Paleomagnetic investigations of the tertiary and quaternary rocks: IX The pliocene of southeast Sicily and some Cretaceous rocks from Capo Passero

A sampling of Plio-Pleistocene and Upper Cretaceous basalts in SE Sicily yielded the following informationAssuming that the Cretaceous direction is reversed, the confidence oval for the virtual pole overlaps that for the Cretaceous pole of Africa determined from the Mlanje Syenite byMcElhinny et al. If SE Sicily was attached to Africa when these Upper Cretaceous lavas erupted, this result implies that extensive relative movement between the two is not likely to have occurred subsequently.

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Zusammenfassung Die Aufsammlung und Untersuchung plio-pleistozäner und oberkretazischer Basalte in SE-Sizilien ergab die folgende paläomagnetische InformationUnter der Annahme einer inversen kretazischen Feld-Richtung überlappt der Konfidenzkreis des virtuellen Pols den kretazischen magnetischen Pol für Afrika, der vonMcElhinny et al. an den Gesteinen des Mlanje Syenites bestimmt wurde.Wenn SE-Sizilien zur Zeit der Extrusion dieser oberkretazischen Laven an Afrika angeheftet war, dann besagt dieses Ergebnis, da\ eine extensive relative Bewegung zwischen diesen beiden schwerlich nacheinander stattgefunden hat.

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Résumé La compilation et l'analyse de basaltes d'âge plio-pleistocène et crétacique supérieur dans la SE-Sicile fournit l'information paléomagnétique suivanteDans l'acceptation d'un champ inversé au Crétacique, le cercle de confidence du pÔle virtuel recouvre le pÔle magnétique crétacique pour l'Afrique, tel queMcElhinny et al. l'ont déduit des roches de la Syénite de Mlanje. Si l'on rattache le SE de la Sicile à l'Afrique au moment de l'éruption de ces laves du Crétacique supérieur, ce résultat signifie qu'il est peu probable qu'un mouvement relatif extensif ait eu lieu entre les deux.

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Multi‐proxy constraints on the significance of covariant δ13C values in carbonate and organic carbon during the early Mississippian

This study investigates the covariation between carbonate and organic δ¹³C values in a proximal to distal transect of four outcrops in the Madison Limestone in the Western United States Rockies, combined with δ³⁴S values of carbonate associated sulphate, the concentration of acid‐insoluble material and measurements of total organic carbon. These new geochemical datasets not only allow for an evaluation of carbon isotope covariance during one of the largest perturbations to the global carbon cycle over the past 550 Myr, but also constrain the cause of the excursion in carbonate δ¹³C values. The results support the hypothesis that a period of anoxia did not play a role in generating the positive carbonate δ¹³C values, but rather favour interpretations by previous workers that the proliferation of land plants destabilized the Carboniferous carbon cycle, setting the stage for a significant change in the carbonate δ¹³C values of contemporaneous marine carbonates. These results also demonstrate that one of the largest perturbations to the global carbon cycle did not produce synchronous variations in carbonate and organic δ¹³C values, emphasizing the importance of local depositional controls on carbon isotope covariance in the geological record in both modern and ancient environments.     

Characteristics of modern carbonate contourite drifts

Carbonate environments inhabit the realm of the surface, intermediate and deep currents of the ocean circulation where they produce and continuously deliver material which is potentially deposited into contourite drifts. In the tropical realm, fine‐grained particles produced in shallow water and transported off‐bank by tidal, wind‐driven, and cascading density currents are a major source for transport and deposition by currents. Sediment production is especially high during interglacial times when sea level is high and is greatly reduced during glacial times of sea‐level lowstands. Reduced sedimentation on carbonate contourite drifts leads to early marine cementation and hardened surfaces, which are often reworked when current strength increases. As a result, reworked lithoclasts are a common component in carbonate drifts. In areas of temperate and cool water carbonates, currents are able to flow across carbonate producing areas and incorporate sediment directly to the current. The entrained skeletal carbonate particles have variable bulk density and shapes that lower the prediction of transport rates in energy‐based transport models, as well as prediction of current velocity based on grain size. All types of contourite drifts known in clastic environments are found in carbonate environments, but three additional drift types occur in carbonates because of local sources and current flow diversion in the complicated topography inherent to carbonate systems. The periplatform drift is a carbonate‐specific plastered drift that is nearly exclusively made of periplatform ooze. Its geometry is built by the interaction of along‐slope currents and downslope currents, which deliver sediment from the adjacent shallow‐water carbonate realm to the contour current via a line source. Because the periplatform drift is plastered on the slopes of the platforms it is also subject to mass gravity flow and large slope failures. At platform edges, a special type of patch drift develops. These hemiconal platform‐edge drifts also contain exclusively periplatform ooze but their geometry is controlled by the current around the corner of the platform. At the north‐western end of Little and Great Bahama Bank are platform‐edge drifts that are over 100 km long and up to 600 m thick. A special type of channel‐related drift forms when passages between carbonate buildups or channels within a platform open into deeper water. A current flowing in these channels will entrain material shed from the sediment producing areas. At the channel mouth, the sediment‐charged current deposits its sediment load into the deeper basin. With continuous flow, a submarine delta drift is built that progrades into the deep water. The strongly focused current forming the delta drift, is able to rework coarse skeletal grains and clasts, making this type of carbonate drift the coarsest drift type.     

Decadal windstorm activity in the North Atlantic-European sector and its relationship to the meridional overturning circulation in an ensemble of simulations with a coupled climate model

The relationship between decadal variations in the North Atlantic meridional overturning circulation (MOC) and North Atlantic/Western European windstorm activity during the extended winter season is studied. According to an ensemble of three 240-year long simulations performed with the ECHAM5-MPIOM model, periods of high decadal windstorm activity frequently occur in the years following a phase of weak MOC (i.e. when the MOC starts to recover). These periods are characterised by a distinctive pattern in the mixed layer ocean heat content (OHC). A positive anomaly is located in the region 45°N?52°N/35°W?16°W (west of France). Negative anomalies are located to the North and South. The signal can be detected both in the heat content of the oceanic mixed layer and in the sea surface temperatures. Its structure is consistent with anomalously enhanced baroclinic instability in the region with the strong negative OHC gradient (30°W?10°W/45°N?60°N), which eventually produces a higher probability of windstorms.     

Multi-stage Ag–Bi–Co–Ni–U and Cu–Bi vein mineralization at Wittichen,Schwarzwald, SW Germany: geological setting,ore mineralogy,and fluid evolution

The Wittichen Co–Ag–Bi–U mining area (Schwarzwald ore district, SW Germany) hosts several unconformity-related vein-type mineralizations within Variscan leucogranite and Permian to Triassic redbeds. The multistage mineralization formed at the intersection of two fault systems in the last 250 Ma. A Permo-Triassic ore stage I with minor U–Bi–quartz–fluorite mineralization is followed by a Jurassic to Cretaceous ore stage II with the main Ag and Co mineralization consisting of several generations of gangue minerals that host the sub-stages of U–Bi, Bi–Ag, Ni–As–Bi and Co–As–Bi. Important ore minerals are native elements, Co and Ni arsenides, and pitchblende; sulphides are absent. The Miocene ore stage III comprises barite with the Cu–Bi sulfosalts emplectite, wittichenite and aikinite, and the sulphides anilite and djurleite besides native Bi, chalcopyrite, sphalerite, galena and tennantite. The mineral-forming fluid system changed from low salinity (<5 wt.% NaCl) at high temperature (around 300°C) in Permian to highly saline (around 25 wt.% NaCl + CaCl₂) at lower temperatures (50–150°C) in Triassic to Cretaceous times. Thermodynamic calculations and comparison with similar mineralizations worldwide show that the Mesozoic ore-forming fluid was alkaline with redox conditions above the hematite–magnetite buffer. We suggest that the precipitation mechanism for native elements, pitchblende and arsenides is a decrease in pH during fluid mixing processes. REE patterns in fluorite and the occurrence of Bi in all stages suggest a granitic source of some ore-forming elements, whereas, e.g. Ag, Co and Ni probably have been leached from the redbeds. The greater importance of Cu and isotope data indicates that the Miocene ore stage III is more influenced by fluids from the overlying redbeds and limestones than the earlier mineralization stages.