Solid‐state 13C NMR characterization of insoluble organic matter from Antarctic CM2 chondrites: Evaluation of the meteoritic alteration level

Abstract— Chemical structures of the insoluble organic matter (IOM) from the Antarctic CM2 chondrites (Yamato [Y‐] 791198, 793321; Belgica [B‐] 7904; Asuka [A‐] 881280, 881334) and the Murchison meteorite were analyzed by solid‐state ¹³C nuclear magnetic resonance (NMR) spectroscopy. Different types of carbons were characterized, such as aliphatic carbon (Ali‐C), aliphatic carbon linked to hetero atom (Hetero‐Ali‐C), aromatic carbon (Aro‐C), carboxyls (COOR), and carbonyls (C=O). The spectra of the IOM from Murchison and Y‐791198 showed two major peaks: Ali‐C and Aro‐C, while the spectra from the other meteorites showed only one major peak of Aro‐C. Carbon distribution was determined both by manual integration and deconvolution. For most IOM, the Aro‐C was the most abundant (49.8–67.8%) of all carbon types. When the ratios of Ali‐C to Aro‐C (Ali/Aro) were plotted with the atomic hydrogen to carbon ratio (H/C), a correlation was observed. If we use the H/C as a parameter for the thermal alteration event on the meteorite parent body, this result shows a different extent of thermal alteration. In addition, IOM with a lower Ali/Aro showed a lower ratio of Ali‐C to COOR plus C=O (Ali / (COOR + C=O)). This result suggests that the ratio of CO moieties to aliphatic carbon in IOM might reflect chemical oxidation that was involved in hydrothermal alteration.     

Infrared spectroscopic taxonomy for carbonaceous chondrites from speciation of hydrous components

Abstract— Mid‐infrared absorption spectra for all types of carbonaceous chondrites were obtained in this study to establish a versatile method for spectroscopic classification of carbonaceous chondrites. Infrared spectra were measured using a conventional KBr pellet method and diamond press method. Spectra of hydrous carbonaceous chondrites exhibit intense O‐H stretching vibrations. CI chondrites are identifiable by a characteristic sharp absorption band appearing at 3685 cm^?1, which is mainly attributable to serpentine. X‐ray diffraction analysis showed the presence of serpentine. However, Yamato (Y‐) 82162 (C1) does not have the band at 3685 cm^?1 because of its thermal metamorphism. CM and CR chondrites have an intense absorption band at approximately 3600 cm^?1. This absorption tends to appear in CM chondrites more strongly than CR chondrites because the intensity ratios of an OH stretching mode at 3520 cm^?1 compared to 3400 cm^?1 for CM chondrites are in the range of 0.95–1.04, which is systematically higher than those of CR chondrites (0.86–0.88). Therefore, the two types of chondrites are distinguishable by their respective infrared spectra. The spectrum feature of the Tagish Lake meteorite is attributable to neither CI nor CM chondrites. CO chondrites are characterized by weak and broad absorption at 3400 cm^?1. CV chondrites have weak or negligible absorption of water. CK chondrites also have no water‐induced absorption. CH and CB chondrites have a sharp absorption at 3692 cm^?1 indicating the presence of chrysotile, which is also supported by observations of X‐ray diffraction and TEM. The combination of spectroscopic classification and the diamond press method allows classification of carbonaceous chondrites of very valuable samples with small quantities. As one example, carbonaceous chondrite clasts in brecciated meteorites were classified using our technique. Infrared spectra for a fragment of carbonaceous clasts (<1 μg) separated from Willard (b) and Tsukuba were measured. The 3685 cm^?1 band found in CI chondrites was clearly detected in the clasts, indicating that they are CI‐like clasts.     

The Sunyaev–Zel'dovich effect and Faraday rotation contributions of galaxy groups to the CMB angular power spectrum

The Sunyaev–Zel'dovich (SZ) effect and the Faraday rotation from haloes are examined over a wide mass range, including gas condensation and magnetic field evolution. Contributions to the cosmic microwave background (CMB) angular power spectrum are evaluated for galaxy clusters, galaxy groups and galaxies. Smaller mass haloes are found to play a more important role than massive haloes for the B -mode polarization associated with the SZ CMB anisotropies. The B modes from the Faraday rotation dominate the secondary B modes caused by gravitational lensing at  ℓ > 3000  . Measurement of B -mode polarization in combination with the SZ power spectrum can potentially provide important constraints on intracluster magnetic field and gas evolution at early epochs.     

Cluster formation and the Sunyaev–Zel'dovich power spectrum in modified gravity: the case of a phenomenologically extended DGP model

We investigate the effect of modified gravity on cluster abundance and the Sunyaev–Zel'dovich (SZ) angular power spectrum. Our modified gravity is based on a phenomenological extension of the Dvali–Gabadadze–Porrati model which includes two free parameters characterizing deviation from Λ cold dark matter cosmology. Assuming that Birkhoff's theorem gives a reasonable approximation, we study the spherical collapse model of structure formation and show that while the growth function changes to some extent, modified gravity gives rise to no significant change in the linear density contrast at collapse time. The growth function is enhanced in the so called normal branch, while in the 'self-accelerating' branch it is suppressed. The SZ angular power spectrum is computed in the normal branch, which allows us to put observational constraints on the parameters of the modified gravity model using small scale cosmic microwave background observation data.     

The cross-correlation of the CMB polarization and the 21-cm line fluctuations from cosmic reionization

The cosmic microwave background (CMB) polarization and the 21-cm line fluctuations are powerful probes of cosmological reionization. We study how the cross-correlation between the CMB polarization ( E modes) and the 21-cm line fluctuations can be used to gain further understanding of the reionization history, within the framework of inhomogeneous reionization. Since the E -mode polarization reflects the amplitude of the quadrupole component of the CMB temperature fluctuations, the angular power spectrum of the cross-correlation exhibits oscillations at all multipoles. The first peak of the power spectrum appears at the scale corresponding to the quadrupole at the redshift, which is probed by the 21-cm line fluctuations. The peak reaches its maximum value in redshift when the average ionization fraction of the universe is about half. On the other hand, on small scales, there is a damping that depends on the duration of reionization. Thus, the cross-correlation between the CMB polarization and the 21-cm line fluctuations has the potential to accurately constrain the epoch and the duration of reionization.     

A comparison of neighbourhood relations based on ordinary Delaunay diagrams and area Delaunay diagrams: an application to define the neighbourhood relations of buildings

ABSTRACT

The aim of this article is to describe a convenient but robust method for defining neighbourhood relations among buildings based on ordinary Delaunay diagrams (ODDs) and area Delaunay diagrams (ADDs). ODDs and ADDs are defined as a set of edges connecting the generators of adjacent ordinary Voronoi cells (points representing centroids of building polygons) and a set of edges connecting two centroids of building polygons, which are the generators of adjacent area Voronoi cells, respectively. Although ADDs are more robust than ODDs, computation time of ODDs is shorter than that of ADDs (the order of their computation time complexity is O(nlogn)). If ODDs can approximate ADDs with a certain degree of accuracy, the former can be used as an alternative. Therefore, we computed the ratio of the number of ADD edges to that of ODD edges overlapping ADDs at building and regional scales. The results indicate that: (1) for approximately 60% of all buildings, ODDs can exactly overlap ADDs with extra ODD edges; (2) at a regional scale, ODDs can overlap approximately 90% of ADDs with 10% extra ODD edges; and (3) focusing on judging errors, although ADDs are more accurate than ODDs, the difference is only approximately 1%.     

Bottom pressure change associated with the 2004–2005 large meander of the Kuroshio south of Japan

A large meander of the Kuroshio was generated in the region off the southern coast of Japan in August 2004 and continued until approximately July 2005. The formation and decay of the large-meander (LM) path was observed by bottom pressure (BP) sensors installed on inverted echo sounders (PIESs) and a seismic observing system off Shikoku. The variation in BP was examined focusing on the development, persistence, and decay of the LM path. The BP was found to be depressed associated with a Kuroshio path disturbance, called a small meander, and this BP depression led the sea surface height (SSH) depression by up to approximately two months. The temporal phase shift between the sea surface and deep disturbances was significantly greater than those of other small meanders that did not develop into large meanders. After the formation of the LM path, the BP beneath the Kuroshio increased with a lag of approximately two months behind the SSH elevation along with the upward displacement of the main thermocline. The increase in BP is associated with that of the positive southward BP gradient anomaly, i.e., the eastward deep Kuroshio current anomaly, which suggests an enhancement of the topographic steering and stability of the LM path. This is consistent with the fact that no small meanders occurred in the early LM period from late July 2004 to late January 2005.