Librations of the Galilean satellites: The influence of global internal liquid layers

The four Galilean satellites are thought to harbor one or even two global internal liquid layers beneath their surface layer. The iron core of Io and Ganymede is most likely (partially) liquid and also the core of Europa may be liquid. Furthermore, there are strong indications for the existence of a subsurface ocean in Europa, Ganymede, and Callisto. Here, we investigate whether libration observations can be used to prove the existence of these liquid layers and to constrain the thickness of the overlying solid layers. For Io, the presence of a small liquid core increases the libration of the mantle by a few percent with respect to an entirely solid Io and mantle libration observations could be used to determine the mantle thickness with a precision of several tens of kilometers given that the libration amplitude can be measured with a precision of 1 m. For Europa, Ganymede, and Callisto, the presence of a water ocean close to the surface increases by at least an order of magnitude the ice shell libration amplitude with respect to an entirely solid satellite. The shell libration depends essentially on the shell thickness and to a minor extent on the density difference between the ocean and the ice shell. The possible presence of a liquid core inside Europa and Ganymede has no noticeable influence on their shell libration. For a precision of several meters on the libration measurements, in agreement with the expected accuracy with the NASA/ESA EJSM orbiter mission to Europa and Ganymede, an error on the shell thickness of a few tens kilometers is expected. Therefore, libration measurements can be used to detect liquid layers such as Io’s core or water subsurface oceans in Europa, Ganymede, and Callisto and to constrain the thickness of the overlying solid surface layers.     

A dynamical solution of the triple asteroid system (45) Eugenia

We present the first dynamical solution of the triple asteroid system (45) Eugenia and its two moons Petit–Prince (diameter ∼ 7 km) and S/2004 (45) 1 (diameter ∼ 5 km). The two moons orbit at 1165 and 610 km from the primary, describing an almost-circular orbit (e ∼ 6 × 10⁻³ and e ∼ 7 × 10⁻² respectively). The system is quite different from the other known triple systems in the main belt since the inclinations of the moon orbits are sizeable (9° and 18° with respect to the equator of the primary respectively). No resonances, neither secular nor due to Lidov–Kozai mechanism, were detected in our dynamical solution, suggesting that these inclinations are not due to excitation modes between the primary and the moons. A 10-year evolution study shows that the orbits are slightly affected by perturbations from the Sun, and to a lesser extent by mutual interactions between the moons. The estimated J₂ of the primary is three times lower than the theoretical one, calculated assuming the shape of the primary and an homogeneous interior, possibly suggesting the importance of other gravitational harmonics.     

Performance evaluation of active wireline heave compensation systems in marine well logging environments

The basic functionality and performance of a new Schlumberger active wireline heave compensation system on the JOIDES Resolution was evaluated during the sea trial and a 3-year period of the IODP Phase II operations. A suite of software programs was developed to enable real-time monitoring of the dynamics of logging tools, and assess the efficiency of wireline heave compensation during downhole operations. The evaluation of the system effectiveness was performed under normal logging conditions as well as during stationary tests. Logging data were analyzed for their overall quality and repeatability, and to assess the reliability of high-resolution data such as formation microscanner (FMS) electrical images. This revealed that the system reduces 65–80 % of displacement or 88–98 % variance of downhole tool motion in stationary mode under heave conditions of ±0.2–1.5 m and water depths of 300–4,500 m in open holes. Under similar water/heave conditions, the compensator system reduces tool displacement by 50–60 %, or 75–84 % variance in downhole tool motion during normal logging operations. Such compensation efficiency (CE) is comparable to previous compensation systems, but using advanced and upgradeable technologies, and provides 50–85 % heave motion and heave variance attenuation. Moreover, logging down/up at low speeds (300–600 m/h) reduces the system’s CE values by 15–20 %, and logging down at higher speeds (1,000–1,200 m/h) eliminates CE values by 55–65 %. Considering the high quality of the logging data collected, it is concluded that the new system can provide an improved level of compensation over previous systems. Also, if practically feasible, future integration of downhole cable dynamics as an input feedback into the current system could further improve its compensation efficiency during logging operations.     

The use of Bluetooth for analysing spatiotemporal dynamics of human movement at mass events: A case study of the Ghent Festivities

In this paper, proximity-based Bluetooth tracking is postulated as an efficient and effective methodology for analysing the complex spatiotemporal dynamics of visitor movements at mass events. A case study of the Ghent Festivities event (1.5 million visitors over 10 days) is described in detail and preliminary results are shown to give an indication of the added value of the methodology for stakeholders of the event. By covering 22 locations in the study area with Bluetooth scanners, we were able to extract 152,487 trajectories generated by 80,828 detected visitors. Apart from generating clear statistics such as visitor counts, the share of returning visitors, and visitor flow maps, the analyses also reveal the complex nature of this event by hinting at the existence of several mutually different visitor profiles. We conclude by arguing why Bluetooth tracking offers significant advantages for tracking mass event visitors with respect to other and more prominent technologies, and outline some of its remaining deficiencies.     

Evolution of extreme temperatures in Belgium since the 1950s

The objective of the present study is to apply a wide range of efficient trend estimation methods for understanding how temperature extremes are locally changing. Temporal patterns of changes in extreme daily maximum or minimum temperature at homogeneous climate stations located in Belgium and their associations with changes in climate means are examined for the period 1952/1953 until present. A considerable amount of work is devoted to the formulation of extreme value models in the presence of non-stationarity. The covariate process is considered to be linear in time or/and in the North Atlantic Oscillation index as well. Additional insights on historical changes in frequency and amplitude of temperature extremes are obtained with the non-parametric quantile-perturbation approach.     

A surface structural model for ferrihydrite II: Adsorption of uranyl and carbonate

The adsorption of uranyl (UO₂²⁺) on ferrihydrite has been evaluated with the charge distribution (CD) model for systems covering a very large range of conditions, i.e. pH, ionic strength, CO₂ pressure, U(VI) concentration, and loading. Modeling suggests that uranyl forms bidentate inner sphere complexes at sites that do not react chemically with carbonate ions. Uranyl is bound by singly-coordinated surface groups present at particular edges of Fe-octahedra of ferrihydrite while another set of singly-coordinated surface groups may form double-corner bidentate complexes with carbonate ions. The uranyl surface speciation strongly changes in the presence of carbonate due to the specific adsorption of carbonate ions as well as the formation of ternary uranyl-carbonate surface complexes. Data analysis with the CD model suggests that a uranyl tris-carbonato surface complex, i.e. (UO₂)(CO₃)₃⁴⁻, is formed. This species is most abundant in systems with a high pH and carbonate concentration. This finding differs significantly from previous interpretations made in the literature. At high pH and low carbonate concentrations, as can be prepared in CO₂-closed systems, the model suggests the additional presence of a ternary uranyl-monocarbonato complex. The binding mode (type A or type B complex) is uncertain. At high uranyl concentrations, uranyl polymerizes at the surface of ferrihydrite giving, for instance, tris-uranyl surface complexes with and without carbonate. The similarities and differences between U(VI) adsorption by goethite and ferrihydrite are discussed from a surface structural point of view.     

Neoproterozoic hydrothermally altered basaltic rocks from Rajasthan, northwest India: Implications for late Precambrian tectonic evolution of the Aravalli Craton

The isolated volcano-sedimentary sequences of the Punagarh and Sindreth Groups occur along the western flank of the Delhi Fold Belt in northwest India, and include mafic rocks (pillow basalts and dolerite dykes) that are dominantly olivine tholeiites with minor quartz-normative and alkali basalts. Sindreth samples appear to have higher primary TiO₂ and P₂O₅ abundances relative to those from Punagarh. Both suites of mafic rocks show variable, but profound hydrothermal alteration effects, with loss on ignition (LOI) values up to 10.3 wt.%, and extensive secondary minerals including albite, sericite, chlorite and calcite. Despite this, there is excellent preservation of magmatic textures, but there has been extensive albitization of plagioclase phenocrysts, a hallmark of hydrothermal alteration processes in oceanic crust. Supporting evidence for such hydrothermal alteration comes from correlations of LOI abundances with CaO/Na₂O, and evidence for U mobility is apparent on diagrams of Nb/Th vs. Nb/U. Felsic volcanic rocks (rhyolite, dacite) interlayered with the Sindreth basalts yield U–Pb zircon ages (TIMS method) between 761 ± 16 and 767 ± 3 Ma, which we interpret as representing the time of primary magmatic activity. We infer that the volcano-sedimentary rocks of the Punagarh also formed at this time, on the basis of similarities in lithology, stratigraphy, field relations and geochemistry. Intermediate granitoid rocks yield older U–Pb ages of 800 ± 2 and 873 ± 3 Ma, which we correlate with the post-Delhi Supergroup Erinpura Granites. Taken together, the features of the Punagarh and Sindreth Groups are consistent with their formation in a back-arc basin setting. Their coevality with other magmatic systems in NW India (Malani Igneous Suite), the Seychelles and Madagascar, for which a continental arc setting has also been proposed, supports the notion of an extensive convergent margin in western Rodinia at 750–770 Ma.     

Airborne gamma-ray and magnetic anomaly signatures of serpentinite in relation to soil geochemistry, northern California

Serpentinized ultramafic rocks and associated soils in northern California are characterized by high concentrations of Cr and Ni, low levels of radioelements (K, Th, and U) and high amounts of ferrimagnetic minerals (primarily magnetite). Geophysical attributes over ultramafic rocks, which include airborne gamma-ray and magnetic anomaly data, are quantified and provide indirect measurements on the relative abundance of radioelements and magnetic minerals, respectively. Attributes are defined through a statistical modeling approach and the results are portrayed as probabilities in chart and map form. Two predictive models are presented, including one derived from the aeromagnetic anomaly data and one from a combination of the airborne K, Th and U gamma-ray data. Both models distinguish preferential values within the aerogeophysical data that coincide with mapped and potentially unmapped ultramafic rocks. The magnetic predictive model shows positive probabilities associated with magnetic anomaly highs and, to a lesser degree, anomaly lows, which accurately locate many known ultramafic outcrops, but more interestingly, locate potentially unmapped ultramafic rocks, possible extensions of ultramafic bodies that dip into the shallow subsurface, as well as prospective buried ultramafic rocks. The airborne radiometric model shows positive probabilities in association with anomalously low gamma radiation measurements over ultramafic rock, which is similar to that produced by gabbro, metavolcanic rock, and water bodies. All of these features share the characteristic of being depleted in K, Th and U. Gabbro is the only rock type in the study area that shares similar magnetic properties with the ultramafic rock. The aerogeophysical model results are compared to the distribution of ultramafic outcrops and to Cr, Ni, K, Th and U concentrations and magnetic susceptibility measurements from soil samples. Analysis of the soil data indicates high positive correlation between magnetic susceptibilities and concentration of Cr and Ni. Although the study focused on characterizing the geophysical properties of ultramafic rocks and associated soils, it has also yielded information on other rock types in addition to ultramafic rocks, which can also locally host naturally-occurring asbestos; specifically, gabbro and metavolcanic rocks.     

Accumulation of short-chain fatty acids in an aquitard linked to anaerobic biodegradation of petroleum hydrocarbons

Investigation of a 17 m vertical profile of a silt and clay aquitard at a natural gas well site in Alberta, Canada revealed a contaminant plume of gas condensate, along with high concentrations of acetate, propionate and butyrate. The pattern of the distribution of these short-chain fatty acids in groundwater and sediment samples suggested that they have been produced by microorganisms in a process associated with degradation of the condensate hydrocarbons. It is suggested that, in certain zones, under water-saturated and/or anaerobic conditions, these acids were actively consumed by SO₄-reducing bacteria. Analyses of DNA extracts by denaturing gel gradient electrophoresis (DGGE) indicated that, compared to sediment samples collected from outside the condensate plume, contaminated samples tended to have fewer, but more strongly developed bands of DNA, which typically had closest affinities to known anaerobes, including species of Fe-reducing Geobacter, and SO₄-reducing Desulfosporosinus.     

Impact of metallurgy on the geochemical signature of dusts, soils and sediments in the vicinity of Elbasan complex (Albania)

An investigation of the metallurgical complex surroundings in Elbasani, Albania used background samples to rule out the level of contamination in the study area. Our results show that atmospheric dust particles and soils are of high concern while overbank sediments and actual river sediments are of lower concern. The heavy metals with concentrations of up to 5 times above the local background values are Zn, Cr, Ni, Cu, Fe and Co in soils; Fe, Cr, Co, Ni, Zn, Pb in dust particles; and, Cr and Zn in the actual river/stream sediments. Due to the small size of the dust particles and the atmospheric transportation mechanism primarily related to prevailing winds, the concern for the transport of dust particles is high, especially with respect to risks associated with inhalation. The people working and living in the vicinity of the metallurgical complex of Elbasani are at the highest risk of exposure. Concerns relating to soils are associated with the potential for translocation of the trace element particles into vegetation, in particular, within the upper part of the plants. Therefore, the consumption of the vegetables grown in the vicinity of the metallurgical site should be avoided. Special attention has been given to the Shkumbini river, where the long residence time of water and particulates may result in transitions of trace elements between dissolved and particulate phases downstream.