Origin of reverse-graded bedding in air-fall pumice, Coso Range, California

The origin of reverse grading in air-fall pyroclastic deposits has been ascribed to: (1) changing conditions at an erupting vent; (2) deposition in water; or (3) rolling of large clasts over smaller clasts on the surface of a steep slope. Structural features in a deposit of air-fall pumice lapilli in the Coso Range, California, indicate that reverse grading there formed by a fourth mechanism during flow of pumice. Reverse-graded beds in this deposit occur where pumice lapilli fell on slopes at or near the angle of repose and formed as parts of the blanket of accumulating pumice became unstable and flowed downslope. The process of size sorting during such flow is probably analogous to that which sorts sand grains in a reverse fashion during avalanching on the slip faces of sand dunes, attributed by Bagnold (1954a) to a grain-dispersive pressure acting on particles subjected to a shear stress. In view of the several ways in which air-fall pyroclastic debris may become reverse graded, caution is advised in interpretation of the origin of this structure both in modern and in ancient deposits.     

The radioracemization of isovaline. Cosmochemical implications

The optically pure d- and l-enantiomers of isovaline (I), which cannot be racemized by ordinary chemical mechanisms involving α-hydrogen removal, and which has been isolated in apparently racemic form from the Murchison meteorite, have been subjected to partial radiolysis by the ionizing radiation from a 3000 Ci ⁶⁰Co γ-ray source. Both in the anhydrous and hydrated solid states and as solid sodium or hydrochloride salts each enantiomer suffered significant radioracemization of the undestroyed residue during its partial radiolysis. The sodium salt of isovaline in 0.1 M aqueous solution suffered extensive radiolysis with relatively small radiation doses, but showed no detectable radioracemization. The significance of these observations with respect to the primordial enantiomeric composition of the isovaline (and other amino acids) indigenous to meteroties is discussed.     

Radiance and color of the sky at twilight: Perturbations caused by stratospheric haze

Layers of stratospheric aerosol with optical thicknesses as small as 10^–4 cause noticeable perturbations in the monochromatic logarithmic brightness gradient,G, and the color ratio,C, of the twilight sky. Modeling of the twilight's radiant properties shows that definite single-valued relationships exist between maxima inC or minima inG and optical thickness, , physical thickness h, and mean altitude, , of stratospheric layers. It is therefore possible to determine , h and and monitor their variations by performing either single wavelength measurements ofG or two-wavelength spectrophotometric measurements ofC. The presence of haze in the lower troposphere and the occurrence of multiple scattering both have relatively minor influences on the recovery of the stratospheric dust properties, provided that 10< <30 km.Formal mathematical inversions of the single-scattering twilight equations are possible in principle, but difficult in practice because of non-linearities. Inversions incorporating an iterative linearization process with constrained smoothing, successfully recovered the features of the haze layer, but tended to oversmooth the vertical profile and underestimate the mean altitude of the haze layer.     

Electron microprobe study of a ‘mysterite’-bearing inclusion from the Krymka LL-chondrite

The black inclusion from the Krymka LL3 chondrite previously found to contain ‘mysterite’ by Lewiset al. (1979) belongs to a hitherto unknown class of carbonaceous chondrites. Its olivine and pyroxene compositions. Fo 97–99 and En 96, respectively, are characteristic of carbonaceous chondrites and its plagioclase composition. An 100, is characteristic of C3's. It contains a peculiar group of Co-, Cr-rich metal grains whose compositions are similar, but not identical, to those in C2 chondrites and which also bear some similarities to those in Renazzo. Its weight ratios of total $\text{Fe}\text{SiO}{}_2$ and $\text{solSiO}{}_2\text{MgO}$ are 0.74 and 1.43, respectively, and its atomic ratio of $\text{Si}\text{Al}$ is 10.7, exactly the same as in carbonaceous chondrites. Its bulk chemical composition is very close to that of the Murchison C2 chondrite. The association of mysterite with a special type of carbonaceous chondrite material suggests that mysterite formed by low-temperature condensation in a different region of the nebula from other carbonaceous chondrites.     

Observations on the asexual reproductive activities of the sessile stages of the sea nettleChrysaora quinquecirrha (Scyphozoa)

Twenty-seven colonies of wild scyphistomae ofChrysaora quinquecirrha were observed for a period of ten weeks during the summer. Asexual activities of individual organisms were recorded several times each week. Polyps most often proceeded to strobilate in mid-June and then strobilate a second time 18 days later. They then detached and changed position by means of stolons and then produced podocysts. Initial cysts first excysted and the resulting polyps then strobilated. A second strobilation was not generally observed. The developmental implications of these activities are discussed.     

Convolute laminations — a theoretical analysis: example of a Pennsylvanian sandstone

Data from an outcropping laminated interval were collected and analyzed to test the applicability of a theoretical model describing instability of layered systems. Rayleigh—Taylor wave perturbations result at the interface between fluids of contrasting density, viscosity, and thickness. In the special case where reverse density and viscosity interlaminations are developed, the deformation response produces a single wave with predictable amplitudes, wavelengths, and amplification rates.Physical measurements from both the outcropping section and modern sediments suggest the usefulness of the model for the interpretation of convolute laminations. Internal characteristics of the stratigraphic interval, and the developmental sequence of convoluted beds, are used to document the developmental history of these structures.     

Regression‐based approach to low flow prediction in the Maryland Piedmont region under joint climate and land use change

We examine the low flow records for six urbanized watersheds in the Maryland Piedmont region and develop regression equations to predict annual minimum low flow events. The effects of both future climate (based on precipitation and temperature projections from two climate models: Hadley and the Canadian Climate Centre (CCC)) and land use change are incorporated to illustrate possible future trends in low flows. A regression modelling approach is pursued to predict the minimum annual 7‐day low flow estimates for the proposed future scenarios. A regional regression model was calibrated with between 10 and 50 years of daily precipitation, daily average temperature, annual imperviousness, and the daily observed flow time‐series across six watersheds. Future simulations based on a 55 km² urbanizing watershed just north of Washington, DC, were performed. When land use and climate change were employed singly, the former predicted no trends in low flows and the latter predicted significant increasing trends under Hadley and no trends under CCC. When employed jointly, however, low flows were predicted to decrease significantly under CCC, whereas Hadley predicted no significant trends in low flows. Antecedent precipitation was the most influential predictor on low flows, followed by urbanization. Copyright © 2006 John Wiley & Sons, Ltd.     

Calibrating a glaciological model of the Greenland ice sheet from the Last Glacial Maximum to present-day using field observations of relative sea level and ice extent

We constrain a three-dimensional thermomechanical model of Greenland ice sheet (GrIS) evolution from the Last Glacial Maximum (LGM, 21 ka BP) to the present-day using, primarily, observations of relative sea level (RSL) as well as field data on past ice extent. Our new model (Huy2) fits a majority of the observations and is characterised by a number of key features: (i) the ice sheet had an excess volume (relative to present) of 4.1 m ice-equivalent sea level at the LGM, which increased to reach a maximum value of 4.6 m at 16.5 ka BP; (ii) retreat from the continental shelf was not continuous around the entire margin, as there was a Younger Dryas readvance in some areas. The final episode of marine retreat was rapid and relatively late (c. 12 ka BP), leaving the ice sheet land based by 10 ka BP; (iii) in response to the Holocene Thermal Maximum (HTM) the ice margin retreated behind its present-day position by up to 80 km in the southwest, 20 km in the south and 80 km in a small area of the northeast. As a result of this retreat the modelled ice sheet reaches a minimum extent between 5 and 4 ka BP, which corresponds to a deficit volume (relative to present) of 0.17 m ice-equivalent sea level. Our results suggest that remaining discrepancies between the model and the observations are likely associated with non-Greenland ice load, differences between modelled and observed present-day ice elevation around the margin, lateral variations in Earth structure and/or the pattern of ice margin retreat.     

Arsenic in an alkaline AMD treatment sludge: Characterization and stability under prolonged anoxic conditions

Lime treatment of acid mine drainage (AMD) generates large volumes of neutralization sludge that are often stored under water covers. The sludge consists mainly of calcite, gypsum and a widespread ferrihydrite-like Fe phase with several associated species of metal(loid) contaminants. The long-term stability of metal(loid)s in this chemically ill-defined material remains unknown. In this study, the stability and speciation of As in AMD sludge subjected to prolonged anoxic conditions is determined. The total As concentration in the sludge is 300 mg kg⁻¹. In the laboratory, three distinct water cover treatments were imposed on the sludge to induce different redox conditions (100%N₂, 100%N₂ + glucose, 95%N₂:5%H₂). These treatments were compared against a control of oxidized, water-saturated sludge. Electron micro-probe (EMP) analysis and spatially resolved synchrotron X-ray fluorescence (SXRF) results indicate that As is dominantly associated with Fe in the sludge. In all treatments and throughout the experiment, measured concentrations of dissolved As were less than 5 μg L⁻¹. Dissolved Mn concentration in the N₂ + glucose treatment increased significantly compared to other treatments. Manganese and As K-edge X-ray absorption near edge structure spectroscopy (XANES) analyses showed that Mn was the redox-active element in the solid-phase, while As was stable. Arsenic(V) was still the dominant species in all water-covered sludges after 9 months of anoxic treatments. In contrast, Mn(IV) in the original sludge was partially reduced into Mn(II) in all water-covered sludges. The effect was most pronounced in the N₂ + glucose treatment, suggesting microbial reduction. Micro-scale SXRF and XANES analysis of the treated sludge showed that Mn(II) accumulated in areas already enriched in Fe and As. Overall, the study shows that AMD sludges remain stable under prolonged anoxic conditions. External sources of chemical reductants or soluble C were needed to induce lower redox state in the systems, and even under these imposed treatments, only weakly reducing conditions (Mn threshold) developed. The results suggest that As(V) in AMD sludge will remain stable under prolonged anoxic conditions as long as Mn(IV) is present and organic matter accumulation is negligible.