Dissolved Trace Metal–Organic Complexes in the Lot–Garonne River System Determined Using the C18 Sep-Pak System

An 11-month observation of dissolved and particulate organic matter, chlorophyll a(Chl a), C18 Sep-Pak extractable hydrophobic dissolved organic matter (hDOM) fraction and associated dissolved trace metals (Cd, Cu, V, Co, Ni, Mo, U) was performed in the Lot–Garonne River system. This system includes the Riou Mort, the Lot River and the downstream reaches of the Garonne River and represents the fluvial transport path of trace metals between the major point source of polymetallic pollution, located in the Riou Mort watershed and the Gironde estuary. Spatial and temporal variations of dissolved and particulate organic carbon and Chl areflect the presence of different types of organic matter and their relation with the hDOM fraction. Maximum Chl a/POC ratios (up to 0.03), indicate intense phytoplankton production from March to May. In the Lot River (Temple), DOC and POC concentrations were clearly higher and mean Chl a concentration (2.8 mg g⁻¹) was about three times higher than those of the other sites. High Chl a/POC ratios suggest high phytoplankton activity with maxima in spring and late summer. In the Riou Mort River, very high POC concentrations of up to 40 (mean: 20) occurred, whereas Chl a concentrations were relatively low indicating low phytoplankton activity. High, strongly variable DOC and POC concentrations suggest important natural (Carboniferous soils, forests) or anthropogenic (e.g., former coal mines, waste areas, agriculture, sewage) carbon sources within the small Riou Mort watershed. Despite high DOC concentrations in the Riou Mort River, hDOM metal fractions were generally lower than those at the other sites. The general order of decreasing binding strength between metals and the organic hydrophobic phase (Cu, U > Co, Ni > V, Mo > Cd) at all four sites was in good agreement with the Irving–William series of transition element affinity towards organic ligands. Accordingly, the role of the hydrophobic phase in dissolved Cd transport appeared to be negligible, whereas the hDOM–Cu fraction strongly contributed to dissolved Cu transport.     

Observations And Modelling Of The On-Ice And Off-Ice Air Flow Over The Northern Baltic Sea

Two cases of on-ice and off-ice air flow characterizing the opposite weather situations over the ice-edge zone in the northern Baltic Sea are analysed on the basis of aircraft observations, and modelled using atwo-dimensional mesoscale model. The stable boundary layer (SBL) during theon-ice flow exhibited little thermal modification, but a low-level jet (LLJ) was generated at the 250-m high top of the SBL. In the model, the LLJ was associated with inertial oscillations in space, while the baroclinicity explained the shape of the wind profile well above the SBL. Although the observed LLJ was most pronounced over the ice, the modelling suggests that it was not generated by the ice edge but by the coastline some 400 km upwind of the ice edge, where a much more drastic change in the thermal stratification and surface roughness took place. The generation, maintenance, and strength of the LLJ were very sensitive to the parameterization of turbulent mixing in the SBL. In the case of the off-ice flow, the modification of the air mass and the development of a convective boundary layer (CBL) both over the ice and open sea were reasonably well modelled. Sensitivity runs suggested that it was essential to take into account the effects of subgrid-scale leads, a forest in the archipelago (which was crossed by the air flow), and water vapour condensationinto ice crystals. The heat flux from leads was particularly important for the heatbudget of the CBL, and the observed growth of the CBL was partly due to theeffective mixing over the rough and relatively warm forest.     

Geochemistry and Rb–Sr geochronology of a ductile shear zone in the Orlica-Śnieżnik dome (West Sudetes, Poland)

Amphibolite-facies orthogneisses of the Orlica-vnie™nik dome in the West Sudetes (Poland) show a local continuous transition from weakly deformed augen gneisses to finely laminated mylonites. Field evidence indicates that ductile shearing developed pre- or syntectonically to a migmatization event. Bulk-rock compositions of variably deformed samples yield no indications for deformation- and/or fluid-enhanced element mobility and redistribution. ⁸⁷Rb-⁸⁶Sr geochronology (biotite, phengite, whole rock) places time constraints on the deformation process and the post-orogenic cooling history. Phengite- and biotite-whole-rock pairs yield Rb-Sr ages of 340 to 334 Ma and 335 to 294 Ma, respectively, independent of the degree of deformation. The weighted mean of phengite-whole-rock pairs indicates an age of 337.4DŽ.3 Ma. Combining most of the biotite-whole-rock data yields a weighted mean age of 328.6dž.4 Ma. Because of their different closure temperatures for the Rb-Sr system, these differences are interpreted to date cooling after a thermal event. Direct dating of the deformation is not possible, but the cooling history record defines a minimum age for the development of ductile shearing and the last migmatization event. These time constraints provide evidence for the initiation of crustal collapse during or immediately following peak metamorphic conditions. The results of this study further document the importance of Variscan metamorphism in the Orlica-vnie™nik dome.     

Facies partitioning and sequence stratigraphy of cool-water, mixed carbonate-siliciclastic sediments (Upper Miocene Guadalquivir Domain, southern Spain)

During the late Miocene, the Guadalquivir Basin and its satellite basin, the Ronda Basin, were under Atlantic cool-water influence. The aim of our study is to develop a sequence stratigraphic subdivision of the Ronda Basin fill and to provide models for the cool-water carbonates. The Upper Miocene of the Ronda Basin can be divided into three depositional sequences. Sequence 1 is early Tortonian, Sequence 2 late Tortonian to earliest Messinian, and Sequence 3 Messinian in age. The sediments were deposited in a ramp depositional system. Sequence 1 is dominated by conglomerates and marls. In Sequence 2 and Sequence 3, carbonate deposits dominate in the inner ramp whereas siliciclastics preferentially occur in the middle and outer ramp. Bryomol carbonate sediments occur in all sequences whereas rhodalgal carbonates are restricted to Sequence 3. In bays protected from siliciclastic influx, rhodalgal deposits formed under transgressive conditions. A bryomol factory occurs in zones of continuous siliciclastic supply. This distribution results from facies partitioning during the flooding of the Ronda Basin, which has a rugged and irregular relief. Embayments were protected from siliciclastic influx and provided regions with less hydraulic energy.     

Occurrence of naphthalenesulfonates and their condensates with formaldehyde in a landfill leachate and their transport behavior in groundwater of the Upper Rhine Valley, Germany

. Naphthalenesulfonates and their condensation products with formaldehyde are manufactured in the chemical industry for broad application as tanning agents, dispersing agents, and as superplasticizers for concrete. With the disposal of waste they have found their way into the aquatic environment. Five monomeric naphthalenesulfonates and a group of dimeric sulfonated naphthalene-formaldehyde condensates (SNFC) were identified in the leachate and in groundwater observation wells downstream in the plume of the Karlsruhe-West landfill, situated in the Upper Rhine Valley in southwest Germany. For the main monomer of technical SNFC products, 2-naphthalenesulfonate (2-NS), the concentration in the leachate was 170 µg l^–1, which decreased to 9.5 µg l^–1 at a distance of about 300 m from the boundary of the landfill. In the Merdingen tracer test field, the transport of these compounds was studied under more controlled conditions in two tracer experiments with (1) two model compounds, and (2) a technical SNFC product and uranine as a reference tracer. In these experiments, the monomeric naphthalenesulfonates and the SNFC with n=2 behave as conservative tracers. Thus, the findings of the landfill study were supported by these results. Higher molecular SNFC were strongly retarded, which is attributed to adsorption to soil particles. The results of the second tracer experiment suggest a degradation of 2-NS and 2,6-naphthalenedisulfonate (2,6-NDS) after adaptation of the microorganisms in the groundwater aquifer as a consequence of the first tracer experiment.     

On the circulation in the East Frisian Wadden Sea: numerical modeling and data analysis

 In this paper we use a combination of numerical modeling and data analysis to gain a better understanding of the major characteristics of the circulation in the East Frisian Wadden Sea. In particular, we concentrate on the asymmetry of the tidal wave and its modulation in the coastal area, which results in a complex pattern of responses to the sea-level forcing from the North Sea. The numerical simulations are based on the 3-D primitive equation General Estuarine Transport Model (GETM) with a horizontal resolution of 200 m and terrain-following vertical coordinates. The model is forced at its open boundaries with sea-level data from an operational model for the German Bight (German Hydrographic Office). The validation data for our model simulations include time series of tidal gauge data and surface currents measured at a pile in the back-barrier basin of the Island Langeoog, as well as several ADCP transects in the Accumer Ee tidal inlet. Circulation and turbulence characteristics are investigated for typical situations driven by spring and neap tides, and the analysis is focused on dominating temporal and spatial patterns. By investigating the response of five back-barrier basins with rather different morphologies to external forcing, an attempt is made to elucidate the dominating physical balances controlling the circulation in the individual sub-basins. It is demonstrated that the friction at the seabed tends to slow down the tidal signal in the shallow water. This leads to the establishment of flood dominance in the shallow sea north of the barrier islands. South of the islands, where the water volume of the channels at low tide is smaller than the tidal prism, the asymmetry of the tidal signal is shifted towards ebb dominance, a feature which is particularly pronounced at spring tide. At the northern open boundary, the tidal wave propagating from west to east generates a sea-level difference of ∼1 m along the boundary, and thereby triggers vigorous alongshore currents. The frictional control in the model is located in the inlets, as well as along the northern boundary. The correlation between velocity and turbulent kinetic energy tends to the establishment of a net southward transport, giving theoretical support to the observed accumulation of sediments on the intertidal flats. Weak turbulence along the northern shores of the barrier islands and the small magnitude of the residual currents there promote accumulation of suspended matter in these areas, although wave action will generally counteract this effect. Received: 29 May 2002 / Accepted: 26 September 2002 Responsible Editor: Jean-Marie Beckers Acknowledgements We are indebted to S. Dick for providing the data from the operational model of BSH and to B. Flemming for the useful discussions. The topography data and Fig. 1 have been prepared in cooperation with F. Meyer. Figure 2 has been prepared by G. Brink-Spalink. We also thank for the comments from an anonymous reviewer which helped to improve our paper.     

Recent ventifact development on the central Oregon coast,western USA

The unusual location of ventifacts, on a boulder‐built jetty at the mouth of the Siuslaw River, Oregon coast, western USA, allows ventifact age and wind abrasion rates to be estimated with some precision. The jetty was built mainly between 1892–1901 and extended throughout the twentieth century. Consideration of historical shoreline position and the history of jetty construction and repair suggests the ventifacts have formed since about 1930. Morphologically the ventifacts are aligned south‐to‐north reflecting winter winds and sediment transport from the adjacent beach. Wind‐parallel grooves and ridges with sharp, sinuous crests are developed on inclined boulder surfaces on top of the jetty and reflect suspended sand transport in wind vortices. Deeply pitted surfaces on steep boulder surfaces nearest the beach reflect impact by saltating sand grains. Based on present wind regimes (1992–2000) from three regional weather stations, southerly winds above the sand transport threshold occur for 21·9–29·6 per cent of the time. Based on estimated depth of loss from boulder surfaces, wind abrasion rates are calculated to be on the order of 0·24–1·63 mm a^?1. This is the first well‐constrained field estimate of ventifact age and ventifaction rate from a modern coastal environment. Copyright © 2003 John Wiley & Sons, Ltd.