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91.
A non-linear three-dimensional unstructured grid model of the M2 tide in the shelf edge area off the west coast of Scotland is used to examine the spatial distribution of the M2 internal tide and its higher harmonics in the region. In addition, the spatial variability of the tidally induced turbulent kinetic energy and associated mixing in the area are considered. Initial calculations involve only tidal forcing, although subsequent calculations are performed with up-welling and down-welling favourable winds to examine how these influence the tidal distribution (particularly the higher harmonics) and mixing in the region. Both short- and long-duration winds are used in these calculations. Tidal calculations show that there is significant small-scale spatial variability particularly in the higher harmonics of the internal tide in the region. In addition, turbulence energy and mixing exhibit appreciable spatial variability in regions of rapidly changing topography, with increased mixing occurring above seamounts. Wind effects significantly change the distribution of the M2 internal tide and its higher harmonics, with appreciable differences found between up- and down-welling winds and long- and short-duration winds because of differences in mixing and the presence of wind-induced flows. The implications for model validation, particularly in terms of energy transfer to higher harmonics, and mixing are briefly discussed.  相似文献   
92.

H2 photoproduction and nitrogenase activities in two strains ofAnabaena variabilis marked wild type ATCC 29413 and mutant PK84 exposed to thermal stress (temperature higher than the normal incubation temperature of 30°C) were studied. Cultures of both strains collected from any interval of logarithmic growth phase exhibited high H2 photoproduction and nitrogenase activities when exposed to limited time heat shock during the assay process. In contrast, the algal H2 photoproduction rate of both strains fluctuated with long term thermal stress caused by increasing the growth temperature from 30°C to 36°C.

The changes of nitrogenase (the key H2 photobiosynthetic enzyme) activities in the mutant PK84 showed variation tendency similar to that of H2 photoproduction during exposure to thermal stress, indicating that fluctuation of H2 photoproduction in the mutant was mainly due to the variation of nitrogenase activities. A temporary maximal H2 photoproduction in the mutant PK84 (wild type ATCC29413) was observed when cells grew at 36°C for 14 (6) days. However, the responses of nitrogenase activities in the wild type to thermal stress were not completely similar to those in the mutant in spite of similar variations of H2 photoproduction in both strains. The data obtained in these studies suggested that the activities of other enzymes (in the wild strain) involved in H2 photoproduction were affected by thermal stress since H2 photoproduction maximized or dropped to 0 without variation tendency similar to that of nitrogenase activities.

Furthermore, an enhancement of H2 photoproduction speed of the mutant strain cultured in a 4.4 L laboratory photobioreactor was also observed when it was subjected to short time continuous charge of argon, and temperature rise.

All these results indicated that high temperature plays an important role in the photo-autotrophic H2 photoproduction, and that long term thermal stress is unfavourable for net H2 photoproduction in both strains ofA. variabilis though short-time heat shock is conducive to H2 photoproduction.

  相似文献   
93.
Analytical perspective on trace element species of interest in exploration   总被引:1,自引:0,他引:1  
Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH2OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH2OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.  相似文献   
94.
95.
Geologic relationships in the central Pyrenees of southern France demonstrate that lherzolite has been emplaced, as a plastic solid, into middle or upper Cretaceous calcareous rocks; that it has been eroded and clastic peridotite debris deposited in rocks of approximately the same age as those it intruded; and that it has also been juxtaposed against Cretaceous limestone or marble along or within the North Pyrenean fault zone. There are at least three types of late Cretaceous lherzolite breccias known from this region.Metamorphism of the country rock and penetrative deformation of the lherzolite and marble took place during shearing. Shearing was accompanied by an important period of motion (perhaps 85–100 m.y. ago) along the North Pyrenean fault and an associated thermal event which involved temperatures of 400 ± 100°C. Cretaceous metamorphism along the North Pyrenean fault zone was not due to forcible primary hot intrusion of lherzolite.  相似文献   
96.
During the AIDJEX Main Experiment, April 1975 through May 1976, a comprehensive microwave sensing program was performed on the sea ice of the Beaufort Sea. Surface and aircraft measurements were obtained during all seasons using a wide variety of active and passive microwave sensors. The surface program obtained passive microwave measurements of various ice types using four antennas mounted on a tracked vehicle. In three test regions, each with an area of approximately 1.5 × 104 m2, detailed ice crystallographic, dielectric properties, and brightness temperatures of first-year, multiyear, and first-year/multiyear mixtures were measured. A NASA aircraft obtained passive microwave measurements of the entire area of the AIDJEX manned station array (triangle) during each of 18 flights. This verified the earlier reported ability to distinguish first-year and multiyear ice types and concentration and gave new information on ways to observe ice mixtures and thin ice types. The active microwave measurements from aircraft included those from an X- and L-band radar and from a scatterometer. The former is used to study a wide variety of ice features and to estimate deformations, while both are equally usable to observe ice types. With the present data, only the scatterometer can be used to distinguish positively multiyear from first-year and various types of thin ice. This is best done using coupled active and passive microwave sensing.We dedicate this work to our beloved friend William NordbergHe pioneered in microwave ice observations, and his brilliance and enthusiasm inspired all of us.  相似文献   
97.
We present experimental data on the steady state deflection of a highly supersonic jet by a side-wind in the laboratory. The use of a long interaction region enables internal shocks to fully cross the jet, leading to the development of significantly more structure in the jet than in previous work with a similar setup (Lebedev et al., 2004). The ability to control the length of the interaction region in the laboratory allows the switch between a regime representing a clumpy jet or wind and a regime similar to a slowly varying mass loss rate. The results indicate that multiple internal oblique shocks develop in the jet and the possible formation of a second working surface as the jet attempts to tunnel through the ambient medium.  相似文献   
98.
The Blue Ridge escarpment is a rugged landform situated within the ancient Appalachian orogen. While similar in some respects to the great escarpments along other passive margins, which have evolved by erosion following rifting, its youthful topographic expression has inspired proposals of Cenozoic tectonic rejuvenation in eastern North America. To better understand the post‐orogenic and post‐rift geomorphic evolution of passive margins, we have examined the origin of this landform using low‐temperature thermochronometry and manipulation of topographic indices. Apatite (U–Th)/He and fission‐track analyses along transects across the escarpment reveal a younging trend towards the coast. This pattern is consistent with other great escarpments and fits with an interpretation of having evolved by prolonged erosion, without the requirement of tectonic rejuvenation. Measured ages are also comparable specifically to those measured along other great escarpments that are as much as 100 Myr younger. This suggests that erosional mechanisms that maintain rugged escarpments in the early post‐rift stages may remain active on ancient passive margins for prolonged periods. The precise erosional evolution of the escarpment is less clear, however, and several end‐member models can explain the data. Our preferred model, which fits with all data, involves a significant degree of erosional escarpment retreat in the Cenozoic. Although this suggests that early onset of topographic stability is not required of passive margin evolution, more data are required to better constrain the details of the escarpment's development.  相似文献   
99.
Abstract

We examine Arctic sea‐ice concentration (SIC) and sea‐level pressure (SLP) data using principal oscillation pattern (POP) and neural network methods. The POP method extracts oscillating patterns from multivariate time series, each pattern being characterized by an oscillation period and a decay time. Predictions can be made for patterns whose decay time is comparable with the period. For both the SIC and SLP, however, the decay times are much shorter than the oscillation periods, and therefore the forcast skill is poor. A neural network is a model of the learning behaviour of a living neural system. Presented with training data, a neural network can learn the linear or non‐linear rules embedded in the data. We trained neural networks with sea‐ice and sea‐level pressure data, and estimated the forecast skill using a cross‐validation technique. The neural networks did not exhibit forecast skill significantly better than that of persistence. We contrast the Arctic situation with previous studies in which POP and neural networks were successfully used to forecast El Niño at lead times up to 6 months. Reasons for the lack of skill in both methods are discussed.  相似文献   
100.
This article presents the developments of an ongoing research aimed at modelling the influence of fissuring on the behaviour of clays. In particular, it recalls the main results of an extensive laboratory investigation on a fissured bentonite clay from the south of Italy and presents the data of a new investigation on the evolution with shearing of the strain fields developing within the clay, resulting from Digital Image Correlation (DIC). Element test results are analysed in the framework of continuum mechanics and linked to the clay fissuring features, once characterised using the Fissuring IDentity (F‐ID) chart. This article compares the bentonite behaviour with that of other fissured clays of different F‐IDs, highlighting the common behavioural features. Thereafter, the soil response at the macro level is related to the DIC‐derived strain fields evolving within the clay with loading. For this purpose, DIC was successfully used to investigate the deformation processes active in the fissured clay and the sources of the localisation phenomena. DIC is shown to provide indications of the extent to which highly to medium fissured clays element test results can be of use to model the clay behaviour according to continuum mechanics. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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