Geochemistry of Adakites from the Philippines: Constraints on Their Origins

Abstract. We have identified in the Philippine Archipelago 230 samples of Late Miocene to Quaternary intermediate and evolved magmatic rocks or glasses, the compositions of which plot within the adakitic field defined by Defant and Drum-mond (1990) using Sr/Y ratios versus Y contents. These rocks belong to four different subductions, along the Manila Trench (Batan, Northern Luzon, Central Luzon), the Negros and Sulu Trenches (Negros and Western Mindano), the Cotobato Trench (Southern Mindanao) and the Philippine Trench (Eastern Mindanao). Lavas from Central Mindanao overlie the deep remnants of the Molucca Sea Plate, and were emplaced in a post-collision setting.
All these samples show a significant depletion in Y and HREE with respect to their "normal" calc-alkaline equivalents, suggesting that garnet was either a residual phase during partial melting or a fractionating mineral during differentiation or assimilation coupled with fractional crystallisation (AFC). However, only 19 samples out of our set (i.e., 8 %) display very high Sr/Y ratios (100–250). Our preferred model for the genesis of these "typical adakites" is ca. 20 % partial melting of subducted altered oceanic metabasalts converted to eclogite. This melting process could have been triggered by water from the underlying serpentinites. Most of the samples, termed "intermediate adakites", display major and trace element chemical features intermediate between those of the former group and those of normal calc-alkaline lavas. We show that magma mixing between slab-derived adakitic magmas and mafic mantle-derived melts accounts for most of the trends linking typical and intermediate adakites, although an additional contribution of mantle is required in some cases.     

Ash layers in deep-sea sediments as tracers of arc volcanic activity: Japan and Central America as case studies

Abstract Arc volcanic activity on opposite sides of the Pacific Ocean (Japan and Central America) has been investigated by examining the number of volcanic ash layers recorded in Neogene and Quaternary deep-sea sediments. The data suggest that ash layers counted in deep-sea sediments may provide a reliable record of arc volcanism. The study is based on a quantitative analysis of arc volcanic activity using cores collected on DSDP (Deep-Sea Drilling Project) and ODP (Ocean Drilling Program) legs. Five distinct parameters which might affect ash distribution in marine sediments were reviewed: nature of the eruption, wind influence, settling conditions, diagenesis, and plate motion. Of these five, past atmospheric circulation was the most significant. The main constraint on the analysis is that temporal scattering of ash is not directly related to wind pattern variations. Results of this analysis are correlated with dating of terrestrial volcanic sequences. Although marine tephra records for individual regions reveal minor differences in the episodes of volcanic activity, a general correlation exists between activity of arc volcanism in Japan and in Central America. Two important pulses of arc volcanism occurred during Middle Miocene times (18–13 Ma) and Plio-Quaternary times (5–0 Ma). These episodes of intense volcanism are separated by a well recorded quiescent period during Late Miocene times. These correlating episodes of the volcanic record indicate a direct link between arc volcanism and the global tectonic evolution of the Pacific ocean margins.     

Q-band esr studies of fossil teeth: Consequences for esr dating

At least 14 axial-symmetry ESR lines in Plio-Quaternary enamel fibres were observed by Q-band technique. Some lines follow a law e.g. the main anisotropic A-line whose g = 2.0018 and g = 1.9977 are close to g_eff = 2.0020 and g_eff = 1.9975 respectively of the isotropic doublets B- and E-lines. The other lines are blocked below 220K e.g. one isotropic hyperfine (g = 2.0033, a = 21.6 Gauss) M-septet and one isotropic singlet (g = 2.0007) D-line. By heating, the M-septet intensity increases up to 250°C and is lost at 280°C; B- and E-lines decrease while a new isotropic (g = 2.0056) C-line appears. At 300°C, only the two C- and A-lines usually remain and hold up to 400°C.The natural dose rate of fossil enamel is calculated from U-, Th-, K-content and disequilibrium measured both in enamel and dentine, bones and sediments in contact, by methods of low-background γ-spectrometry, isotopic dilution and fission-tracks mapping.ESR dating of quaternary Proboscidae, Bovidae, Equidae and Cervidae has been attempted by a new comparative method: the A-line intensity, normalized for the same dose rate and weight, of various fossil dental enamels varies quasi-linearly with the age of the geological sites from which they are issued.     

Calc-alkaline and alkaline miocene and calc-alkaline recent volcanism in the Southernmost Patagonian Cordillera, Chile

In the southernmost Patagonian Cordillera (south of Lat. 54°45′) previously unrecorded calc-alkaline dacites and andesites, and adjacent alkali-basalts, were dated at 21 and 18 Ma (K-Ar), respectively. In the same area post-glacial low-K calc-alkaline andesites, identified at Isla Cook, represent the southernmost Recent volcanism recorded so far in South America, about 400 km south of Monte Burney, previously known as the southernmost Recent volcano. The association of contemporaneous calc-alkaline and alkali volcanics suggests a subduction-related environment for the Miocene volcanism, and the Recent calc-alkaline volcanics indicate that currently there is a small component of subduction of the Antarctic Plate beneath the South American part of the Scotia Plate.     

The oceanic substratum of Northern Luzon: Evidence from xenoliths within Monglo adakite (the Philippines)

Abstract   A 8.65 Ma adakitic intrusive sheet exposed near Monglo village in the Baguio District of Northern Luzon contains a suite of ultramafic and mafic xenoliths including in order of abundance: spinel dunites showing typical mantle-related textures, mineral and bulk rock compositions, and serpentinites derived from them; amphibole-rich gabbros displaying incompatible element patterns similar to those of flat or moderately enriched back-arc basin basalt magmas; and amphibolites derived from metabasalts and/or metagabbros of identical affinity. A single quartz diorite xenolith carrying a similar subduction-related geochemical signature has also been sampled. One amphibolite xenolith provided a whole-rock K–Ar age of 115.6 Ma (Barremian). We attribute the origin of this suite to the sampling by ascending adakitic magmas of a Lower Cretaceous ophiolitic complex located at a depth within the 30–35 km thick Luzon crust. It could represent an equivalent of the Isabela-Aurora and Pugo-Lepanto ophiolitic massifs exposed in Northern Luzon.     

Extreme deuterium enrichment of organic radicals in the Orgueil meteorite: Revisiting the interstellar interpretation?

The insoluble organic matter of the carbonaceous meteorites contains radicals having a polyaromatic structure and a heterogeneous distribution. By using Hyperfine Sublevel Correlation spectroscopy (HYSCORE) in pulsed Electron Paramagnetic Resonance (pulsed-EPR), whereby nuclear frequencies of magnetic nuclei and their hyperfine interaction with electron spin of radicals are detected with high resolution, the radicals are shown to be considerably enriched in deuterium in the Orgueil meteorite, with a D/H ratio of 1.5 ± 0.5 × 10⁻². These radicals hold 3.6 ± 1.2 × 10⁻³ H relative to total organic H.Analysis of hydrogen and deuterium hyperfine interactions indicates that the deuterium atoms are localized in the benzylic position, on aliphatic carbons bonded to aromatic radical moieties. This type of C-H bond exhibits one of the smallest bond energy, reinforcing the recent finding that the lower the C-H bond energy the higher the deuterium-enrichment (Remusat L., Palhol F., Robert F., Derenne S. and France-Lanord C. (2006) Enrichment of deuterium in insoluble organic matter from primitive meteorites: a solar system origin? Earth Planet. Sci. Lett.243, 15-25). Such a behavior is difficult to reconcile with the usual interpretation according to which high D/H ratios represent survivals of interstellar grains. More likely, the deuterium-enrichment process took place after the formation of organic grains whose initial isotopic compositions was close to the protosolar D/H ratio. These grains were possibly loaded at the surface of the protosolar disk where they exposed to the intense solar UV irradiation, triggering an isotopic exchange with deuterium-rich highly reactive ions.     

Syn-extensional intra-plate trachydacite-rhyolitic dome volcanism of the Mesa Central, southern Sierra Madre Occidental volcanic province, Mexico

Oligocene dome complexes of trachydacitic to rhyolitic composition are common in the southern portion of the Mesa Central physiographic province, which forms part of the southern Basin and Range extensional province as well as of the southern Sierra Madre Occidental volcanic province. Generally, dome complexes occur aligned with regional fault systems, mostly associated with the southern Basin and Range province, and thus suggesting that faults controlled the felsic magmas that formed these domes. Two distribution patterns are evident, one aligned NE–SW and another aligned NNE. The set of domes were emplaced at 33–28 Ma. Emplacement of domes occurred in three continuous phases starting with those of trachydacite affinity at 33–32 Ma, to trachydacite–rhyolitic at 32–31 Ma, and finally to those with rhyolitic composition at 31–28 Ma. Felsic magmas that originated the domes were apparently generated by partial melting at the base of the continental crust. Contrary to previous hypothesis, our evidence suggest that these magmas in these particular areas of the Mesa Central were not accumulated in large magma reservoirs emplaced at shallow levels in the crust, but crossed the continental crust directly. Since continental crust in this region is relatively thin (30–33 km), we propose that an intense extensional episode favored the direct ascension of these magmas through the brittle crust, with little interaction with the country rock during ascent to the surface, to end up forming aligned dome chains or complexes. Geochemical data favors this model, as the felsic rocks show no depletions in Nb and Th but instead relatively enrichment in these elements. REE show flat or concave up patterns, suggesting that the magmas involved enriched (fertile), metasomatized lithospheric fluids that generated partial melting at the base of the continental crust. Based upon these data, we infer an intra-plate tectonic setting for these rocks.     

Linear viscoelastic behavior of asphalt mixes from dynamic frequency response functions

In the small strain domain, asphalt mixes (AM) have a linear viscoelastic (LVE) behavior that is strongly dependent on frequency and temperature. The maximum ratio of modulus values can be up to 1000, and traditional elastic analyses are not pertinent. The possibility to characterize AM from frequency response functions (FRFs) was studied. A new optimization process using the finite element method (FEM) has been developed to back-calculate the LVE properties of AM from FRFs. The numerical optimization process was applied to a reference material with averaged LVE properties determined from tension-compression tests performed on a wide variety of AM types. The LVE properties were modeled considering the 3-Dim version of the model 2S2P1D (2 Springs, 2 Parabolic elements, and 1 Dashpot). Reference FRFs for the considered reference material were obtained from FEM simulations. Three different configurations that may be of interest for practical tests were studied at five different temperatures. The proposed numerical optimization method consists in performing separate optimizations at each temperature to obtain the LVE properties for the considered temperature. Then values obtained at each temperature are considered to optimize 2S2P1D and Williams Landel Ferry (WLF) Equation constants to simulate the global LVE behavior of the material. The accuracy of the process was assessed regarding both the calculated FRFs and the complex modulus evaluation. Results indicate that the proposed optimization process converges almost perfectly towards the reference FRFs. The simulated complex modulus values are also in very good agreement with the values of the reference material.     

Active faulting and natural hazards in Armenia, eastern Turkey and northwestern Iran

Active fault zones of Armenia, SE Turkey and NW Iran present a diverse set of interrelated natural hazards. Three regional case studies in this cross-border zone are examined to show how earthquakes interact with other hazards to increase the risk of natural disaster. In northern Armenia, a combination of several natural and man-made phenomena (earthquakes, landslides and unstable dams with toxic wastes) along the Pambak-Sevan-Sunik fault (PSSF) zone lowers from 0.4 to 0.2–0.3g the maximum permissible level (MPL) of seismic hazard that may induce disastrous destruction and loss of life in the adjacent Vanadzor depression.

In the Ararat depression, a large active fault-bounded pull-apart basin at the junction of borders of Armenia, Turkey, Iran and Azerbaijan, an earthquake in 1840 was accompanied by an eruption of Ararat Volcano, lahars, landslides, floods, soil subsidence and liquefaction. The case study demonstrates that natural hazards that are secondary with respect to earthquakes may considerably increase the damage and the casualties and increase the risk associated with the seismic impact.

The North Tabriz–Gailatu fault system poses a high seismic hazard to the border areas of NW Iran, eastern Turkey, Nakhichevan (Azerbaijan) and southern Armenia. Right-lateral strike–slip motions along the North Tabriz fault have given rise to strong earthquakes, which threaten the city of Tabriz with its population of 1.2 million.

The examples illustrate how the concentration of natural hazards in active fault zones increases the risk associated with strong earthquakes in Armenia, eastern Turkey and NW Iran. This generally occurs across the junctions of international borders. Hence, the transboundary character of active faults requires transboundary cooperation in the study and mitigation of the natural risk.