Tracing seafloor methane emissions with benthic foraminifera: Results from the Ana submarine landslide (Eivissa Channel,Western Mediterranean Sea)

The hypothesis that benthic foraminifera are useful proxies of local methane emissions from the seafloor has been verified on sediment core KS16 from the headwall of the Ana submarine landslide in the Eivissa Channel, Western Mediterranean Sea. The core MS312 from a nearby location with no known methane emissions is utilised as control. The core was analysed for biostratigraphy, benthic foraminiferal assemblages, Hyalinea balthica and Uvigerina peregrina carbon and oxygen stable isotope composition, and sedimentary structures. The upper part of the core records post-landslide deglacial and Holocene normal marine hemipelagic sediments with highly abundant benthic foraminifera species that are typical of outer neritic to upper bathyal environment. In this interval, the δ¹³C composition of benthic foraminifera indicates normal marine environment analogous to those found in the control core. Below the sedimentary hiatus caused by the emplacement of the slide, the foraminiferal assemblages are characterised by lower density and higher Shannon Index. Markedly negative δ¹³C shifts in benthic foraminifera are attributed to the release of methane through the seabed. The mean values of the ¹³C anomaly in U. peregrina are ? 0.951 ± 0.208 in the pre-landslide sediments, and ? 0.269 ± 0.152 in post-slide reworked sediments deposited immediately above the hiatus. The δ¹³C anomaly in Hyalinea balthica is ? 2.497 ± 0.080 and ? 2.153 ± 0.087, respectively. To discard the diagenetic effects on the δ¹³C anomaly, which could have been induced by Ca–Mg replacement and authigenic carbonate overgrowth on foraminifera tests, a benthic foraminifera subsample has been treated following an oxidative and reductive cleaning protocol. The cleaning has resulted, only in some cases, in a slight reduction of the anomaly by 0.95% for δ¹³C and < 0.80% for δ¹⁸O. Therefore, the first conclusion is that the diagenetic alteration is minor and it does not alter significantly the overall carbon isotopic anomaly in the core. Consequently, the pre-landslide sediments have been subject to pervasive methane emissions during a time interval of several thousand years. Methane emissions continued during and immediately after the occurrence of Ana Slide at about 61.5 ka. Subsequently, methane emissions decreased and definitely ceased during the last deglaciation and the Holocene.     

Long‐term nitrogen and phosphorus fertilization effects on N2 fixation rates and nifH gene community patterns in mangrove sediments

The bioavailability of nutrients is important in controlling ecological processes and nitrogen cycling in oligotrophic mangrove forests, yet the variation of diazotrophic community structure and activity with nutrient availability in sediments remains largely unexplored. To investigate for the first time how nutrients in sediments affect spatial and temporal patterns of diazotrophic community structure and activity, the sedimentary environment of Twin Cays, Belize, was examined with respect to the effects of long‐term fertilization [treatments: control (Ctrl), nitrogen (N), and phosphorus (P)] on N₂ fixation rates and nifH gene community structure. We found that N₂ fixation rates were significantly higher at the P‐treatment, intermediate at the Ctrl‐treatment and lower in the N‐treatment (P: 4.2 ± 0.5, Crtl: 0.8 ± 0.1, N: 0.4 ± 0.1 nmol·N·g^?1·h^?1; P < 0.001) with spatial (Ctrl‐ and P‐treatments) and temporal (only P‐treatment) variability positively correlated with live root abundance (r² = 0.473, P < 0.001) and concentration (r² = 0.458, P < 0.0001). The community structure of diazotrophs showed larger spatial and temporal variability in the fertilized treatments than in the Ctrl‐treatment, with the relative abundance of OTUs (nifH operational taxonomic units) at the fertilized treatments inversely related to live root abundance. Overall, long‐term fertilization (with either N or P) affects not only nutrient levels in mangrove sediments directly, but also spatial and temporal patterns of both community structure and activity and likely plant‐microbe interactions as well. Our findings suggest that the maintenance of natural nutrient conditions in mangrove sediments is important to ensure the stability of microbial functional groups like diazotrophs.     

Extension of observed flood series by combining a distributed hydro-meteorological model and a copula-based model

Long flood series are required to accurately estimate flood quantiles associated with high return periods, in order to design and assess the risk in hydraulic structures such as dams. However, observed flood series are commonly short. Flood series can be extended through hydro-meteorological modelling, yet the computational effort can be very demanding in case of a distributed model with a short time step is considered to obtain an accurate flood hydrograph characterisation. Statistical models can also be used, where the copula approach is spreading for performing multivariate flood frequency analyses. Nevertheless, the selection of the copula to characterise the dependence structure of short data series involves a large uncertainty. In the present study, a methodology to extend flood series by combining both approaches is introduced. First, the minimum number of flood hydrographs required to be simulated by a spatially distributed hydro-meteorological model is identified in terms of the uncertainty of quantile estimates obtained by both copula and marginal distributions. Second, a large synthetic sample is generated by a bivariate copula-based model, reducing the computation time required by the hydro-meteorological model. The hydro-meteorological modelling chain consists of the RainSim stochastic rainfall generator and the Real-time Interactive Basin Simulator (RIBS) rainfall-runoff model. The proposed procedure is applied to a case study in Spain. As a result, a large synthetic sample of peak-volume pairs is stochastically generated, keeping the statistical properties of the simulated series generated by the hydro-meteorological model. This method reduces the computation time consumed. The extended sample, consisting of the joint simulated and synthetic sample, can be used for improving flood risk assessment studies.     

Archeoseismic study of damage in Roman and Medieval structures in the center of Cologne, Germany

The causes of damage observed in archeological records or preserved monuments are often difficult to be determined unequivocally, particularly when the possibility of secondary earthquake damage exists. Such secondary damage has been previously proposed for the Roman Praetorium, the governor’s palace in the center of Cologne. Ongoing excavations since 2007 revealed additional damage. The existing ground that has been uncovered and documented extends the affected area to 175?×?180 m. We present a comprehensive virtual model of the excavation area based on 200 3D laserscans together with a systematic analysis of the damage patterns and an improved model of the terrain during Roman/Medieval times including geotechnical parameters of the subsurface. Five locations with different damage patterns, including a Roman sewer, the octagonal central part of the Praetorium, a section with strongly inclined massive walls, a 13 m deep deformed well, a collapsed hypocaust, and damages in the Medieval mikveh are analyzed in detail. We use site-specific synthetic strong ground motion seismograms to test the possibility of earthquake-induced ground failures as a cause for the observed damage. This subsurface model is also used to test the possibility of hydraulically-induced damages by seepage and erosion of fine-grained material from stray sand. Heavy rainstorms can induce a direct stream of surface water through the fine sand layers to the ground water table. Simulated ground motion for assumed worst-case earthquake scenarios do not provoke slope instability at the level necessary to explain the structural damages.     

Development of FLEMOcs – a new model for the estimation of flood losses in the commercial sector

Abstract

The estimation of flood damage is an important component for risk-oriented flood design, risk mapping, financial appraisals and comparative risk analyses. However, research on flood-loss modelling, especially in the commercial sector, has not gained much attention so far. Therefore, extensive data about flood losses were collected for affected companies via telephone surveys after the floods of 2002, 2005 and 2006 in Germany. Potential loss determining factors were analysed. The new Flood Loss Estimation MOdel for the commercial sector (FLEMOcs) was developed on the basis of 642 loss cases. Losses are estimated depending on water depth, sector and company size as well as precaution and contamination. The model can be applied to the micro-scale, i.e. to single production sites as well as to the meso-scale, i.e. land-use units, thus enabling its countrywide application.

Citation Kreibich, H., Seifert, I., Merz, B. & Thieken, A. H. (2010) Development of FLEMOcs – a new model for the estimation of flood losses in the commercial sector. Hydrol. Sci. J. 55(8), 1302–1314.     

Application and validation of FLEMOcs – a flood-loss estimation model for the commercial sector

Abstract

The estimation of flood loss is difficult, especially in the commercial sector, because of its great inhomogeneity. However, the reliability of loss modelling is fairly unknown, since flood-loss models are scarcely validated. The newly developed Flood Loss Estimation MOdel for the commercial sector (FLEMOcs) was validated on the micro-scale using a leave-one-out cross-validation procedure. Additionally, different meso-scale loss functions were compared. Meso-scale model application was undertaken in 19 municipalities which were affected during the 2002 flood in Germany. Model results were compared with the results of three other loss models, as well as with official loss records. The micro-scale validation shows very good results, with no bias and mean absolute errors between 23 and 31%. The meso-scale validation indicates that FLEMOcs provides good results, especially in large areas with many affected companies where high losses are expected.

Citation Seifert, I., Kreibich, H., Merz, B. & Thieken, A. H. (2010) Application and validation of FLEMOcs – a flood-loss estimation model for the commercial sector. Hydrol. Sci. J. 55(8), 1315–1324.     

Effects of seawater acidification on early development of the intertidal sea urchin Paracentrotus lividus (Lamarck 1816)

The effect of pH ranging from 8.0 to 6.8 (total scale - pH_T) on fertilization, cleavage and larval development until pluteus stage was assessed in an intertidal temperate sea urchin. Gametes were obtained from adults collected in two contrasting tide pools, one showing a significant nocturnal pH decrease (lowest pH_T = 7.4) and another where pH was more stable (lowest pH_T = 7.8). The highest pH_T at which significant effects on fertilization and cleavage were recorded was 7.6. On the contrary, larval development was only affected below pH_T 7.4, a value equal or lower than that reported for several subtidal species. This suggests that sea urchins inhabiting stressful intertidal environments produce offspring that may better resist future ocean acidification. Moreover, at pH_T 7.4, the fertilization rate of gametes whose progenitors came from the tide pool with higher pH decrease was significantly higher, indicating a possible acclimatization or adaptation of gametes to pH stress.     

Patterns of rare earth and other trace elements in different size fractions of clays of Campanian–Maastrichtian deposits from the Portuguese western margin (Aveiro and Taveiro Formations)

The Upper Cretaceous (Campanian–Maastrichtian) Taveiro and Aveiro Formations belong to the northern sector of the Lusitanian basin (Portuguese western margin). The Taveiro Formation was deposited in alluvial fans, including mud flow beds, lakes and sinuous rivers. The Aveiro Formation was deposited in a flat region with low hydrodynamics channels, with the formation of a barrier island-tidal system. The reconstruction of this sedimentary basin may be difficult due to its complex architecture. This work aims a methodology to be used in the reconstruction of Cretaceous sedimentary environments of the Lusitanian basin, through the establishment of geochemical patterns of different size fractions of those deposits. Chemical analysis was performed by instrumental neutron activation analysis (INAA), and the mineralogical composition obtained by X-ray diffractometry (XRD). The whole rock and different size fractions (? ≥ 125 μm, 63–125 μm, 20–63 μm, 2–20 μm and ? < 2 μm) of selected samples were studied aiming the rare earth elements (REE) and other trace elements distribution and its correlation with the grain size and mineralogy.The results obtained for the studied Cretaceous sediments showed that REE patterns and other trace elements distribution in the different size fractions may be used as a tool to differentiate deposits within and between sedimentary formations. Within the Taveiro Formation, REE are concentrated in the silt fractions (20–63 μm and 2–20 μm) of the Reveles deposit, and in the clay size fraction of S. Pedro deposit, which is richer in kaolinite. The 1st transition elements, particularly Zn, are correlated with the presence of smectite in the clay fraction of Reveles deposit. In the sand and silt size fractions (>2 μm) of samples from Taveiro Formation correlations were found between: Ga and 1st transition elements, and phyllosilicates; Cs and mica; and Rb and Ba, and K–feldspars.The Bustos deposit (Aveiro Formation) samples are very fine-grained and with a high proportion of the fine silt fraction where REE are concentrated, especially the heavy ones. Incorporation of MREE, Co and U in carbonates of the coarser fraction appears to occur. The abundances of the 1st transition elements, Ga and As, are correlated with phyllosilicates.Significant differences were found in the trace elements patterns of the various analysed size fractions of the Lusitanian basin of Cretaceous sediments, between and even within formations, which can be used as a methodological approach for a fine paleogeographic reconstruction.     

Spatial gradients in plant leaf wax D/H across a coastal salt marsh in southern California

Coastal salt marsh ecosystems contain strong environmental gradients that are anticipated to influence the D/H ratios recorded in the leaf waxes of salt-tolerant plants. We characterized the molecular and hydrogen isotopic composition of alkanes in plant and sediment samples as well as the D/H ratios of environmental and plant waters across an elevation and inundation gradient in a southern Californian, coastal salt marsh. We sampled the dominant salt marsh plant species: Salicornia virginica, Arthrocnemum subterminale and Jamuea carnosa (all succulents), as well as Monanthochloe littoralis and Limonium californicum (nonsucculents). Plant xylem water hydrogen isotopic compositions indicate a shift in source waters from meteoric influences at upland sites (δD value −20‰) to seawater dominated values (0‰) at lowland areas. We found leaf water D enrichment relative to xylem water ranging from mean δD values of +54‰ (upland) to +28‰ (lowland), interpreted as a reduction of transpiration with increasing inundation time. This has the effect of increasing the net fractionation between source water and leaf wax product across the environmental gradient from mean values of −101‰ (upland) to −134‰ (lowland), with an attenuated signal recorded in the δD values of plant leaf wax n-alkanes (−122‰ to −136‰). These results constrain the hydrogen isotopic composition of salt marsh organic matter that may contribute to marine carbon budgets of the Santa Barbara Basin, and further indicate the potential for plant leaf waxes to resolve paleoenvironmental change, including sea level change, in sediment cores from salt marsh ecosystems.