Heavy metals distribution in agricultural topsoils in urban area

Intensive urbanisation of the Croatian capital of Zagreb has led to a situation where very good agricultural soils, developed mostly on Pleistocene eolian sediments and alluvial and proluvian Holocene sediments are entrapped within urban and suburban areas. Therefore the influence of urban and industrialised environments on the accumulation of metals in agricultural topsoils has been investigated. On an area of 860 km² of the wider Zagreb region, 331 samples were taken according to a regular 1ǵ km square mesh. Samples were dissolved in aqua regia and analysed for Cd, Cu, Fe, Mn, Ni, Pb and Zn with flame atomic aqua regia absorption spectroscopy. The following concentration ranges have been determined: Cd 0.25-3.85 mg kg^-1 (average 0.66 mg kg^-1), Cu 4.30-183 mg kg^-1 (average 20.8 mg kg^-1), Fe 5.8-51.8 g kg^-1 (average 27 g kg^-1), Mn 79.2-1282 mg kg^-1 (average 613 mg kg^-1), Ni 0.70-282 mg kg^-1 (average 49.5 mg kg^-1), Pb 1.50-139 mg kg^-1 (average 25.9 mg kg^-1), and Zn 15.2-277 mg kg^-1 (average 77.9 mg kg^-1). Visualisation of the spatial data is made by the aid of GIS, and selected maps of the heavy metal concentrations in topsoils are displayed. Statistical multivariate analysis was carried out for quantitative study and data were processed by means of R-mode factor analysis, applying the varimax-raw rotational technique. F1, which grouped Cd, Pb, Cu, Zn and partially Ni, is characterized as a factor with strongly scattered anthropogenic influence. The elements in F2, Fe, Mn and partially Ni are mainly of geogenic, i.e. pedogenic, origin. The variations in concentrations of the investigated elements are thus of both natural and anthropogenic origins. The variations in the main soil constituents, particularly Fe and Mn, are determined primarily by the composition of different regolithic substrates of the fluvial origin in recent pedogenesis. High concentrations of nickel are also related to morphogenetic characteristics of the wider region, primarily basic and ultrabasic magmatic rocks of the surrounding mountain range. It is, however, assumed that the anomalous nickel concentrations in the vicinity of the highway and the airport are of anthropogenic origin, i.e. caused by fuel combustion. Copper is characterized by strongly scattered anthropogenic influence, which is related particularly to uncontrolled solid waste disposals or discharges of liquid waste from households or agricultural enterprises. With Zn, Pb and Cd, there are two possible ways of diffuse pollution. The Sava River, which drains the area and feeds the abundant Quaternary aquifer spreading below the major part of the investigated agricultural areas, has been exposed to intensive pollution by mining, industry and cities in the recent history. The part of the area with the highest determined concentrations of Zn, Pb and Cd was repeatedly flooded as recently as the previous decade; therefore, the recent sedimentation of the river deposits exposed to pollution is a very probable cause of the accumulation of metals in this until recently inundation area. The other way is atmospheric deposition of particles from urban sources (industrial emission, traffic, waste disposals, heating plants, etc.). In addition to agricultural enterprises, several economically important, but ecologically risky, facilities are situated in the vicinity of the water-protection area. The area is intersected by a very busy ring road, while a marshalling yard, the city dump, pharmaceutical and chemical industry, the district-heating plant and the airport are all located in close proximity. The geochemical maps show a clear relationship between human activities and metal concentration gradients.     

Application of visual,statistical and artificial neural network methods in the differentiation of water from the exploited aquifers in Kuwait

The ability of artificial neural network to differentiate water samples from the two aquifers of Kuwait on the basis of their major ion chemistry has been demonstrated. The major ion concentration distribution in the groundwater of the Kuwait Group and the Dammam Formation aquifers of Kuwait appears very similar. Cross-plots, supported by the discriminant function analysis of the data, however, suggest that there are some subtle differences in the overall composition of the water from the two aquifers that make it possible to differentiate the water from the two aquifers in almost 80% of the cases. An artificial neural network improved the differentiation capability to 90% of the cases. It is also possible to estimate the fraction of Kuwait Group water in the flow stream of dually completed wells with the help of an artificial neural network developed for this purpose. Electronic Publication     

Environmental impact assessment in the Moradabad industrial area (rivers Ramganga-Ganga interfluve), Ganga Plain,India

Sediment samples collected in the Moradabad area, lying in the interfluve of the Ganga and Ramganga Rivers, were analysed for heavy metals, after studying the geomorphology of the area. Geomorphologically, the area can be divided into three terraces - the T₀, T₁ and T₂ surfaces. The rivers on these three surfaces show varying amounts of pollution depending upon the input from industries and urban settlements. The Ramganga River on the T₀ surface shows the highest amount of pollution. However, the pollution levels in all these rivers show a downstream dilution effect. The characteristic feature of the vast interfluve area (T₂ surface) is the presence of several, independent basins which are closed and rarely interact with each other or with any river. The sediments are redistributed and redeposited within the basin itself, and thus these basins serve as sinks. The sediments of one such basin in the study area show significant concentrations of arsenic, chromium, copper, nickel, lead, zinc and organic carbon. The concentrations of heavy metals in such a basin will show exponential increases with time, because there is no activity to funnel out the sediments and dilute the effect of pollution. This increase will pose more threats, as ultimately it will make its way laterally and vertically through the sediments, thereby polluting groundwater.     

Circulation characteristics of a monsoon depression during BOBMEX-99 using high-resolution analysis

The skill and efficiency of a numerical model mostly varies with the quality of initial values, accuracy on parameterization of physical processes and horizontal and vertical resolution of the model. Commonly used low-resolution reanalyses are hardly able to capture the prominent features associated with organized convective processes in a monsoon depression. The objective is to prepare improved high-resolution analysis by the use of MM5 modelling system developed by the Pennsylvania State University/National Center for Atmospheric Research (PSU/NCAR). It requires the objective comparison of high and low-resolution analysis datasets in assessing the specific convective features of a monsoon depression. For this purpose, reanalysis datasets of NCAR/NCEP (National Center for Atmospheric Research/National Centers for Environmental Prediction) at a horizontal resolution of 2.5‡ (latitude/longitude) have been used as first guess in the objective analysis scheme. The additional asynoptic datasets obtained during BOBMEX-99 are utilized within the assimilation process. Cloud Motion Wind (CMW) data of METEOSAT satellite and SSM/I surface wind data are included for the improvement of derived analysis. The multiquadric (MQD) interpolation technique is selected and applied for meteorological objective analysis at a horizontal resolution of 30 km. After a successful inclusion of additional data, the resulting reanalysis is able to produce the structure of convective organization as well as prominent synoptic features associated with monsoon depression. Comparison and error verifications have been done with the help of available upper-air station data. The objective verification reveals the efficiency of the analysis scheme.     

Volatiles in glasses from Mauna Loa Volcano,Hawai'i: implications for magma degassing and contamination,and growth of Hawaiian volcanoes

Glasses from Mauna Loa pillow basalts, recent subaerial vents, and inclusions in olivine were analyzed for S, Cl, F, and major elements by electron microprobe. Select submarine glasses were also analyzed for H₂O and CO₂ by infrared spectroscopy. The compositional variation of these tholeiitic glasses is dominantly controlled by crystal fractionation and they indicate quenching temperatures of 1,115-1,196 °C. Submarine rift zone glasses have higher volatile abundances (except F) than nearly all other submarine and subaerial glasses with the maximum concentrations increasing with water depth. The overwhelming dominance of degassed glasses on the submarine flanks of Mauna Loa implies that much of volcano's recent submarine growth involved subaerially erupted lava that reached great water depths (up to 3.1 km) via lava tubes. Anomalously high F and Cl in some submarine glasses and glass inclusions indicate contamination possibly by fumarolic deposits in ephemeral rift zone magma chambers. The relatively high CO₂ but variable H₂O/K₂O and S/K₂O in some submarine rift zone glasses indicates pre-eruptive mixing between degassed and undegassed magma within Mauna Loa's rift system. Volatile compositions for Mauna Loa magmas are similar to other active Hawaiian volcanoes in S and F, but are less Cl-rich than Ll'ihi glasses. However, Cl/K2O ratios are similar. Mauna Loa and Ll'ihi magmas have comparable, but lower H₂O than those from Kilauea. Thus, Kilauea's source may be more H₂O-rich. The dissimilar volatile distribution in glasses from active Hawaiian volcanoes is inconsistent with predictions for a simple, concentrically zoned plume model.     

A coupled,dynamical and chemical model for the prestellar core L1544: Comparison of modeled and observed C<Superscript>18</Superscript>O,HCO<Superscript>+</Superscript>, and CS emission spectra

We consider radiative transfer in C¹⁸O, HCO⁺, and CS molecular lines in a spherically symmetrical, coupled, dynamical and chemical model of a prestellar core whose evolution is determined by ambipolar diffusion. Theoretical and observed line profiles are compared for the well-studied core L1544, which may be a collapsing protostellar cloud. We study the relationship between the line shapes and model parameters. The structure of the envelope and kinematic parameters of the cloud are the most important factors determining the shape of the lines. Varying the input model parameters for the radiative transfer—the kinetic temperature and microturbulent velocity—within the limits imposed by observations does not result in any substantial variations of the line profiles. The comparison between the model and observed spectra indicates that L1544 displays a flattened structure, and is viewed at an oblique angle. A two-dimensional model is needed to reproduce this structure.     

2D stabilised analytic signal method in DC pole-pole potential data interpretation

Using analytic signal method, interpretation of pole-pole secondary electric potentials due to 2D conductive/resistive prisms is presented. The estimated parameters are the location, lateral extent or width and depth to top surface of the prism. Forward modelling is attempted by 2D-Finite Difference method. The proposed stabilised analytic signal algorithm (RES2AS) uses Tikhonov’s regularization scheme and FFT routines. The algorithm is tested on three theoretical examples and field data from the campus of Roorkee University. The stability of RES2AS is also tested on synthetic error prone secondary pole-pole potential data.     

2-D deformation analysis of a half-space due to a long dip-slip fault at finite depth

Closed form analytical expressions of stresses and displacements at any field point due to a very long dip-slip fault of finite width buried in a homogeneous, isotropic elastic half-space, are presented. Airy stress function is used to derive the expressions of stresses and displacements which depend on the dip angle and depth of the upper edge of the fault. The effect of dip angle and depth of the upper edge of the fault on stresses and displacements is studied numerically and the results obtained are presented graphically. Contour maps for stresses and displacements are also presented. The results of Rani and Singh (1992b) and Freund and Barnett (1976) have been reproduced.