows only incipient diagenesis characterized by the fragmentation of diatom frustules, the minor to moderate corrosion of frustules and the formation of minor amounts of opal-A' (X-ray amorphous inorganic opal) cement. The low degree of diagenesis results from the young age of the deposits, low burial temperatures and possibly also from the presence of abundant organic matter and the dissolution of kaolinite. The presence of only weak diagenesis is also reflected by the characteristically poor consolidation of the rocks and low rank of the associated coal.  相似文献   
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