A photochemical model of the martian atmosphere

The factors governing the amounts of CO, O2, and O3 in the martian atmosphere are investigated using a minimally constrained, one-dimensional photochemical model. We find that the incorporation of temperature-dependent CO2 absorption cross sections leads to an enhancement in the water photolysis rate, increasing the abundance of OH radicals to the point where the model CO abundance is smaller than observed. Good agreement between models and observations of CO, O2, O3, and the escape flux of atomic hydrogen can be achieved, using only gas-phase chemistry, by varying the recommended rate constants for the reactions CO + OH and OH + HO2 within their specified uncertainties. Similar revisions have been suggested to resolve discrepancies between models and observations of the terrestrial mesosphere. The oxygen escape flux plays a key role in the oxygen budget on Mars; as inferred from the observed atomic hydrogen escape, it is much larger than recent calculations of the exospheric escape rate for oxygen. Weathering of the surface may account for the imbalance. Quantification of the escape rates of oxygen and hydrogen from Mars is a worthwhile objective for an upcoming martian upper atmospheric mission. We also consider the possibility that HOx radicals may be catalytically destroyed on dust grains suspended in the atmosphere. Good agreement with the observed CO mixing ratio can be achieved via this mechanism, but the resulting ozone column is much higher than the observed quantity. We feel that there is no need at this time to invoke heterogeneous processes to reconcile models and observations.     

鲁23井“动水位”观测的分析

本文介绍了鲁23井“动水位”观测情况。提出了一个分析有泄流的“动水位”的新方法,即把流量换算成水位,以等效静水位来表示“动水位”与流量。由于把“动水位”与流量用一个量来计算,从而为“动水位”观测定量的、统一的分析研究提供了新的方法。这对提高“动水位”井的监测预报地震能力起一定的作用。 本文还以鲁23井“动水位”观测资料为例,利用新方法进行处理的观测分析结果与理论研究结果是一致的。     

浙东晚白垩世小雄破火山中火山-侵入杂岩的岩石成因

破火山内出露的火山岩与浅成侵入岩为硅质岩浆演化研究提供了一个重要窗口，从而备受关注。小雄破火山内的火山-侵入杂岩是中国东南沿海晚白垩世岩浆活动的典型代表，包括小雄组火山岩（K₂x）与两类侵入岩（花岗斑岩、正长斑岩）。本文以小雄火山-侵入杂岩为研究对象，开展了系统的锆石U-Pb年代学、岩石学和地球化学研究，旨在深入探讨破火山内火山岩与侵入岩之间的成因联系和岩浆演化过程。系统的LA-ICP-MS 锆石U-Pb年代学研究表明，小雄组火山岩形成于98~88Ma，并具有多期次喷发的特点，可分为下段、中段和上段，年龄分别为98~96Ma（K₂x¹）、95~92Ma（K₂x²）、~ 88Ma（K₂x³）。小雄花岗斑岩形成年龄为90Ma；正长斑岩形成稍晚，约88Ma。与下段流纹质玻屑凝灰岩的Nd-Hf同位素组成[ε_Nd（t）=-8.3~-7.2， ε_Hf（t）=-11.8~-7.2]相比，中段流纹岩要更为亏损[ε_Nd（t）=-5.84~-5.32， ε_Hf（t）=-10.1~-0.5]。研究表明，小雄组流纹质火山岩的母岩浆可能起源于发生在深部岩浆房中渐进的壳幔相互作用，中段流纹岩的源区混入了更多的亏损幔源组分。中段流纹岩与花岗斑岩具有相似的Nd-Hf同位素组成，以及 "互补"的微量元素地球化学特征，由发生在浅部岩浆房的分离结晶作用和堆晶作用所制约。值得注意的是，正长斑岩与花岗斑岩并不存在直接的成因演化关系，两者应是不同的起源。不同的正长斑岩岩株具有高度一致的结晶年龄、微量元素特征以及Nd-Hf同位素组成，以上特征均表明小雄破火山内的正长斑岩具有相同的起源。正长斑岩母岩浆起源于富集岩石圈地幔的部分熔融，岩浆源区混入了来自亏损的软流圈地幔组分，其地球化学成分变化主要受"普通辉石+磷灰石+钛铁矿"的分离结晶所控制。     

Evidence of ancient life at 207 m depth in a granitic aquifer

The results of electron-microscopy investigations of calcite precipitated in a water-conducting fracture in a ca. 1800 Ma granitic rock from 207 m below sea level at the island of Aspo on the southeastern (Baltic) coast of Sweden are compared with measurements of carbon, oxygen, and sulfur isotope composition of the calcite and embedded pyrite. Parts of the calcite had extremely low delta 13C values, indicative of biological activity, and contained bacteria-like microfossils occurring in colonies and as typical biofllms. X-ray microanalysis demonstrated these fossils to be enriched in carbon. Our results provide evidence for ancient life in deep granitic rock aquifers and suggest that the modern microbial life found there is intrinsic. Modeling historical and present geochemical processes in deep granitic aquifers should, therefore, preferably include biologically catalyzed reactions. The results also suggest that the search for life on other planets, e.g., Mars, should include subsurface material.     

矿物标型六性及其在胶东金矿中的应用

目前矿物标型研究和应用已进入一个新的阶段。作者从哲学的高度,把国内外矿物标型特征的分散研究加以集中概括和总结,提出了“矿物标型六性”的普遍规律,即普遍性、特殊性、变化性、相应性、继承性和分带性,对矿物标型特征研究具重要的指导意义。这些规律在胶东金矿中得到广泛应用,并已取得良好效果。     

中国三个大地震的震源参数及讨论

大地震的震源机制及地震矩、应力降等参数,不(又对认识地震的破裂过程,而且对预报强地面运动都是非常重要的。一些文章对板内地震应力降的特点、地震矩与高频源谱的关系及区域特征的讨论,使我们可直接由长周期体波或面波得出的地震矩M₀估计出不同地区中大地震的高频源谱,以供强地面运动预报参考。 由于对发生在中国板内的1976年11月6日盐源地震（M_s=6.5）和1976年11月15日宁河地震（M_s=6.3）的震源参数还没有详尽的报道;另外,对1973年7月14日     

张家口市湿地资源现状、问题与保护对策

张家口地区有丰富的湿地资源,张家口的河流、湖淖等湿地对京津地区的水资源供应与调节、生物多样性保护、生态环境的平衡与区域可持续发展关系重大,本文对该区域主要湿地现状、导致其退化的主要原因与问题进行了探讨,并提出了当前湿地保护的建议与对策。     

Improved reliability in the interpretation of geochemical measurements by the quantification of uncertainty from sampling

All geochemical measurements require the taking of field samples, but the uncertainty that this process causes is often ignored when assessing the reliability of the interpretation, of the geochemistry or the health implications. Recently devised methods for the estimation, optimisation and reduction of this uncertainty have been evaluated by their application to the investigation of contaminated land. Uncertainty of measurement caused by primary sampling has been estimated for a range of six different contaminated land site investigations, using an increasingly recognized procedure. These site investigations were selected to reflect a wide range of different sizes, contaminants （organic and metals）, previous land uses （e.g. tin mining, railway sidings and gas works）, intended future use （housing to nature reserves） and routinely applied sampling methods. The results showed that the uncertainty on measurements was substantial, ranging from 25% to 186% of the concentration values at the different sites. Sampling was identified as the dominant source of the uncertainty （〉70% of measurement uncertainty） in most cases. The fitness-for-purpose of the measurements was judged using the optimized contaminated land investigation （OCLI） method. This identifies the optimal level of uncertainty that reduces to overall financial loss caused by the measurement procedures and the misclassification of the contamination, caused by the uncertainty. Generally the uncertainty of the actual measurements made in these different site investigations was found to be sub-optimal, and too large by a factor of approximately two. The uncertainty is usually limited by the sampling, but this can be reduced by increasing the sample mass by a factor of 4 （predicted by sampling theory）. It is concluded that knowing the value of the uncertainty enables the interpretation to be made more reliable, and that sampling is the main factor limiting most investigations. This new approach quantifies this problem for the first time, and allows sampling procedures to be critically evaluated, and modified, to improve the reliability of the geochemical assessment.