Effect of the contraction of Zn-O bonds on X-ray emission spectra

Physics and Chemistry of Minerals - The X-ray emission spectra were measured for tetrahedrally coordinated Zn ion in several synthetic compounds. Intensity ratios of L β and L α spectral...     

Temporal change in scattering and attenuation associated with the earthquake occurrence—A review of recent studies on coda waves

The study of coda waves has recently attracted increasing attention from seismologists. This is due to the fact that it is viewed as a new means by which the stress accumulation stage preceding a large earthquake can be measured, since the scattering paths nearly uniformly cover a fairly large region around the focus and observation stations, compared with the direct ray paths. To date, we have had many reports on the temporal variation of the relation between coda duration and amplitude magnitude, and that of the coda attenuationQ _c ^–1 which is estimated from coda amplitude decay. Some of these have shown a precursor-like behavior; however, others seem to have shown a coseismic change. We have critically reviewed these reports, and discussed what these observational facts tell us about the change in the heterogeneous crust. We found significant temporal variations, not only in the mean but also in the scatter ofQ _c ^–1 , associated with the mainshock occurrence. The formation of new cracks, the reopening and growing of existing cracks, the interaction of these cracks, and the pore water movement through these cracks might correspond to such variations. In addition, we may expect an inhomogeneous distribution of crack clusters in a fairly large region, compared with the aftershock region. The gradual appearance of such crack clusters seems to be the most plausible mechanism by which coda decay gradients are caused to largely scatter in the stress accumulation stage.     

Discharge of H2 from the Atotsugawa and Ushikubi Faults,Japan, and its relation to earthquakes

The concentration of H₂ in soil gases has been measured weekly at five stations on the Atotsugawa and Ushikubi faults in northern central Main Island, Japan, since 1981 in search of possible relationship with earthquakes. The observed H₂ concentration varies from lower than 1 ppm to 7.8% in time and place. When a large earthquake (M: 7.7, epicenter distance: 486 km) occurred on 26 May 1983, an outstanding discharge of H₂ was observed at all five stations, preseismically at three of them, and coseismically at the other two. Simultaneous H₂ emission was also observed at some stations in seven other occasions. These periods of unusual H₂ discharge nearly coincided with occurrences of major earthquakes in Japan, but not of local minor earthquakes along the Atotsugawa fault. This fault, being a deep fracture zone, may be sensitive to large-scale crustal stress changes which incidentally cause the major earthquakes. Increased H₂ may be produced by rock fracture caused by the increased stresses on the fault and by the earthquakes themselves. Local minor earthquakes along Atotsugawa fault with magnitude lower than 3 may be unable to cause sufficient rock fracture to produce significant H₂.     

Experimental multipole-refined and theoretical charge density study of LiGaSi<Subscript>2</Subscript>O<Subscript>6</Subscript> clinopyroxene at ambient conditions

The synthetic LiGaSi₂O₆ clinopyroxene is monoclinic C2/c at room-T. Its experimental electron density, ρ(r), has been derived starting from accurate room-T single-crystal diffraction data. Topological analysis confirms an intermediate ionic-covalent character for Si–O bonding, as found by previous electron-density studies on other silicates such as diopside, coesite and stishovite. The non-bridging Si–O bonds have more covalent character than the bridging ones. The Ga–O bonds have different bonding characters, the Ga–O2 bond being more covalent than the two Ga–O1 bonds. Li–O bonds are classified as pure closed-shell ionic interactions. Similar to spodumene (LiAlSi₂O₆), Li has sixfold coordination, but the bond critical points associated to the two longest bonds are characterized by very low electron density values. Similar to what previously found in spodumene and diopside, O···O interactions were detected from the topological analysis of ρ(r), and indicate a cooperative interaction among the lone pairs of neighbouring oxygen atoms. In particular, this kind of interaction has been obtained for the O1···O1 edge shared between two Ga octahedra. Integration over the atomic basins gives net charges of −1.39(10), 2.82(10), 1.91(10) and 0.82(8) e for O (averaged), Si, Ga and Li atoms, respectively. Periodic Hartree–Fock and DFT calculations confirm the results obtained by multipole refinement of the experimental data. Moreover, the theoretical topological properties of the electron density distribution on the Si₂O₆ group are very similar to those calculated for spodumene. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Characterization of forests and deforestation in Cambodia using ALOS/PALSAR observation

In this study, we have demonstrated the capability of full polarimetric ALOS/Phased Array L-band Synthetic Aperture Radar data for the characterization of the forests and deforestation in Cambodia, to support climate change mitigation policies of Reducing Emission from Deforestation and Forest Degradation (REDD). We have observed mean backscattering coefficient (σ°), entropy (H), alpha angle (α), anisotropy (A), pedestal height (PH), Radar Vegetation Index (RVI) and Freeman–Durden three-component decomposition parameters. The observations show that the forest types and deforested area are showing variable polarimetric and backscattering properties because of the structural difference. Evergreen forest is characterized by a high value of σ° HV (?12.96 dB) as compared with the deforested area (σ° HV=?22.2 dB). The value of polarimetric parameters such as entropy (0.93), RVI (0.91), PH (0.41) and Freeman–Durden volume scattering (0.43) is high for evergreen forest, whereas deforested area is characterized by the low values of entropy (0.36) and RVI (0.17). Based on these parameters, it is found that σ° HV, entropy, RVI and PH provide best results among other parameters.     

Tsunami deposit associated with the 2011 Tohoku‐oki tsunami in the Hasunuma site of the Kujukuri coastal plain,Japan

We describe the detailed sedimentary characteristics of a tsunami deposit associated with the 2011 Tohoku‐oki tsunami in Hasunuma, a site on the Kujukuri coastal plain, Japan. The thick tsunami deposit was limited to within 350 m from the coastline whereas the inundation area extended about 1 km from the coastline. The tsunami deposit was sampled by excavation at 29 locations along three transects and studied using peels, soft‐X imaging and grain‐size analysis. The deposit covers the pre‐existing soil and reached a maximum measured thickness of 35 cm. It consists mainly of well‐sorted medium to fine sand. On the basis of sedimentary structures and changes in grain size, we divided the tsunami deposit into several sedimentary units, which may correspond to multiple inundation flows. The numbers of units and their sedimentary features vary among the three transects, despite the similar topography. This variation implies a considerable influence of local effects such as elevation, vegetation, microtopography, and distance from footpaths, on the tsunami‐related sedimentation.