吉尔吉斯马克马尔金矿床地质特征及其意义

马克马尔大型金矿床位于吉尔吉斯中天山造山带,属中-酸性侵入体接触交代型金矿床。新疆是中-酸性侵入岩分布广泛地区,目前已发现多处金矿床或矿点分布于中-酸性侵入体内或外接触带。新疆具备这类金矿床的成矿条件和找矿远景,并已找到多纳拉萨依等多个该类型金矿,但目前该类型金矿产地不多,规模不大,笔者通过对马克马尔接触交代型金矿床地质特征的总结,以期对新疆地区该类型金矿床的查找有所帮助。     

内蒙古东乌旗达勒廷查干矿区成矿特征及成因类型浅析

内蒙古东乌旗达勒廷查干矿区位于宝格达山西南约70km处,是近两年以地、物、化、工程综合方法新发现的铅锌银多金属矿产地.矿区地处西伯利亚板块东南缘,考虑到其所处成矿环境,研究其成矿特征及成因类型,不论是对于矿区本身后续阶段的勘查,还是对邻区的矿产勘查以及成矿区带的研究均具有借鉴意义.     

彬长矿区煤层气储层参数及开发潜力

彬长矿区煤的变质程度低,矿井瓦斯涌出量大,瓦斯治理形势日趋严峻。根据矿区地质勘查、井下及煤层气井所获得的地质资料显示,煤层气开发的主要目标4煤层厚度大,分布稳定,煤体结构好,渗透率和气含量相对较高,气含量最高可达6.29m3/t,估算煤层气资源量为132.743×108m3。依据煤层气资源丰度划分,矿区煤层气富集区总面积为87.41km2,资源量为40.06×108m3,主要分布在大佛寺井田,相对富集区主要位于胡家河井田中南部和孟村井田东部,贫气区主要位于孟村井田西部、文家坡井田。综合分析认为研究区煤层气开发地质条件相对较好,属于可以抽采煤层,大佛寺井田为地面煤层气勘探开发最具潜力的地区。     

Investigating soil thermodynamic parameters of the active layer on the northern Qinghai-Tibetan Plateau

The soil thermodynamic parameters, including thermal conductivity, diffusivity and volumetric capacity within the active layer on the northern Tibetan Plateau, were calculated using the measured data of soil temperature gradient, heat flux, and moisture at four stations from October 2003 to September 2004. The results showed that the soil thermodynamic parameters exhibited clear seasonal fluctuation. The thermal conductivity and diffusivity in summer and autumn at Beiluhe, Kexinling, and Tongtianhe were larger than those in winter. The volumetric thermal capacity causes an opposite change; it was larger in autumn and winter than in summer. In spring, the soil thermal conductivity at the Kekexili station was larger than that in summer. Generally, fine-grained soils and lower saturation degrees in the topsoil might be a reason for the lower soil thermal conductivity in winter. For a given soil, soil moisture was the main factor influencing the thermodynamic parameters. The unfrozen water content that existed in frozen soils greatly affected the soil thermal conductivity, whose contribution rate was estimated to be 55 %. The thermodynamic parameters of frozen soils could be expressed as a function of soil temperature, volumetric ice content and soil salinity, while for the unfrozen ground the soil moisture content is the dominant factor for those thermal parameters. As for the soil thermal diffusivity, there exists a critical value of soil moisture content. When the soil moisture content becomes less than a critical value, the soil thermal diffusivity increases as the soil moisture content rises.     

Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

重庆涪陵页岩气勘查开发区环境地质调查进展

紧密结合国家非常规能源勘探开发的重大战略,聚焦重庆涪陵页岩气勘查开发区环境地质调查工作,总结了研究区岩溶发育特征与分布规律,评价了涪陵页岩气开发区区域水资源量和地下水质量。在此基础上,收集分析国内外资料,梳理了页岩气勘查开发所引发的6类环境(地质)问题及勘查、钻井、压裂、开采、闭井等5个阶段需关注的地质环境问题或风险等,其中涪陵页岩气勘查开发区主要诱发水土污染、地质灾害和大气污染等环境(地质)问题; 基本识别了2种地下水污染模式、3种污染类型及可能的地下水污染风险途径; 初步确定了涪陵页岩气勘查开发区污染指示性特征因子,并形成了页岩气勘查开发区地质环境影响评价指标体系,可指导页岩气勘查开发的环境地质调查。该研究为页岩气国家新型清洁能源的绿色开发和开发区生态文明建设提供支撑。     

敞开酸溶-电感耦合等离子体质谱法同时测定钨矿石和锡矿石中14种微量元素

钨矿石和锡矿石成分复杂,具有丰富的共生或伴生元素。在国家标准方法中,对其中的微量共生或伴生元素含量多采用单元素测定,分析强度大,效率低。本文采用混合酸在敞开体系中消解样品,以50%盐酸提取盐类,电感耦合等离子体质谱仪(ICP-MS)同时测定钨矿石和锡矿石中的锂钪铬钴镍铜铅锌铷钼铯锑铋钍等14种微量元素。通过比较碱熔法、盐酸+氢氟酸+硝酸+高氯酸四酸溶矿法、氢氟酸+硝酸+高氯酸三酸溶矿法这三种样品前处理方法,确定选择使用氢氟酸+硝酸+高氯酸三酸溶矿法溶解样品。ICPMS测定过程中,选择铑和铼作为内标元素,有效监控分析信号的漂移。测定结果表明,各元素的检出限为0.003~1.64μg/g,相对标准偏差在0.1%~3.1%,方法回收率在93.1%~104.3%。方法应用于实际钨矿石和锡矿石分析,测定结果与各元素标准测定值吻合较好。相对于传统处理方法,本法一次溶样,多元素同时测定,使分析效率得到了有效提高,更适合大批量多元素钨矿石和锡矿石样品的分析。     

青海西部尕斯库勒盐湖沉积物中铀和钍地球化学特征探讨

文章以柴达木盆地西部尕斯库勒盐湖沉积物为研究对象,通过对钻孔沉积物和地表沉积物中铀和钍含量的研究,探讨了盐湖沉积物中铀和钍的地球化学特征。分析表明,钻孔沉积物中铀和钍之间存在明显的正相关关系。在横向上,随地表取样点逐渐远离湖表卤水,沉积物中铀和钍的含量先增高后又急剧降低,且受补给水铀含量影响大;在纵向上,同一个晶间卤水层或者碎屑物沉积层内铀含量垂直分异明显,铀含量随深度增加而递增。就沉积物中铀和钍的赋存形式而言,2/3的铀被黏土质点吸附,1/3的铀夹杂在盐类矿物中;而90%以上的钍被黏土质点吸附,10%以下的钍夹杂在盐类矿物中。干盐滩中毛细蒸发和淋滤等化学沉积分异作用造成盐湖沉积中心的沉积物铀含量相对较高。     

皖赣两省地质公园造景花岗岩的岩石特征、形成时代及景观成因

皖赣两省气候宜人,旅游资源丰富。黄山、三清山、天柱山、九华山、牯牛降等地质公园更是以独特的花岗岩地貌景观闻名于世。通过对地质公园内造景花岗岩进行年代学、岩石学、地球化学等方面的研究,证明上述地质公园内的花岗岩集中形成于135~125 Ma,属于早白垩世强烈岩浆活动的产物。这些花岗岩高硅、富碱、过铝,轻重稀土分馏不明显,Eu强烈亏损,稀土配分曲线呈海鸥型;强烈亏损Ba、Sr、P、Ti,形成四个明显的凹槽,具有造山后铝质A型花岗岩的岩石地化特征,属于铝质A型花岗岩或者高分异花岗岩。上述花岗岩主要形成于造山后伸展的构造背景。该构造背景下产出的花岗岩以浅色矿物为主,暗色矿物含量稀少,抗风化蚀变能力更佳;并具有多组密集的原生节理,对花岗岩地貌景观的形成起着极其重要的控制作用。     

大兴安岭北段塔源地区~330Ma变辉长岩-花岗岩的岩石成因及构造意义

大兴安岭北段塔源地区石炭纪侵入岩分布于中亚造山带东段,构造上位于额尔古纳-兴安地块拼合处。发育岩体由变辉长岩和花岗岩组成,它们在时空上紧密伴生,变辉长岩中的锆石CL图像呈典型条带状,弱环状结构或面状结构(Th/U值为0.15~1.09,平均0.66),Th和U具有正相关关系;花岗岩的锆石CL图像呈明显岩浆型振荡环带特征(Th/U为值0.22~4.54,平均为1.95)。LA-ICP-MS锆石U-Pb测年指示两者侵位年龄分别为331.0±2.6Ma和329.4±2.4Ma,表明形成于同一构造岩浆作用事件。岩石学和地球化学特征显示它们成因上密切相关,SiO2含量呈双峰式。塔源变辉长岩为中钾钙碱性系列,MgO含量较低(5.41%~6.45%),属于演化岩浆,TiO2、FeOT和P2O5含量较高,富集LREE,Eu异常不明显(δEu=0.71~0.90),稀土元素总量和轻重稀土元素的分馏程度较高(La/Sm=4.61~5.84,Gd/Yb=2.50~2.81),Ti/V、Ti/Y、Zr/Y比值较低,富集大离子亲石元素(LILE)而亏损高场强元素(HFSE),尤其是强烈亏损Nb,形成于板内构造环境。花岗岩以TiO2、FeOT和P2O5含量较低为特征,REE配分模式为LREE富集型,其中花岗岩为Eu弱负异常(δEu=0.76~0.92),微量元素蛛网图上类似于A型花岗岩分配模式。不相容元素(如La/Sm、La/Ta、Th/Ta)以及MgO含量等指示原始岩浆受到地壳混染比例较小,以分离结晶作用为主。塔源变辉长岩还显示岩石圈地幔物质的印记,并与石榴石二辉橄榄岩熔融有关,它们被解释成早期地幔源区曾发生过俯冲流体交代。变辉长岩和花岗岩由不同源区熔融形成,基性岩源于受到陆壳混染比例较小的原始地幔,而花岗岩可能来自底侵作用,基性岩浆使其上部地壳发生大规模的部分熔融形成大面积花岗岩。大兴安岭塔源侵入岩的形成是岩石圈伸展减薄背景下玄武质岩浆底侵作用的结果。