Nucleation and crystallization of otavite, witherite, calcite, strontianite, hydrozincite, and hydrocerussite by CO2 membrane diffusion technique

Otavite, witherite, calcite, strontianite, hydrozincite and hydrocerussite nucleation was induced by CO₂ diffusion through a polyethylene membrane into a metal bearing solution. Nucleation and ongoing precipitation was followed at 25 ± 1 °C by the chemical evolution of the solution and the consumption of sodium hydroxide (pH-stat conditions). X-ray diffraction patterns as well as FT-infrared and Raman spectra confirmed the formation of well crystallized solids, except for less crystalline hydrozincite. In several experiments simonkolleite and laurionite precipitated concurrently with hydrozincite and hydrocerussite. The carbonate end-member minerals, smithsonite and cerussite, however were not formed. Carbonate minerals crystallized as spherical aggregates of thin layered otavite, spherical orientated witherite needles, rhombohedral calcite, pseudo-hexagonal strontianite laths, fibrous lumps of hydrozincite and planar hexagonal hydrocerussite crystals. Crystal and aggregate sizes range between 1 and 100 μm. Nucleation occurred at well defined reaction times and distinct critical supersaturation indices (SI_crit). The time for nucleation at constant pH decreased as the initial metal concentration increased for a given solid. The SI_crit values decreased in the order of hydrocerussite (3.2), otavite (2.5), strontianite (1.6), witherite (0.9) and calcite (0.7).     

Present rate of uplift in Fennoscandia from GRACE and absolute gravimetry

Fennoscandia is a key region for studying effects of glacial isostatic adjustment. The associated mass variations can be detected by the Gravity Recovery and Climate Experiment (GRACE) satellite mission, which observes the Earth's gravity field since April 2002, as well as by absolute gravimetry field campaigns. Since 2003, annual absolute gravity (AG) measurements have been performed in Fennoscandia by the Institut für Erdmessung (IfE, Institute of Geodesy) of the Leibniz Universität Hannover, Germany, within a multi-national cooperation. This offers a unique opportunity for validation and evaluation of the GRACE results. In this preliminary study, the GRACE results are compared to secular gravity changes based on the surveys from 2004 to 2007 with the FG5-220 gravimeter of the IfE.The results from GRACE monthly solutions provided by different analysis centres show temporal gravity variations in Fennoscandia. The included secular variations are in good agreement with former studies. The uplift centre is located west of the Bothnian Bay, the whole uplift area comprises Northern Europe. Nevertheless, the differences between the GRACE solutions are larger than expected and the different centre-specific processing techniques have a very strong effect on possible interpretations of GRACE results. The comparison of GRACE to the AG measurements reveals that the determined trends fit well with results from GRACE at selected stations, especially for the solution provided by the GFZ. Variations of land hydrology clearly influence results from GRACE and the AG measurements.     

Flexural isostasy in the Bolivian Andes: Chaco foreland basin development

The Chaco foreland basin was initiated during the late Oligocene as a result of thrusting in the Eastern Cordillera in response to Nazca–South America plate convergence. Foreland basins are the result of the flexural isostatic response of an elastic plate to orogenic and/or thrust sheet loading. We carried out flexural modelling along a W–E profile (21.4°S) to investigate Chaco foreland basin development using new information on ages of foreland basin strata, elastic and sedimentary thicknesses and structural histories. It was possible to reproduce present-day elevation, gravity anomaly, Moho depth, elastic thicknesses, foreland sedimentary thicknesses and the basin geometry. Our model predicted the basin geometry and sedimentary thicknesses for different evolutionary stages. Measured thicknesses and previously proposed depozones were compared with our predictions. Our results shed more light on the Chaco foreland basin evolution and suggest that an apparent decrease in elastic thickness beneath the Eastern Cordillera and the Interandean Zone could have occurred between 14 and 6 Ma.     

N-body integrators with individual time steps from Hierarchical splitting

We review the implementation of individual particle time-stepping for N-body dynamics. We present a class of integrators derived from second order Hamiltonian splitting. In contrast to the usual implementation of individual time-stepping, these integrators are momentum conserving and show excellent energy conservation in conjunction with a symmetrized time step criterion. We use an explicit but approximate formula for the time symmetrization that is compatible with the use of individual time steps. No iterative scheme is necessary. We implement these ideas in the HUAYNO¹ code and present tests of the integrators and show that the presented integration schemes shows good energy conservation, with little or no systematic drift, while conserving momentum and angular momentum to machine precision for long term integrations.     

GETEMME—a mission to explore the Martian satellites and the fundamentals of solar system physics

GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.     

CoRoT/ESTA–TASK 1 and TASK 3 comparison of the internal structure and seismic properties of representative stellar models

We compare stellar models produced by different stellar evolution codes for the CoRoT/ESTA project, comparing their global quantities, their physical structure, and their oscillation properties. We discuss the differences between models and identify the underlying reasons for these differences. The stellar models are representative of potential CoRoT targets. Overall we find very good agreement between the five different codes, but with some significant deviations. We find noticeable discrepancies (though still at the per cent level) that result from the handling of the equation of state, of the opacities and of the convective boundaries. The results of our work will be helpful in interpreting future asteroseismology results from CoRoT.     

APEX and ATCA observations of the southern hot core G327.3-0.6 and its environs

There is no generally accepted evolutionary scheme for high mass star formation yet. A simple approach to address this problem is to cover several of the known stages during the formation of massive stars in the same cloud and then investigate their properties trying to construct an evolutionary sequence. Here we present such a project conducted with complementary APEX and ATCA observations. These observations show a compact and bright single hot core in the G327.3-0.6 region on a 0.03 pc scale with a mass of 500 M_⊙ and 0.5–1.5 10⁵ L_⊙. Additionally a clumpy filament is seen in N₂H⁺. Together with cm continuum observations, the data reveal like pearls on a string several stages of massive star formation, with likely the youngest stages hiding in the cold N₂H⁺ cores analysed with a multilevel study of the APEX and ATCA observations.     

Geysers of Enceladus: Quantitative analysis of qualitative models

Aspects of two qualitative models of Enceladus’ dust plume—the so-called “Cold Faithful” [Porco, C.C., et al., 2006. Cassini observes the active south pole of Enceladus. Science 311, 1393-1401; Ingersoll, A.P., et al., 2006. Models of the Enceladus plumes. In: Bulletin of the American Astronomical Society, vol. 38, p. 508] and “Frigid Faithful” [Kieffer, S.W., et al., 2006. A clathrate reservoir hypothesis for Enceladus’ south polar plume. Science 314, 1764; Gioia, G., et al., 2007. Unified model of tectonics and heat transport in a Frigid Enceladus. Proc. Natl. Acad. Sci. 104, 13578-13591] models—are analyzed quantitatively. The former model assumes an explosive boiling of subsurface liquid water, when pressure exerted by the ice crust is suddenly released due to an opening crack. In the latter model the existence of a deep shell of clathrates below Enceladus’ south pole is conjectured; clathrates can decompose explosively when exposed to vacuum through a fracture in the outer icy shell. For the Cold Faithful model we estimate the maximal velocity of ice grains, originating from water splashing in explosive boiling. We find that for water near the triple point this velocity is far too small to explain the observed plume properties. For the Frigid Faithful model we consider the problem of momentum transfer from gas to ice particles. It arises since any change in the direction of the gas flow in the cracks of the shell requires re-acceleration of the entrained grains. While this effect may explain the observed speed difference of gas and grains if the gas evaporates from triple point temperature (273.15 K) [Schmidt, J., et al., 2008. Formation of Enceladus dust plume. Nature 451, 685], the low temperatures of the Frigid Faithful model imply a too dilute vapor to support the observed high particle fluxes in Enceladus’ plume.